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公开(公告)号：US5369184A
公开(公告)日：1994-11-29
申请号：US172469
申请日：1993-12-23
CPC分类号： C08F8/30
摘要： Resins which comprise polymers which contain multiple acetal groups have been developed which are useful for crosslinking and adhesion promotion in coating and adhesive applications. The polymers which make up these resins are prepared by the addition of aminoacetals to polymers containing anhydride functionality. The polymers are modified by titration with ammonia or a primary or secondary amine which solubilizes the polymer in aqueous systems.
摘要翻译： 已经开发了包含多个缩醛基团的聚合物的树脂，其可用于涂料和粘合剂应用中的交联和粘合促进。 构成这些树脂的聚合物通过向含有酸酐官能团的聚合物中加入氨基缩醛制备。 聚合物通过用氨或一种或多种仲胺进行滴定而改性，其在水性体系中溶解聚合物。
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公开(公告)号：US5360876A
公开(公告)日：1994-11-01
申请号：US184316
申请日：1994-01-21
IPC分类号： C07C233/18 , C07C233/20 , C07C233/60 , C07C233/69 , C07C235/08 , C07D209/48 , C08F8/30
CPC分类号： C07D209/48 , C07C233/18 , C07C233/20 , C07C233/60 , C07C233/69 , C07C235/08 , C07C2101/14
摘要： Crosslinking agents are provided which are stable in both the solid state and in solution without undergoing uncontrolled self-crosslinking reactions. The crosslinking agents are formed by the amination of compounds having multiple ester moieties using homogeneous catalysis, and provide for formaldehyde-free crosslinking.
摘要翻译： 提供在固态和溶液中均稳定的交联剂，而不会发生不受控制的自交联反应。 交联剂通过使用均相催化胺化具有多个酯部分的化合物形成，并提供无甲醛交联。
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3.发明授权
公开(公告)号：US5298567A
公开(公告)日：1994-03-29
申请号：US77696
申请日：1993-06-15
CPC分类号： C08F8/30 , C08F2800/10 , C08F2810/20
摘要： Resins which comprise polymers which contain multiple acetal groups have been developed which are useful for crosslinking and adhesion promotion in coating and adhesive applications. The polymers which make up these resins are prepared by the addition of aminoacetals to polymers containing anhydride functionality. Optionally, these polymers may be modified by titration with a tertiary amine or alkali base which solubilizes the polymer in aqueous systems.
摘要翻译： 已经开发了包含多个缩醛基团的聚合物的树脂，其可用于涂料和粘合剂应用中的交联和粘合促进。 构成这些树脂的聚合物通过向含有酸酐官能团的聚合物中加入氨基缩醛制备。 任选地，这些聚合物可以通过用在水系统中溶解聚合物的叔胺或碱碱进行滴定来改性。
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4.发明授权Polyurethane system using monotertiary-alkyltoluenediamine as a cross linker 失效使用单三烷基甲苯二胺作为交联剂的聚氨酯体系
公开(公告)号：US4816543A
公开(公告)日：1989-03-28
申请号：US768886
申请日：1985-08-23
CPC分类号： C08G18/6618 , C08G18/10 , C08G18/324 , C08G2120/00
摘要： This invention relates to improved polyurethane systems prepared by reacting an organic polyisocyanate with a hydroxyl containing compound, the improvement comprising utilizing mono tertiary-alkyltoluenediamine where the tertiary-alkyl group is ortho to an amine group as a chain extender or component thereof. The ortho-tertiary-butyltoluenediamine isomer is particular effective for use in reaction injection molding of polyurethanes and can be formulated with polyol as a chain extender mix.
摘要翻译： 本发明涉及通过使有机多异氰酸酯与含羟基的化合物反应制备的改进的聚氨酯体系，其改进包括使用叔烷基甲苯二胺，其中叔烷基与胺基邻近作为扩链剂或其组分。 邻 - 叔丁基甲苯二胺异构体特别适用于聚氨酯的反应注射成型，并可与多元醇一起配制为扩链剂混合物。
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公开(公告)号：US5369185A
公开(公告)日：1994-11-29
申请号：US172470
申请日：1993-12-23
CPC分类号： C08F8/30 , C08F2800/10
摘要： Resins which comprise polymers which contain multiple acetal groups have been developed which are useful for crosslinking and adhesion promotion in coating and adhesive applications. The polymers which make up these resins are prepared by the addition of aminoacetals to polymers containing anhydride functionality. The polymers are modified by titration with a tertiary amine or alkali base.
摘要翻译： 已经开发了包含多个缩醛基团的聚合物的树脂，其可用于涂料和粘合剂应用中的交联和粘合促进。 构成这些树脂的聚合物通过向含有酸酐官能团的聚合物中加入氨基缩醛制备。 通过用叔胺或碱碱进行滴定来改性聚合物。
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公开(公告)号：US4745223A
公开(公告)日：1988-05-17
申请号：US768885
申请日：1985-08-23
IPC分类号： C07C211/51 , C08G18/32 , C07C87/58
CPC分类号： C08G18/324 , C08G2120/00
摘要： This invention relates to a class of tertiary-alkyltoluenediamines having alkyl groups ortho to an amine group. More particularly the aromatic diamines are represented by the formulas: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are C.sub.1-3 alkyl groups or R.sub.2 and R.sub.3 are combined to form a C.sub.5-6 membered ring.The above described alkylated aromatic diamines have been found to be well suited for use as a chain extender in forming polyurethane/urea elastomer systems and the mono tert-butyltoluenediamine isomers have been found to be nonmutagenic in the Ames test.
