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1.发明授权Hydrogenation of methylenedianiline to produce bis(para-aminocyclohexyl)methane 失效亚甲基二苯胺的氢化生成双（对氨基环己基）甲烷
公开(公告)号：US4946998A
公开(公告)日：1990-08-07
申请号：US154662
申请日：1988-02-10
IPC分类号： C07B61/00 , B01J23/00 , B01J23/46 , C07C65/24 , C07C67/00 , C07C209/00 , C07C209/68 , C07C209/72 , C07C211/36 , C07C211/37 , C07C211/54
CPC分类号： C07C209/72 , C07C2101/14
摘要： This invention relates to an improved hydrogenation process wherein methylenedianiline is reduced to form bis(para-aminocyclohexyl)methane (PACM). The process contemplates contacting methylenedianiline and hydrogen in the presence of a two component metal catalyst comprising rhodium and ruthenium under mild hydrogenation conditions. Use of the mixed metal catalyst system allows one to obtain a preselected isomer ratio having from about 5-40% by weight, typically 14`28% by weight of the trans,trans- configurational isomer.
摘要翻译： 本发明涉及一种改进的氢化方法，其中亚甲基二苯胺被还原形成双（对 - 氨基环己基）甲烷（PACM）。 该方法考虑在温和氢化条件下，在包含铑和钌的双组分金属催化剂的存在下使亚甲基二苯胺和氢气接触。 使用混合金属催化剂体系允许获得具有反式，反式构型异构体的约5-40重量％，通常为14.28重量％的预选异构体比例。
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2.发明授权Hydrogenation of methylenedianiline to produce bis(para-aminocyclohexyl)methane 失效亚甲基二苯胺的氢化生成双（对氨基环己基）甲烷
公开(公告)号：US4754070A
公开(公告)日：1988-06-28
申请号：US821629
申请日：1986-01-23
IPC分类号： C07B61/00 , B01J23/00 , B01J23/46 , C07C65/24 , C07C67/00 , C07C209/00 , C07C209/68 , C07C209/72 , C07C211/36 , C07C211/37 , C07C211/54
CPC分类号： C07C209/72 , C07C2101/14
摘要： This invention relates to an improved hydrogenation process wherein methylenedianiline is reduced to form bis(para-aminocyclohexyl)methane (PACM). The process contemplates contacting methylenedianiline and hydrogen in the presence of a two component metal catalyst comprising rhodium and ruthenium under mild hydrogenation conditions. Use of the mixed metal catalyst system allows one to obtain a preselected isomer ratio having from about 5-40% by weight, typically 14-28% by weight of the trans,trans- configurational isomer.
摘要翻译： 本发明涉及一种改进的氢化方法，其中亚甲基二苯胺被还原形成双（对 - 氨基环己基）甲烷（PACM）。 该方法考虑在温和氢化条件下，在包含铑和钌的双组分金属催化剂的存在下使亚甲基二苯胺和氢气接触。 使用混合金属催化剂体系允许获得具有反式，反式构型异构体的约5-40重量％，通常为14-28重量％的预选异构体比例。
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3.发明授权Branched alkyl-containing aminobenzamides as chain extenders in polyurethane-urea elastomers 失效支链烷基氨基苯甲酰胺作为聚氨酯 - 尿素弹性体中的扩链剂
公开(公告)号：US5371288A
公开(公告)日：1994-12-06
申请号：US227840
申请日：1994-04-13
IPC分类号： C07C237/34 , C08G18/10 , C08G8/10 , C08G8/32
CPC分类号： C07C237/34 , C08G18/10
摘要： N,N'-Di-(branched alkyl)-alkylenediamine-bis-p-aminobenzamides are useful as chain extenders in the manufacture of polyurethane-urea elastomers. These compositions have remarkably uniform reactivities but can be varied structurally to achieve a range of processibility characteristics by altering the melting points of the chain extenders. The preferred compounds melt in a range of 50.degree. to 175.degree. C. while exhibiting t.sub.5000 reactivities of about four minutes. The combination of processing characteristics, reactivities and physical properties of the elastomer products offers advantages not available in commonly used diamine chain extenders of the prior art.
