摘要:
An anode for a secondary battery capable of inserting and extracting a lithium ion having a multi-layered structure including a first anode layer containing carbon as a main component; a second anode layer made of a film-like material through which a lithium component passes; and a third anode layer containing lithium and/or a lithium-containing compound as a main component. The battery capacity of the lithium ion battery is substantially increased while the higher charge-discharge efficiency and the stable cycle performance are maintained.
摘要:
A lithium secondary battery in the present invention includes as a negative electrode a lithium alloy, lithium metal formed on a conductive substrate by vacuum film-forming, or the lithium metal having a hydrophobic material layer formed on a surface of an amorphous metallic lithium. Such a lithium secondary battery gives satisfaction with no dendrite formation and long cycle life.
摘要:
An anode with a multi-layer structure including a first layer (21) having carbon as a main component, and a second layer (22) having lithium-ion conductivity and including a material as a main component thereof which can insert and extract lithium ions, or a multi-layer structure including a third layer (23) containing lithium in addition to the first layer and the second layer, and a lithium secondary battery including the same. The lithium secondary battery can be provided in which the battery capacity is substantially enhanced in the voltage range where the battery is actually used while maintaining the higher charge-discharge efficiency and the excellent cycle performance.
摘要:
An object of the present invention is to provide a negative electrode for a secondary battery which has large capacity and restrains a rise in resistance inside the battery and reduction in capacity even after cycles and the secondary battery using the same. A first active material layer 2a comprising members occluding and releasing Li onto a collector 1a is formed and a second active material layer 3a as an alloy layer containing metal forming alloy with lithium or lithium and metal not-forming alloy with lithium is formed thereon. The secondary battery is constituted using the negative electrode.
摘要:
An object of the present invention is to provide a negative electrode for a secondary battery which has large capacity and restrains a rise in resistance inside the battery and reduction in capacity even after cycles and the secondary battery using the same. A first active material layer 2a comprising members occluding and releasing Li onto a collector 1a is formed and a second active material layer 3a as an alloy layer containing metal forming alloy with lithium or lithium and metal not-forming alloy with lithium is formed thereon. The secondary battery is constituted using the negative electrode.
摘要:
This invention relates to an anode for a secondary battery capable of occluding and releasing lithium ions, the anode having a multi-layer structure comprising: a first layer containing carbon as a main component; and a second layer as a main component containing a lithium-occluding material film, the film capable of occluding lithium more than a theoretical lithium-occlusion capacity for carbon, as well as a secondary battery using the anode. This invention can provide a secondary battery with a substantially improved battery capacity in a range where the battery is actually used, while having a higher charge-discharge efficiency and good cycle properties.
摘要:
A lithium ion secondary battery provided with both high weight energy density and good cycle characteristics (capacity retaining ratio during an extended use). A secondary battery comprising a negative electrode having, as a negative electrode active material, carbon and a lithium absorbing material that forms an alloy with lithium, the above active material having a layer structure, a positive electrode capable of absorbing and desorbing lithium ions, and an electrolyte disposed between the positive and negative electrodes, wherein the Li content in the lithium absorbing material layer in the negative electrode is between 31 and 67% at a discharge depth of 100%.
摘要:
A negative electrode for a rechargeable battery including: a current collector, a first layer containing a conductive material to occlude and release lithium ion, the first layer formed on the current collector, a second layer containing a metal selected from lithium and lithium alloy, the second layer formed on the first layer, and a third layer containing a lithium ion conductive material, the third layer formed on the second layer. The third layer prevents the lithium and/or the lithium alloy in the second layer from being in contact with the electrolyte and smoothly feeds the lithium to the second layer to improve the efficiency of the negative electrode. The first layer can occlude and release the part of the lithium to be occluded and released, thereby reducing the volume change of the second layer. Such a structure of the negative electrode enables us to enhance cycling efficiency, and to attain long cycle life and good safety.
摘要:
An anode with a multi-layer structure including a first layer (21) having carbon as a main component, and a second layer (22) having lithium-ion conductivity and including a material as a main component thereof which can insert and extract lithium ions, or a multi-layer structure including a third layer (23) containing lithium in addition to the first layer and the second layer, and a lithium secondary battery including the same. The lithium secondary battery can be provided in which the battery capacity is substantially enhanced in the voltage range where the battery is actually used while maintaining the higher charge-discharge efficiency and the excellent cycle performance.
摘要:
A lithium secondary cell has, on a conductive substrate (collector) a lithium layer containing metallic lithium or an alloy thereof, and further has a metal fluoride substance film containing at least one type metal fluoride substance.