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公开(公告)号：US09206302B2
公开(公告)日：2015-12-08
申请号：US14005672
申请日：2012-03-21
IPC分类号： C08K13/02 , C08K5/04 , C08F299/04 , C08J3/24 , C08K3/00 , C08K5/00 , C08K5/05 , C08K5/14 , C08K5/16
CPC分类号： C08K13/02 , C08F299/04 , C08J3/241 , C08J3/248 , C08K3/11 , C08K5/0025 , C08K5/0091 , C08K5/04 , C08K5/05 , C08K5/14 , C08K5/16 , C08L67/06
摘要： Accelerator solution suitable for forming a redox system with peroxides, comprising (i) a compound of a first transition metal selected from manganese and copper, (ii) a compound of a second transition metal; the weight ratio of first transition metal:second transition metal being in the range 3:1 to 200:1, (iii) a nitrogen-containing base, and (iv) a hydroxy-functional solvent, with the proviso that the accelerator solution does not contain ascorbic acid.
摘要翻译： 适合于形成具有过氧化物的氧化还原体系的促进剂溶液，包括（i）选自锰和铜的第一过渡金属的化合物，（ii）第二过渡金属的化合物; 第一过渡金属：第二过渡金属的重量比在3:1至200:1的范围内，（iii）含氮碱，和（iv）羟基官能溶剂，条件是加速剂溶液 不含抗坏血酸。
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公开(公告)号：US20130211013A1
公开(公告)日：2013-08-15
申请号：US13704855
申请日：2011-06-14
申请人： Frederik Willem Karel Koers , Johannes Martinus Gerardus Maria Reijnders , Auke Gerardus Talma , Johannes Hermanus Ter Beek
发明人： Frederik Willem Karel Koers , Johannes Martinus Gerardus Maria Reijnders , Auke Gerardus Talma , Johannes Hermanus Ter Beek
IPC分类号： C08G63/83
CPC分类号： C08G63/83 , C08K5/0091 , C08L67/06 , C08L63/10
摘要： Solution suitable for accelerating the cure of a curable resin using a peroxide, said accelerator solution comprising (i) at least one organic solvent, (ii) a manganese salt, a copper salt, or a combination thereof, and (iii) an iron complex of a tetradentate, pentadentate or hexadentate nitrogen donor ligand.
摘要翻译： 所述促进剂溶液包含（i）至少一种有机溶剂，（ii）锰盐，铜盐或其组合，和（iii）铁络合物 的四齿，五齿或六齿氮供体配体。
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公开(公告)号：US20140005342A1
公开(公告)日：2014-01-02
申请号：US14005672
申请日：2012-03-21
CPC分类号： C08K13/02 , C08F299/04 , C08J3/241 , C08J3/248 , C08K3/11 , C08K5/0025 , C08K5/0091 , C08K5/04 , C08K5/05 , C08K5/14 , C08K5/16 , C08L67/06
摘要： Accelerator solution suitable for forming a redox system with peroxides, comprising (i) a compound of a first transition metal selected from manganese and copper, (ii) a compound of a second transition metal; the weight ratio of first transition metal:second transition metal being in the range 3:1 to 200:1, (iii) a nitrogen-containing base, and (iv) a hydroxy-functional solvent, with the proviso that the accelerator solution does not contain ascorbic acid.
摘要翻译： 适合于形成具有过氧化物的氧化还原体系的促进剂溶液，包括（i）选自锰和铜的第一过渡金属的化合物，（ii）第二过渡金属的化合物; 第一过渡金属：第二过渡金属的重量比在3:1至200:1的范围内，（iii）含氮碱，和（iv）羟基官能溶剂，条件是加速剂溶液 不含抗坏血酸。
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公开(公告)号：US09428631B2
公开(公告)日：2016-08-30
申请号：US14423197
申请日：2012-08-29
CPC分类号： C08K5/098 , C08K3/08 , C08K5/0025 , C08K5/0091 , C08K5/07 , C08K5/56 , C08K2003/0856 , C08L67/06
摘要： Accelerator solution suitable for forming a redox system with peroxides, comprising (i) an iron compound selected from iron carboxylates, iron 1,3-dioxo complexes, and iron dicylcopentadienyl complexes, (ii) a compound of a second transition metal; the weight ratio of iron:second transition metal being in the range 3:1 to 200:1, with the proviso that the accelerator solution is essentially free of ascorbic acid.
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公开(公告)号：US09034785B2
公开(公告)日：2015-05-19
申请号：US13704855
申请日：2011-06-14
申请人： Frederik Willem Karel Koers , Johannes Martinus Gerardus Maria Reijnders , Auke Gerardus Talma , Johannes Hermanus Ter Beek
发明人： Frederik Willem Karel Koers , Johannes Martinus Gerardus Maria Reijnders , Auke Gerardus Talma , Johannes Hermanus Ter Beek
CPC分类号： C08G63/83 , C08K5/0091 , C08L67/06 , C08L63/10
摘要： Solution suitable for accelerating the cure of a curable resin using a peroxide, said accelerator solution comprising (i) at least one organic solvent, (ii) a manganese salt, a copper salt, or a combination thereof, and (iii) an iron complex of a tetradentate, pentadentate or hexadentate nitrogen donor ligand.
