摘要:
Process for preparing ethylene copolymers in the presence of free-radical polymerization initiator at pressures in the range of from 160 MPa to 350 MPa and temperatures in the range of from 100° C. to 350° C. in a tubular reactor by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers, wherein the bi- or multifunctional comonomer bears at least two different functional groups, of which at least one is a unsaturated group, which can be incorporated into the growing polymer chain, and at least another functional group can act as chain transfer agent in radical ethylene polymerization, ethylene copolymers obtainable by such a process, the use of the ethylene copolymers for extrusion coating and a process for extrusion coating a substrate selected from the group consisting of paper, paperboard, polymeric film, and metal, with such ethylene copolymers.
摘要:
New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5 s−1, at 150° C.), branching index g′ equal or lower than 0.9 (at Mw of 2·106 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100° C., for a time of at least 10 minutes.
摘要翻译:新的乙烯聚合物具有宽分子量分布和长链支化,首先是高分子量级分; 聚合物具有等于或高于1.4的应变硬化(在150s的恒定伸长率为0.5s -1,支化指数g'等于或等于0.9)(Mw为2·10 6 g / mol)。 通过使用包含基于具有三齿配体的后过渡金属组分的聚合催化剂和在高于100℃的温度下退火的齐格勒聚合催化剂至少10分钟的混合催化剂体系来制备聚合物 。
摘要:
Process for preparing ethylene copolymers in the presence of free-radical polymerization initiator at pressures in the range of from 160 MPa to 350 MPa and temperatures in the range of from 100° C. to 350° C. in a tubular reactor by copolymerizing ethylene, a bi- or multifunctional comonomer and optionally further comonomers, wherein the bi- or multifunctional comonomer bears at least two different functional groups, of which at least one is a unsaturated group, which can be incorporated into the growing polymer chain, and at least another functional group can act as chain transfer agent in radical ethylene polymerization, ethylene copolymers obtainable by such a process, the use of the ethylene copolymers for extrusion coating and a process for extrusion coating a substrate selected from the group consisting of paper, paperboard, polymeric film, and metal, with such ethylene copolymers.
摘要:
New ethylene polymers having broad molecular weight distribution and long-chain branching, above all at high molecular weight fractions; the polymers have strain hardening equal or higher than 1.4 (at constant elongational rate of 0.5 s−1, at 150° C.), branching index g′ equal or lower than 0.9 (at Mw of 2·106 g/mol). The polymers are prepared by using a mixed catalyst system comprising a polymerization catalyst based on a late transition metal component having a tridentate ligand, and a Ziegler polymerization catalyst annealed at a temperature higher than 100° C., for a time of at least 10 minutes.
摘要翻译:新的乙烯聚合物具有宽分子量分布和长链支化,首先是高分子量级分; 聚合物具有等于或高于1.4的应变硬化(在150s的恒定伸长率为0.5s -1,支化指数g'等于或等于0.9)(Mw为2·10 6 g / mol)。 通过使用包含基于具有三齿配体的后过渡金属组分的聚合催化剂和在高于100℃的温度下退火的齐格勒聚合催化剂至少10分钟的混合催化剂体系来制备聚合物 。