Drag reducing agent and process of manufacture thereof

    公开(公告)号:US11814458B2

    公开(公告)日:2023-11-14

    申请号:US17510770

    申请日:2021-10-26

    Abstract: A process of manufacturing a composition comprises a particulate drag reducing agent is disclosed. The process comprising: continuously forming a temporary container; introducing an unsaturated monomer component and a radical polymerization component into the temporary container; sealing the temporary container to form a sealed temporary container; allowing the unsaturated monomer component to polymerize in the sealed temporary container to form the drag reducing agent via a radical polymerization reaction, the drag reducing agent having a molecular weight of about 1 million gram/mol to about 50 million gram/mol; and grinding the drag reducing agent to form a composition comprising a particulate drag reducing agent, the particulate drag reducing agent having a particle size of about 1 to about 1,500 microns.

    DRAG REDUCING AGENT AND PROCESS OF MANUFACTURE THEREOF

    公开(公告)号:US20220195098A1

    公开(公告)日:2022-06-23

    申请号:US17510770

    申请日:2021-10-26

    Abstract: A process of manufacturing a composition comprises a particulate drag reducing agent is disclosed. The process comprising: continuously forming a temporary container; introducing an unsaturated monomer component and a radical polymerization component into the temporary container; sealing the temporary container to form a sealed temporary container; allowing the unsaturated monomer component to polymerize in the sealed temporary container to form the drag reducing agent via a radical polymerization reaction, the drag reducing agent having a molecular weight of about 1 million gram/mol to about 50 million gram/mol; and grinding the drag reducing agent to form a composition comprising a particulate drag reducing agent, the particulate drag reducing agent having a particle size of about 1 to about 1,500 microns.

    Polymerization Process with catalyst reactivation
    6.
    发明申请
    Polymerization Process with catalyst reactivation 有权
    催化剂再活化聚合过程

    公开(公告)号:US20090312505A1

    公开(公告)日:2009-12-17

    申请号:US11990841

    申请日:2006-08-28

    Abstract: Polymerization processes of the present invention comprise low catalyst concentration. Embodiments include a polymerization process comprising polymerizing free radically (co)polymerizable monomers in a polymerization medium comprising one or more radically (co)polymerizable monomers, a transition metal catalyst complex capable of participating in a one electron redox reaction with an ATRP initiator; a free radical initiator; and an ATRP initiator; (wherein the concentration of transition metal catalyst complex in the polymerization medium is less than 100 ppm). Further embodiments include a polymerization process, comprising polymerizing one or more radically (co)polymerizable monomers in the presence of at least one transition metal catalyst complex; and an ATRP initiator; and a reducing agent; wherein the transition metal catalyst complex is present at less than 10″3 mole compared to the moles of radically transferable atoms or groups present on the ATRP initiator.

    Abstract translation: 本发明的聚合方法包括低催化剂浓度。 实施方案包括聚合方法,其包括在包含一种或多种自由基(共)可聚合单体的聚合介质中自由基(共)可聚合单体聚合,能够与ATRP引发剂参与一电子氧化还原反应的过渡金属催化剂络合物; 自由基引发剂; 和ATRP引发剂; (其中聚合介质中过渡金属催化剂配合物的浓度小于100ppm)。 另外的实施方案包括聚合方法,包括在至少一种过渡金属催化剂络合物的存在下聚合一种或多种自由基(共)可聚合单体; 和ATRP引发剂; 和还原剂; 其中与ATRP引发剂上存在的可自由基转移的原子或基团的摩尔数相比,过渡金属催化剂络合物的存在量小于10'3摩尔。

    POLYMERIZATION PROCESS WITH CATALYST REACTIVATION
    10.
    发明申请
    POLYMERIZATION PROCESS WITH CATALYST REACTIVATION 审中-公开
    具有催化反应的聚合方法

    公开(公告)号:US20110065875A1

    公开(公告)日:2011-03-17

    申请号:US12949466

    申请日:2010-11-18

    Abstract: Polymerization processes of the present invention comprise low catalyst concentration. Embodiments include a polymerization process comprising polymerizing free radically (co)polymerizable monomers in a polymerization medium comprising one or more radically (co)polymerizable monomers, a transition metal catalyst complex capable of participating in a one electron redox reaction with an ATRP initiator; a free radical initiator; and an ATRP initiator; (wherein the concentration of transition metal catalyst complex in the polymerization medium is less than 100 ppm). Further embodiments include a polymerization process, comprising polymerizing one or more radically (co)polymerizable monomers in the presence of at least one transition metal catalyst complex; an ATRP initiator; and a reducing agent; wherein the transition metal catalyst complex is present at less than 10−3 mole compared to the moles of radically transferable atoms or groups present on the ATRP initiator.

    Abstract translation: 本发明的聚合方法包括低催化剂浓度。 实施方案包括聚合方法,其包括在包含一种或多种自由基(共)可聚合单体的聚合介质中自由基(共)可聚合单体聚合,能够与ATRP引发剂参与一电子氧化还原反应的过渡金属催化剂络合物; 自由基引发剂; 和ATRP引发剂; (其中聚合介质中过渡金属催化剂配合物的浓度小于100ppm)。 另外的实施方案包括聚合方法,包括在至少一种过渡金属催化剂络合物的存在下聚合一种或多种自由基(共)可聚合单体; ATRP引发剂; 和还原剂; 其中与ATRP引发剂上存在的可自由基转移的原子或基团的摩尔数相比,过渡金属催化剂络合物的存在量小于10-3摩尔。

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