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    Integrated process for the production of tame
    1.
    发明授权
    Integrated process for the production of tame 失效
    整合生产温驯的过程

    公开(公告)号：US5792891A

    公开(公告)日：1998-08-11

    申请号：US792980

    申请日：1997-02-03

    申请人： John R. Adams ,  Lawrence A. Smith, Jr. ,  Dennis Hearn ,  Edward M. Jones, Jr. ,  Robert P. Arganbright

    发明人： John R. Adams ,  Lawrence A. Smith, Jr. ,  Dennis Hearn ,  Edward M. Jones, Jr. ,  Robert P. Arganbright

    IPC分类号： B01D3/00 ,  B01D3/14 ,  C07C41/06 ,  C07C41/42

    CPC分类号： C07C41/06 ,  B01D3/009 ,  B01D3/146 ,  C07C41/42 ,  Y02P20/125 ,  Y02P20/127

    摘要： An alkene skeletal isomerization process is employed in an integrated process for the production of tertiary ether, e.g., tertiary amyl methyl ether (TAME) from the reaction of isoamylenes (iC.sub.5.sup.= 's) with methanol in the presence of an acid cation exchange resin. A light naphtha from a fluid catalytic cracking unit is used as the source of the iC.sub.5.sup.= 's in a process which separates the C.sub.5 containing fraction from the light naphtha, selectively hydrogenates the di-olefins contained in the C.sub.5 containing fraction, reacts the iC.sub.5.sup.= 's contained in the C.sub.5 containing fraction with methanol to form TAME, separates the TAME from the unreacted materials as a product, separates methanol from the unreacted materials, isomerizes a portion of the nC.sub.5.sup.= 's to iC.sub.5.sup.= 's , for example using a zeolite or an alumina treated with methanol, and use of the isomerization product as feed for a TAME reactor.

    摘要翻译： 烯烃骨架异构化方法用于在酸性阳离子交换树脂存在下，从异戊烯（iC5 = s）与甲醇的反应生产叔醚如叔戊基甲基醚（TAME）的一体化方法中。 在将含C5馏分与轻石脑油分离的方法中，使用来自流化催化裂化装置的轻石脑油作为iC5 =的来源，选择性地氢化含C5馏分中所含的二烯烃，使iC5 包含在含甲醇的馏分中形成TAME，将TAME与未反应的物质作为产物分离，从未反应的物质中分离出甲醇，将nC5 =的一部分异构化为iC5 =，例如 使用沸石或用甲醇处理的氧化铝，并使用异构化产物作为TAME反应器的进料。

    Reformate benzene reduction via alkylation
    5.
    发明授权
    Reformate benzene reduction via alkylation 有权
    通过烷基化改性苯还原

    公开(公告)号：US08101810B2

    公开(公告)日：2012-01-24

    申请号：US12195118

    申请日：2008-08-20

    申请人： Christopher C. Boyer ,  Lawrence A. Smith, Jr. ,  Arvids Judzis, Jr. ,  John R. Adams

    发明人： Christopher C. Boyer ,  Lawrence A. Smith, Jr. ,  Arvids Judzis, Jr. ,  John R. Adams

    IPC分类号： C07C2/52

    CPC分类号： C07C2/66 ,  Y02P20/127 ,  C07C15/085 ,  C07C15/02

    摘要： A process for reformate benzene reduction, the process including: feeding a light reformate fraction, an olefin feed, and an alkylation catalyst to an alkylation reaction zone; contacting the light reformate fraction and the olefin feed in the presence of the alkylation catalyst in the alkylation reaction zone to convert at least a portion of the benzene and the olefin to a monoalkylate; recovering a catalyst fraction from an alkylation reaction zone effluent; and recovering a light reformate product having a reduced benzene content.

    摘要翻译： 一种重整苯还原的方法，该方法包括：将轻质重整油馏分，烯烃进料和烷基化催化剂进料至烷基化反应区; 在烷基化反应区中在烷基化催化剂存在下使轻重整油馏分和烯烃进料接触，将至少一部分苯和烯烃转化成单烷基化物; 从烷基化反应区流出物回收催化剂级分; 并回收苯含量降低的轻质重整产物。

    REFORMATE BENZENE REDUCTION VIA ALKYLATION
    7.
    发明申请
    REFORMATE BENZENE REDUCTION VIA ALKYLATION 有权
    通过烷基化改性降低苯并噻吩

    公开(公告)号：US20100048970A1

    公开(公告)日：2010-02-25

    申请号：US12195118

    申请日：2008-08-20

    申请人： Christopher C. Boyer ,  Lawrence A. Smith, JR. ,  Arvids Judzis, JR. ,  John R. Adams

    发明人： Christopher C. Boyer ,  Lawrence A. Smith, JR. ,  Arvids Judzis, JR. ,  John R. Adams

    IPC分类号： C07C2/64

    CPC分类号： C07C2/66 ,  Y02P20/127 ,  C07C15/085 ,  C07C15/02

    摘要： A process for reformate benzene reduction, the process including: feeding a light reformate fraction, an olefin feed, and an alkylation catalyst to an alkylation reaction zone; contacting the light reformate fraction and the olefin feed in the presence of the alkylation catalyst in the alkylation reaction zone to convert at least a portion of the benzene and the olefin to a monoalkylate; recovering a catalyst fraction from an alkylation reaction zone effluent; and recovering a light reformate product having a reduced benzene content.

