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    ATOM TRANFER DISPERSION POLYMERIZATION
    3.
    发明申请
    ATOM TRANFER DISPERSION POLYMERIZATION 有权
    原子转移分散聚合

    公开(公告)号：US20100273906A1

    公开(公告)日：2010-10-28

    申请号：US12451581

    申请日：2008-05-23

    Applicant: Krzysztof Matyjaszewski ,  Ke Min ,  James Spanswick

    Inventor： Krzysztof Matyjaszewski ,  Ke Min ,  James Spanswick

    IPC: C08J9/00 ,  C08F36/20

    CPC classification number: C08F12/08 ,  C08F2/14 ,  C08F2/38 ,  C08F212/36 ,  C08F2438/01

    Abstract: The present disclosure describes a two-step batch dispersion polymerization process for the preparation of substantially uniformed-sized functional (co)polymer particles. The first step of the process includes polymerizing at least one first radically (co)polymerizable monomer by a free radical polymerization process to form a (co)polymer in a stable colloidal dispersion and the second step includes polymerizing the at first radically (co)polymerizable monomer or an additional radically (co)polymerizable monomer in the stable colloidal dispersion by a living/controlled radical (co)polymerization process.

    Abstract translation: 本公开描述了用于制备基本上均匀尺寸的功能（共）聚合物颗粒的两步间歇分散聚合方法。 该方法的第一步包括通过自由基聚合方法聚合至少一种第一自由基（共）可聚合单体，以在稳定的胶态分散体中形成（共）聚合物，第二步包括首先从根本上聚合（共）可聚合 单体或通过活/受控自由基（共）聚合方法在稳定的胶体分散体中的另外的自由基（共）可聚合单体。

    Polymerization Process with catalyst reactivation
    4.
    发明申请
    Polymerization Process with catalyst reactivation 有权
    催化剂再活化聚合过程

    公开(公告)号：US20090312505A1

    公开(公告)日：2009-12-17

    申请号：US11990841

    申请日：2006-08-28

    Applicant: Krzysztof Matyjaszewski ,  Wojciech Jakubowski ,  James Spanswick

    Inventor： Krzysztof Matyjaszewski ,  Wojciech Jakubowski ,  James Spanswick

    IPC: C08F4/42

    CPC classification number: C08F2/40 ,  C08F4/04 ,  C08F4/40 ,  C08F212/08 ,  C08F212/10 ,  Y02P20/584 ,  C08F220/12

    Abstract: Polymerization processes of the present invention comprise low catalyst concentration. Embodiments include a polymerization process comprising polymerizing free radically (co)polymerizable monomers in a polymerization medium comprising one or more radically (co)polymerizable monomers, a transition metal catalyst complex capable of participating in a one electron redox reaction with an ATRP initiator; a free radical initiator; and an ATRP initiator; (wherein the concentration of transition metal catalyst complex in the polymerization medium is less than 100 ppm). Further embodiments include a polymerization process, comprising polymerizing one or more radically (co)polymerizable monomers in the presence of at least one transition metal catalyst complex; and an ATRP initiator; and a reducing agent; wherein the transition metal catalyst complex is present at less than 10″3 mole compared to the moles of radically transferable atoms or groups present on the ATRP initiator.

    Abstract translation: 本发明的聚合方法包括低催化剂浓度。 实施方案包括聚合方法，其包括在包含一种或多种自由基（共）可聚合单体的聚合介质中自由基（共）可聚合单体聚合，能够与ATRP引发剂参与一电子氧化还原反应的过渡金属催化剂络合物; 自由基引发剂; 和ATRP引发剂; （其中聚合介质中过渡金属催化剂配合物的浓度小于100ppm）。 另外的实施方案包括聚合方法，包括在至少一种过渡金属催化剂络合物的存在下聚合一种或多种自由基（共）可聚合单体; 和ATRP引发剂; 和还原剂; 其中与ATRP引发剂上存在的可自由基转移的原子或基团的摩尔数相比，过渡金属催化剂络合物的存在量小于10'3摩尔。

    Esterification of phenol catalyzed with a strong base plus boron
    5.
    发明授权
    Esterification of phenol catalyzed with a strong base plus boron 失效
    用强碱加硼催化苯酚酯化

    公开(公告)号：US4271311A

    公开(公告)日：1981-06-02

    申请号：US57198

    申请日：1979-07-13

    Applicant: William W. Knickmeyer ,  James Spanswick ,  James R. Stephens

    Inventor： William W. Knickmeyer ,  James Spanswick ,  James R. Stephens

    IPC: C07C67/08 ,  C07C69/773 ,  C07C69/035

    CPC classification number: C07C67/08

    Abstract: Esterification of phenolic compounds which comprises reacting a phenolic compound and a carboxylic acid using a catalyst consisting essentially of an alkali metal compound and a boron compound wherein said alkali metal compound is at least one member selected from the group consisting of alkali metal salts of boric acid, alkali metal polyborates, alkali metal hydroxides, and alkali metal borohydrides and said boron compound is at least one member selected from the group consisting of boric acid, boric anhydride, alkali metal polyborates, alkali metal salts of boric acid and alkali metal borohydrides.