摘要翻译： 所述促进剂溶液包含（i）至少一种有机溶剂，（ii）锰盐，铜盐或其组合，和（iii）铁络合物 的四齿，五齿或六齿氮供体配体。
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公开(公告)号：US20140011966A1
公开(公告)日：2014-01-09
申请号：US14005718
申请日：2012-03-21
IPC分类号： C08K13/02
CPC分类号： C08K13/02 , C08F299/04 , C08K5/0025 , C08K5/0091 , C08L67/06 , C08L67/08
摘要： Process for the preparation of an accelerator solution suitable for forming a redox system with peroxides, comprising the steps of heating a liquid formulation comprising a hydroxy-functional solvent and a nitrogen-containing base to a temperature in the range 50-200° C., followed by adding a transition metal salt or complex to said heated formulation.
摘要翻译： 用于制备适于用过氧化物形成氧化还原体系的促进剂溶液的方法，包括以下步骤：将包含羟基官能溶剂和含氮碱的液体制剂加热到50-200℃的温度， 然后向所述加热的配方中加入过渡金属盐或络合物。
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公开(公告)号：US20150203656A1
公开(公告)日：2015-07-23
申请号：US14423197
申请日：2012-08-29
CPC分类号： C08K5/098 , C08K3/08 , C08K5/0025 , C08K5/0091 , C08K5/07 , C08K5/56 , C08K2003/0856 , C08L67/06
摘要： Accelerator solution suitable for forming a redox system with peroxides, comprising (i) an iron compound selected from iron carboxylates, iron 1,3-dioxo complexes, and iron dicylcopentadienyl complexes, (ii) a compound of a second transition metal; the weight ratio of iron:second transition metal being in the range 3:1 to 200:1, with the proviso that the accelerator solution is essentially free of ascorbic acid.
摘要翻译： 适合于形成具有过氧化物的氧化还原体系的促进剂溶液，其包含（i）选自铁羧酸盐，铁1,3-二氧杂络合物和铁二甲基戊二烯基络合物的铁化合物，（ii）第二过渡金属化合物; 铁：第二过渡金属的重量比在3:1至200:1的范围内，条件是促进剂溶液基本上不含抗坏血酸。
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公开(公告)号：US08366960B2
公开(公告)日：2013-02-05
申请号：US12594067
申请日：2008-04-10
IPC分类号： C08F4/34
CPC分类号： C08K5/14 , C07C407/006 , C08F4/32 , C07C409/32
摘要： The invention pertains to a peroxide composition comprising, based on the total weight of the composition: a) 10-90 wt % of an organic peroxide; b) 90-10 wt % of an organic solvent in which the organic peroxide does not dissolve; and c) optionally additives; wherein the water content is less than 20 wt %.
摘要翻译： 本发明涉及一种过氧化物组合物，其包含基于组合物的总重量：a）10-90重量％的有机过氧化物; b）90-10重量％有机过氧化物不溶解的有机溶剂; 和c）任选的添加剂; 其中水含量小于20重量％。
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公开(公告)号：US09255196B2
公开(公告)日：2016-02-09
申请号：US14005697
申请日：2012-03-21
IPC分类号： C08K5/05 , C08K5/16 , C08K5/49 , C08K13/02 , C08L67/06 , C08L67/08 , C08G63/91 , C08G63/698 , C08K3/00 , C08K5/14 , C08F299/04 , C08J3/24 , C08K5/00
CPC分类号： C08K13/02 , C08F299/04 , C08J3/241 , C08J3/248 , C08K3/11 , C08K5/0025 , C08K5/0091 , C08K5/05 , C08K5/14 , C08K5/16 , C08K5/49 , C08L67/06
摘要： Accelerator solution suitable for forming a redox system with peroxides, comprising a Cu(I) compound, a transition metal selected from cobalt and titanium, a phosphorous-containing compound, a nitrogen-containing base, and a hydroxy-functional solvent.
摘要翻译： 包含Cu（I）化合物，选自钴和钛的过渡金属，含磷化合物，含氮碱和羟基官能溶剂的适用于形成具有过氧化物的氧化还原体系的促进剂溶液。
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公开(公告)号：US20080207841A1
公开(公告)日：2008-08-28
申请号：US11916077
申请日：2006-05-24
CPC分类号： C08F299/00 , C08F2/42 , C08F4/40
摘要： Accelerator solution suitable for forming a redox system with peroxides and having a high storage stability, consisting essentially of (a) more than 1.0 wt % of one or more reducing agents, at least one of them being selected from ascorbic acid and sodium formaldehyde sulphoxylate, (b) one or more metal salts, at least one of them being selected from the group consisting of transition metal salts, lithium salts, and magnesium salts, (c) one or more organic oxygen-containing solvents, (d) optionally one or more stabilisers, and (e) optionally water.
摘要翻译： 适用于形成具有过氧化物并具有高储存稳定性的氧化还原体系的加速剂溶液，其基本上由（a）大于1.0重量％的一种或多种还原剂组成，其中至少一种选自抗坏血酸和甲醛磺酸钠， （b）一种或多种金属盐，其中至少一种选自过渡金属盐，锂盐和镁盐，（c）一种或多种有机含氧溶剂，（d）任选的一种或 更多的稳定剂，和（e）任选的水。
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