    摘要翻译： 一种重整苯还原的方法，该方法包括：将轻质重整油馏分，烯烃进料和烷基化催化剂进料至烷基化反应区; 在烷基化反应区中在烷基化催化剂存在下使轻重整油馏分和烯烃进料接触，将至少一部分苯和烯烃转化成单烷基化物; 从烷基化反应区流出物回收催化剂级分; 并回收苯含量降低的轻质重整产物。

    Paraffin alkylation
    8.
    发明授权
    Paraffin alkylation 有权
    石蜡烷基化

    公开(公告)号：US06858770B2

    公开(公告)日：2005-02-22

    申请号：US10219877

    申请日：2002-08-15

    申请人： Lawrence A. Smith, Jr. ,  Mitchell E. Loescher ,  John R. Adams ,  Abraham P. Gelbein

    发明人： Lawrence A. Smith, Jr. ,  Mitchell E. Loescher ,  John R. Adams ,  Abraham P. Gelbein

    IPC分类号： B01J27/053 ,  B01J35/12 ,  C07C2/06 ,  C07C2/54 ,  C07C2/56 ,  C07C2/58 ,  C07C2/62 ,  C10G35/04 ,  C10G50/00 ,  C10G63/02

    CPC分类号： C07C2/62 ,  C07C11/02 ,  C07C2527/054 ,  C10G29/205 ,  C10G2300/1081 ,  C10G2300/1088

    摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.

    摘要翻译： 一种烷烃与烯烃或烯烃前体烷基化的方法，例如叔烯烃的低聚物，包括使含有酸催化剂，异链烷烃和烯烃的液体体系同时向下流动，在温度和压力条件下在分散网中与反应区接触 使所述异链烷烃和所述烯烃反应生成烷基化物产物。 优选地，液体系统保持在反应区域的大约沸点。 出乎意料地，已经发现烯烃低聚物作为烯烃前体而不是反应中的烯烃。 因此，例如，使用异丁烯（主要是二聚体和三聚体）的低聚物与异丁烷的冷酸烷基化产生异辛烷，异丁烷与摩尔的低聚物的组分异丁烯单元反应。 产物异辛烷基本上与常规冷酸法中产生的相同。

    Paraffin alkylation
    9.
    发明授权
    Paraffin alkylation 有权
    石蜡烷基化

    公开(公告)号：US07250542B2

    公开(公告)日：2007-07-31

    申请号：US10793028

    申请日：2004-03-04

    申请人： Lawrence A. Smith, Jr. ,  Mitchell E. Loescher ,  John R. Adams ,  Abraham P. Gelbein

    发明人： Lawrence A. Smith, Jr. ,  Mitchell E. Loescher ,  John R. Adams ,  Abraham P. Gelbein

    IPC分类号： C07C6/00 ,  C07C2/58 ,  C07C2/62

    CPC分类号： C07C2/62 ,  C07C11/02 ,  C07C2527/054 ,  C10G29/205 ,  C10G2300/1081 ,  C10G2300/1088

    摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.

    摘要翻译： 一种烷烃与烯烃或烯烃前体烷基化的方法，例如叔烯烃的低聚物，包括使含有酸催化剂，异链烷烃和烯烃的液体体系同时向下流动，在温度和压力条件下在分散网中与反应区接触 使所述异链烷烃和所述烯烃反应生成烷基化物产物。 优选地，液体系统保持在反应区域的大约沸点。 出乎意料地，已经发现烯烃低聚物作为烯烃前体而不是反应中的烯烃。 因此，例如，使用异丁烯（主要是二聚体和三聚体）的低聚物与异丁烷的冷酸烷基化产生异辛烷，异丁烷与摩尔的低聚物的组分异丁烯单元反应。 产物异辛烷基本上与常规冷酸法中产生的相同。

    Paraffin alkylation
    10.
    发明授权
    Paraffin alkylation 有权

    公开(公告)号：US06995296B2

    公开(公告)日：2006-02-07

    申请号：US10870104

    申请日：2004-06-17

    申请人： Lawrence A. Smith, Jr. ,  Mitchell E. Loescher ,  John R. Adams ,  Abraham P. Gelbein

    发明人： Lawrence A. Smith, Jr. ,  Mitchell E. Loescher ,  John R. Adams ,  Abraham P. Gelbein

    IPC分类号： C07C2/62

    CPC分类号： C07C2/62 ,  C07C11/02 ,  C07C2527/054 ,  C10G29/205 ,  C10G2300/1081 ,  C10G2300/1088

    摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.