摘要翻译： N，N'-二 - （支链烷基） - 亚烷基二胺 - 双 - 对氨基苯甲酰胺可用作制造聚氨酯 - 尿素弹性体的扩链剂。 这些组合物具有非常均匀的反应性，但可在结构上变化，以通过改变扩链剂的熔点来实现一定程度的加工特性。 优选的化合物在50℃至175℃的范围内熔融，同时具有约4分钟的t5000反应性。 弹性体产品的加工特性，反应性和物理性质的组合提供了在现有技术的常用二胺扩链剂中不可用的优点。
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公开(公告)号：US5369184A
公开(公告)日：1994-11-29
申请号：US172469
申请日：1993-12-23
CPC分类号： C08F8/30
摘要： Resins which comprise polymers which contain multiple acetal groups have been developed which are useful for crosslinking and adhesion promotion in coating and adhesive applications. The polymers which make up these resins are prepared by the addition of aminoacetals to polymers containing anhydride functionality. The polymers are modified by titration with ammonia or a primary or secondary amine which solubilizes the polymer in aqueous systems.
摘要翻译： 已经开发了包含多个缩醛基团的聚合物的树脂，其可用于涂料和粘合剂应用中的交联和粘合促进。 构成这些树脂的聚合物通过向含有酸酐官能团的聚合物中加入氨基缩醛制备。 聚合物通过用氨或一种或多种仲胺进行滴定而改性，其在水性体系中溶解聚合物。
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公开(公告)号：US5360876A
公开(公告)日：1994-11-01
申请号：US184316
申请日：1994-01-21
IPC分类号： C07C233/18 , C07C233/20 , C07C233/60 , C07C233/69 , C07C235/08 , C07D209/48 , C08F8/30
CPC分类号： C07D209/48 , C07C233/18 , C07C233/20 , C07C233/60 , C07C233/69 , C07C235/08 , C07C2101/14
摘要： Crosslinking agents are provided which are stable in both the solid state and in solution without undergoing uncontrolled self-crosslinking reactions. The crosslinking agents are formed by the amination of compounds having multiple ester moieties using homogeneous catalysis, and provide for formaldehyde-free crosslinking.
摘要翻译： 提供在固态和溶液中均稳定的交联剂，而不会发生不受控制的自交联反应。 交联剂通过使用均相催化胺化具有多个酯部分的化合物形成，并提供无甲醛交联。
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6.发明授权
公开(公告)号：US5298567A
公开(公告)日：1994-03-29
申请号：US77696
申请日：1993-06-15
CPC分类号： C08F8/30 , C08F2800/10 , C08F2810/20
摘要： Resins which comprise polymers which contain multiple acetal groups have been developed which are useful for crosslinking and adhesion promotion in coating and adhesive applications. The polymers which make up these resins are prepared by the addition of aminoacetals to polymers containing anhydride functionality. Optionally, these polymers may be modified by titration with a tertiary amine or alkali base which solubilizes the polymer in aqueous systems.
摘要翻译： 已经开发了包含多个缩醛基团的聚合物的树脂，其可用于涂料和粘合剂应用中的交联和粘合促进。 构成这些树脂的聚合物通过向含有酸酐官能团的聚合物中加入氨基缩醛制备。 任选地，这些聚合物可以通过用在水系统中溶解聚合物的叔胺或碱碱进行滴定来改性。
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公开(公告)号：US5264501A
公开(公告)日：1993-11-23
申请号：US743463
申请日：1991-08-09
IPC分类号： C07C211/36 , C08G59/50
CPC分类号： C08G59/5026 , C07C211/36 , C07C2101/14
摘要： This invention pertains to alkyl substituted bi(cyclohexylamine) and derivatives having a high trans,trans-isomer distribution. This isomer distribution represents a thermodynamic mixture of the isomers and provides for extended pot life and extended thermal properties in epoxy resins which are not seen with the kinetic isomer mixture. The bridged cyclohexylamine and derivatives are represented by the formula: ##STR1## wherein; R.sup.1 is hydrogen or C.sub.1-4 alkyl;R.sup.2 is C.sub.1-4 alkyl; andR.sup.3 is hydrogen or C.sub.1-4 alkylThe invention also relates to epoxy resins cured with the bridged bi(cyclohexylamines).