    Abstract translation: 酚类化合物的酯化反应，其包括使用主要由碱金属化合物和硼化合物组成的催化剂使酚类化合物与羧酸反应，其中所述碱金属化合物是选自硼酸的碱金属盐中的至少一种 ，碱金属多硼酸盐，碱金属氢氧化物和碱金属硼氢化物，所述硼化合物是选自硼酸，硼酸酐，碱金属多硼酸盐，硼酸碱金属盐和碱金属硼氢化物中的至少一种。

    Translucent impact polystyrene
    6.
    发明授权
    Translucent impact polystyrene 失效
    TRANSLING IMPACT POLYSTYRENE

    公开(公告)号：US3957915A

    公开(公告)日：1976-05-18

    申请号：US573311

    申请日：1975-04-30

    Applicant: James Spanswick

    Inventor： James Spanswick

    IPC: C08F279/02 ,  C08L9/06

    CPC classification number: C08F279/02

    Abstract: Translucent rubber-modified styrene polymers are prepared by adding 0.005 to 0.5% of 1,2-dibromo-2-phenylpropane or methyl-2,3-dibromo-3-phenylpropionate to the polymerization feedstock.

    Atom transfer radical polymerization process
    8.
    发明授权
    Atom transfer radical polymerization process 有权
    原子转移自由基聚合过程

    公开(公告)号：US08404788B2

    公开(公告)日：2013-03-26

    申请号：US13026919

    申请日：2011-02-14

    Applicant: Krzysztof Matyjaszewski ,  Lindsay Bombalski ,  Wojciech Jakubowski ,  Ke Min ,  Nicolay V. Tsarevsky ,  James Spanswick

    Inventor： Krzysztof Matyjaszewski ,  Lindsay Bombalski ,  Wojciech Jakubowski ,  Ke Min ,  Nicolay V. Tsarevsky ,  James Spanswick

    IPC: C08F4/40

    CPC classification number: C08F265/04 ,  C08F4/40 ,  C08F220/18 ,  C08F265/00 ,  C08F291/00 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/01

    Abstract: Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprises reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.

    Abstract translation: 本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。 聚合介质可另外包含还原剂。 还原剂可以以连续或间歇的方式最初或在聚合过程中加入。 聚合方法可以进一步包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合过程的化合物。 本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

    Well Defined stars with segmented arms
    9.
    发明申请
    Well Defined stars with segmented arms 审中-公开
    定义明星与分段武器

    公开(公告)号：US20110263722A1

    公开(公告)日：2011-10-27

    申请号：US12799412

    申请日：2010-04-23

    Applicant: Wojciech Jakubowski ,  Patrick McCarthy ,  Nicolay Tsarevsky ,  James Spanswick

    Inventor： Wojciech Jakubowski ,  Patrick McCarthy ,  Nicolay Tsarevsky ,  James Spanswick

    IPC: C08F20/06 ,  A61K47/32

    CPC classification number: A61K47/32 ,  C08F293/005 ,  C08F2438/01

    Abstract: The present invention relates to the preparation and use of well defined star macromolecules wherein the composition of the arms are selected to induce self assembly when the multi-arm segmented star macromolecules are dispersed in a liquid. The self assembled star macromolecules modify the rheology of the dispersing media. When targeting use in aqueous based systems the inner shell of the star macromolecules comprise non-ionizable monomer units. Compositions comprising the self assemblable star macromolecules are suitable for use as rheology modifiers in a number of applications including cosmetic and personal care compositions.

    Abstract translation: 本发明涉及明确定义的星形大分子的制备和用途，其中当多臂分段的星形大分子分散在液体中时，选择臂的组成以诱导自组装。 自组装的星形大分子改变了分散介质的流变性。 当在含水系统中靶向时，星形大分子的内壳包含不可离子化的单体单元。 包含自组装星形大分子的组合物适用于许多应用中的流变改性剂，包括化妆品和个人护理组合物。

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