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公开(公告)号：US20100317895A1
公开(公告)日：2010-12-16
申请号：US12747295
申请日：2009-01-13
CPC分类号： C07C409/14 , C07C13/28 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C49/08 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2:1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.
摘要翻译： 在生产环己基苯的方法中，将氢和含苯的液体原料引入反应区，并在加氢烷基化条件下在反应区中接触以制备环己基苯。 将包含环己基苯和未反应苯的流出物流从反应区除去，并分成至少第一和第二部分，其中流出物流第一部分与流出物流第二部分的质量比至少为2:1。 然后将流出物流第一部分冷却，将冷却的流出物流第一部分再循环至反应区。
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公开(公告)号：US08084648B2
公开(公告)日：2011-12-27
申请号：US12747295
申请日：2009-01-13
CPC分类号： C07C409/14 , C07C13/28 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C49/08 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2:1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.
摘要翻译： 在生产环己基苯的方法中，将氢和含苯的液体原料引入反应区，并在加氢烷基化条件下在反应区中接触以制备环己基苯。 将包含环己基苯和未反应苯的流出物流从反应区除去，并分成至少第一和第二部分，其中流出物流第一部分与流出物流第二部分的质量比至少为2:1。 然后将流出物流第一部分冷却，将冷却的流出物流第一部分再循环至反应区。
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公开(公告)号：US08519194B2
公开(公告)日：2013-08-27
申请号：US13145007
申请日：2009-11-24
CPC分类号： B01J29/7676 , B01J29/7476 , C07C2/76 , Y02P20/52 , C07C13/28
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone comprising a catalyst system which comprises a molecular sieve and at least one hydrogenation metal. The MCM-22 family molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and the hydrogenation metal is selected from the group consisting of palladium, ruthenium, nickel, zinc, tin, cobalt, and combinations of any two or more thereof. Hydroalkylation conditions of temperature and pressure are selected to produce a hydroalkylation conversion in a range of from about 15% to about 75% The benzene and hydrogen are then contacted in the at least one reaction zone under said selected hydroalkylation condition to produce an effluent containing cyclohexylbenzene.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个包含催化剂体系的反应区，该催化剂体系包含分子筛和至少一种氢化金属。 具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值的X射线衍射图的MCM-22族分子筛，氢化金属选自钯， 钌，镍，锌，锡，钴及其任何两种或更多种的组合。 选择温度和压力的烷基化条件以产生约15％至约75％的加氢烷基转化率。然后在所述选择的加氢烷基化条件下，使苯和氢在至少一个反应区中接触，以产生含有环己基苯 。
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公开(公告)号：US20110288341A1
公开(公告)日：2011-11-24
申请号：US13145007
申请日：2009-11-24
CPC分类号： B01J29/7676 , B01J29/7476 , C07C2/76 , Y02P20/52 , C07C13/28
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone comprising a catalyst system which comprises a molecular sieve and at least one hydrogenation metal. The MCM-22 family molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and the hydrogenation metal is selected from the group consisting of palladium, ruthenium, nickel, zinc, tin, cobalt, and combinations of any two or more thereof Hydroalkylation conditions of temperature and pressure are selected to produce a hydroalkylation conversion in a range of from about 15% to about 75% The benzene and hydrogen are then contacted in the at least one reaction zone under said selected hydroalkylation condition to produce an effluent containing cyclohexylbenzene.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个包含催化剂体系的反应区，该催化剂体系包含分子筛和至少一种氢化金属。 具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值的X射线衍射图的MCM-22族分子筛，氢化金属选自钯， 钌，镍，锌，锡，钴及其任何两种或更多种的组合选择温度和压力的压缩烷基化条件以产生约15％至约75％的加氢烷基转化率。然后将苯和氢气接触 在所述选择的加氢烷基化条件下的至少一个反应区中，以产生含有环己基苯的流出物。
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公开(公告)号：US20110152577A1
公开(公告)日：2011-06-23
申请号：US13060773
申请日：2009-08-04
CPC分类号： C07C7/163 , C07C2/66 , C07C7/14891 , C07C37/08 , C07C37/20 , C07C45/53 , C07C407/00 , C07C409/08 , C07C2529/70 , Y02P20/127 , C07C15/02 , C07C11/08 , C07C49/10 , C07C39/04 , C07C39/16
摘要： In a process for producing sec-butylbenzene, a C4 olefinic hydrocarbon feedstock comprising isobutene and at least one n-butene is contacted with methanol and/or water in the presence of an acid catalyst to selectively oxygenate isobutene to produce an effluent stream rich in n-butene and containing less isobutene than the feedstock. The effluent stream is then contacted with benzene under alkylation conditions and in the presence of an alkylation catalyst to produce alkylation stream comprising sec-butylbenzene.