摘要翻译： 本发明涉及一类具有与胺基邻位烷基的叔烷基甲苯二胺。 更具体地，芳族二胺由下式表示：其中R 1，R 2和R 3是C 1-3烷基或R 2和R 3结合形成C 5-6元环。 已经发现上述烷基化芳族二胺非常适合用作形成聚氨酯/脲弹性体体系的扩链剂，并且在Ames试验中已经发现单叔丁基甲苯二胺异构体是非引发剂。
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公开(公告)号：US5336807A
公开(公告)日：1994-08-09
申请号：US77580
申请日：1993-06-15
IPC分类号： C07C233/18 , C07C233/20 , C07C233/60 , C07C233/69 , C07C235/08 , C07D209/48 , C07C49/00
CPC分类号： C07D209/48 , C07C233/18 , C07C233/20 , C07C233/60 , C07C233/69 , C07C235/08 , C07C2101/14
摘要： Crosslinking agents are provided which are stable in both the solid state and in solution without undergoing uncontrolled self-crosslinking reactions. The crosslinking agents are formed by the amination of compounds having multiple ester moieties using homogeneous catalysis, and provide for formaldehyde-free crosslinking.
摘要翻译： 提供在固态和溶液中均稳定的交联剂，而不会发生不受控制的自交联反应。 交联剂通过使用均相催化胺化具有多个酯部分的化合物形成，并提供无甲醛交联。
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公开(公告)号：US4952220A
公开(公告)日：1990-08-28
申请号：US420087
申请日：1989-10-11
CPC分类号： B01D67/0093 , B01D71/64 , B01D71/82 , C08G73/1042 , B01D2323/30
摘要： The present invention is a class of polyimide membranes containing copolymerizable, surface modifiable units containing both aromatic diamines and alkenylated diamines having an allyl or allylaryl group preferably positoned ortho to an amine functionality. The polyimide membranes can be surface modified by treatment with an activating force such as high energy electromagnetic irradiation or with a free radical source to impart high selectivity to the membrane without causing a large decrease in composite permeance.
摘要翻译： 本发明是一类聚酰亚胺膜，其含有可共聚的表面改性单元，其含有芳族二胺和具有烯丙基或烯丙基芳基的烯基化二胺，优选与胺官能团邻位。 聚酰亚胺膜可以通过用诸如高能电磁照射的激活剂处理或用自由基源进行表面改性以赋予膜高选择性而不引起复合渗透性的大幅度降低。
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公开(公告)号：US4931182A
公开(公告)日：1990-06-05
申请号：US433495
申请日：1989-11-08
CPC分类号： B01D67/0093 , B01D71/64 , B01D71/82 , C08G73/1039 , B01D2323/30
摘要： The present invention is a class of polyimide membranes containing copolymerizable, surface modifiable units containing both aromatic diamines and alkenylated diamines having a vinyl or vinylaryl group preferably positioned ortho to an amine functionality. The polyimide membranes can be crosslinked by treatment with an activating force such as high energy electromagnetic irradiation or with a free radical source to impart high selectivity to the membrane without causing a large decrease in composite permeance.
摘要翻译： 本发明是一类聚酰亚胺膜，其含有可共聚的表面改性单元，其含有芳族二胺和具有乙烯基或乙烯基芳基的烯基化二胺优选位于胺官能团的邻位。 聚酰亚胺膜可以通过用诸如高能电磁照射的激活剂处理或用自由基源进行交联，以赋予膜高的选择性而不引起复合渗透性的大的降低。
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10.发明授权Branched alkyl-containing aminobenzamides as chain extenders in polyurethane-urea elastomers 失效支链烷基氨基苯甲酰胺作为聚氨酯 - 尿素弹性体中的扩链剂
公开(公告)号：US5371288A
公开(公告)日：1994-12-06
申请号：US227840
申请日：1994-04-13
IPC分类号： C07C237/34 , C08G18/10 , C08G8/10 , C08G8/32
CPC分类号： C07C237/34 , C08G18/10
摘要： N,N'-Di-(branched alkyl)-alkylenediamine-bis-p-aminobenzamides are useful as chain extenders in the manufacture of polyurethane-urea elastomers. These compositions have remarkably uniform reactivities but can be varied structurally to achieve a range of processibility characteristics by altering the melting points of the chain extenders. The preferred compounds melt in a range of 50.degree. to 175.degree. C. while exhibiting t.sub.5000 reactivities of about four minutes. The combination of processing characteristics, reactivities and physical properties of the elastomer products offers advantages not available in commonly used diamine chain extenders of the prior art.
摘要翻译： N，N'-二 - （支链烷基） - 亚烷基二胺 - 双 - 对氨基苯甲酰胺可用作制造聚氨酯 - 尿素弹性体的扩链剂。 这些组合物具有非常均匀的反应性，但可在结构上变化，以通过改变扩链剂的熔点来实现一定程度的加工特性。 优选的化合物在50℃至175℃的范围内熔融，同时具有约4分钟的t5000反应性。 弹性体产品的加工特性，反应性和物理性质的组合提供了在现有技术的常用二胺扩链剂中不可用的优点。
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