摘要翻译： 本发明涉及烷基取代的双（环己胺）和具有高反式，反式异构体分布的衍生物。 这种异构体分布表示异构体的热力学混合物，并且提供了在动力学异构体混合物中未见的环氧树脂中的延长的适用期和延长的热性能。 桥连环己胺及其衍生物由下式表示：其中： R1是氢或C1-4烷基; R2是C1-4烷基; 并且R 3是氢或C 1-4烷基本发明还涉及用桥连双（环己胺）固化的环氧树脂。
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公开(公告)号：US5071809A
公开(公告)日：1991-12-10
申请号：US519711
申请日：1990-05-07
IPC分类号： C07C217/08 , C07D295/088 , C08G18/18 , C08G18/20
CPC分类号： C07D295/088 , C07C217/08 , C08G18/1825 , C08G18/1833 , C08G18/2009
摘要： The invention pertains to tertiary amines used as catalysts for the preparation of polyurethane foams prepared via the catalytic reaction of a polyisocyanate with a polyol in the presence of blowing agents, etc. The tertiary amine catalysts are prepared by reacting an olefinic nitrile with aliphatic polyol having at least secondary hydroxyl functionality in a ratio less than stoichiometric for providing cyanoalkylated polyol having residual hydroxyl functionality. The resulting cyanoalkylated polyol then is reacted with a secondary amine under conditions for effective reductive alkylation.The tertiary amine catalysts, because of residual secondary hydroxyl functionality, provide for uniform dispersion within a polyurethane formulation; they provide for additional or extended pot life in polyurethane formulations at temperatures below reaction condition, and they are bound by reaction on cure.
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公开(公告)号：US4946925A
公开(公告)日：1990-08-07
申请号：US444492
申请日：1989-12-01
IPC分类号： C07C211/36 , C08G59/50
CPC分类号： C08G59/5026 , C07C211/36 , C07C2101/14
摘要： This invention relates to bridged cyclohexylamines represented by the formula: ##STR1## A is C.sub.0, --CH.sub.2 --, ##STR2## R.sub.1 is C.sub.1-3 alkyl R.sub.2 is C.sub.1-6 alkylR.sub.3 is C.sub.1 or C.sub.2 alkylR.sub.4 is H or C.sub.1-4 alkylx is 0 or 1y is 0 or 1These bridged bis(cyclohexylamine) derivatives are well suited as curing agents for epoxy resins. These compositions lead to enhanced processing of the epoxy resin and permit adjustment of the reactivity/performance in formulating epoxies which demonstrate superior high temperature properties.
摘要翻译： 本发明涉及由下式表示的桥连环己胺：A为C 0，-CH 2 - ，R 1为C 1-3烷基R 2为C 1-6烷基R 3为C 1或C 2烷基R 4为H或C 1-4 烷基x为0或1 y为0或1这些桥连双（环己胺）衍生物非常适合用作环氧树脂的固化剂。 这些组合物导致环氧树脂的加工增强，并且允许调节表现出优异的高温性能的环氧树脂的反应性/性能。
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公开(公告)号：US4908394A
公开(公告)日：1990-03-13
申请号：US267217
申请日：1988-11-04
申请人： Jeremiah P. Casey , Susan M. Clift
发明人： Jeremiah P. Casey , Susan M. Clift
CPC分类号： C08G18/325 , C08G18/1825
摘要： The present invention relates to a process for the production of polyurethanes wherein a tertiary amine functionality is incorporated into the side chain of a diaminobenzoate to form catalytic polyurethane chain extender. These chain extenders are polyurethane catalysts which provide adequate cure without residual odor and safety hazards associated with the more traditional tertiary amine catalysts. When reacted with the isocyanate reactive group the non-tertiary amine portion of the chain extender is bound to the polymeric network thereby preventing diffusion of the catalyst species from the polyurethane and negating odor and toxicity as problems. The diaminobenzoate provides enhanced polyurethane physical properties.
摘要翻译： 本发明涉及生产聚氨酯的方法，其中叔胺官能团被引入到二氨基苯甲酸酯的侧链中以形成催化聚氨酯增链剂。 这些增链剂是提供足够固化而不具有与更传统的叔胺催化剂相关的残留气味和安全危害的聚氨酯催化剂。 当与异氰酸酯反应性基团反应时，扩链剂的非叔胺部分结合到聚合物网络，从而防止催化剂物质从聚氨酯扩散，并且作为问题消除气味和毒性。 二氨基苯甲酸酯提供增强的聚氨酯物理性能。
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