摘要翻译： 在制备仲丁基苯的方法中，包含异丁烯和至少一个正丁烯的C 4烯烃原料在酸催化剂的存在下与甲醇和/或水接触以选择性地使异丁烯氧化以产生富含n 并且含有比原料少的异丁烯。 然后在烷基化条件下和在烷基化催化剂的存在下将流出物流与苯接触以产生包含仲丁基苯的烷基化流。
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公开(公告)号：US08440864B2
公开(公告)日：2013-05-14
申请号：US13060773
申请日：2009-08-04
CPC分类号： C07C7/163 , C07C2/66 , C07C7/14891 , C07C37/08 , C07C37/20 , C07C45/53 , C07C407/00 , C07C409/08 , C07C2529/70 , Y02P20/127 , C07C15/02 , C07C11/08 , C07C49/10 , C07C39/04 , C07C39/16
摘要： In a process for producing sec-butylbenzene, a C4 olefinic hydrocarbon feedstock comprising isobutene and at least one n-butene is contacted with methanol and/or water in the presence of an acid catalyst to selectively oxygenate isobutene to produce an effluent stream rich in n-butene and containing less isobutene than the feedstock. The effluent stream is then contacted with benzene under alkylation conditions and in the presence of an alkylation catalyst to produce alkylation stream comprising sec-butylbenzene.
摘要翻译： 在制备仲丁基苯的方法中，包含异丁烯和至少一个正丁烯的C 4烯烃原料在酸催化剂的存在下与甲醇和/或水接触以选择性地使异丁烯氧化以产生富含n 并且含有比原料少的异丁烯。 然后在烷基化条件下和在烷基化催化剂的存在下将流出物流与苯接触以产生包含仲丁基苯的烷基化流。
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公开(公告)号：US08106243B2
公开(公告)日：2012-01-31
申请号：US12933709
申请日：2009-02-23
CPC分类号： C07C37/06 , C07C2/74 , C07C6/126 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted with a catalyst under hydroalkylation conditions to produce an effluent containing cyclohexylbenzene. The catalyst comprises a composite of a molecular sieve, an inorganic oxide different from said molecular sieve and at least one hydrogenation metal, wherein at least 50 wt % of said hydrogenation metal is supported on the inorganic oxide and the inorganic oxide has an average particle size less than 40 μm (microns).
摘要翻译： 在生产环己基苯的方法中，苯和氢在加氢烷基化条件下与催化剂接触以产生含有环己基苯的流出物。 催化剂包括分子筛，不同于所述分子筛的无机氧化物和至少一种氢化金属的复合物，其中至少50重量％的所述氢化金属负载在无机氧化物上，无机氧化物具有平均粒度 小于40μm（微米）。
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公开(公告)号：US20110028762A1
公开(公告)日：2011-02-03
申请号：US12904215
申请日：2010-10-14
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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公开(公告)号：US20100179351A1
公开(公告)日：2010-07-15
申请号：US12663303
申请日：2008-08-12
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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公开(公告)号：US08329956B2
公开(公告)日：2012-12-11
申请号：US13409331
申请日：2012-03-01
申请人： Jane C. Cheng , Tan-Jen Chen , Prasenjeet Ghosh
发明人： Jane C. Cheng , Tan-Jen Chen , Prasenjeet Ghosh
IPC分类号： C07C45/27 , C07C27/08 , C07C2/68 , C07C15/067
CPC分类号： B01J29/7088 , B01J21/04 , B01J23/44 , B01J29/7476 , B01J29/7676 , B01J35/0006 , B01J37/0009 , B01J2229/42 , C07C2/74 , C07C6/126 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2521/06 , C07C2523/44 , C07C2529/74 , C07C2529/76 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted under hydroalkylation conditions with a catalyst system comprising a MCM-22 family molecular sieve and at least one hydrogenation metal. The conditions comprise a temperature of about 140° C. to about 175° C., a pressure of about 135 psig to about 175 psig (931 kPag to 1207 kPag), a hydrogen to benzene molar ratio of about 0.30 to about 0.65 and a weight hourly space velocity of benzene of about 0.26 to about 1.05 hr−1.
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