Process For Producing Cyclohexylbenzene
    1.
    发明申请
    Process For Producing Cyclohexylbenzene 有权
    生产环己基苯的方法

    公开(公告)号:US20100317895A1

    公开(公告)日:2010-12-16

    申请号:US12747295

    申请日:2009-01-13

    IPC分类号: C07C45/00 C07C2/66

    摘要: In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2:1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.

    摘要翻译: 在生产环己基苯的方法中,将氢和含苯的液体原料引入反应区,并在加氢烷基化条件下在反应区中接触以制备环己基苯。 将包含环己基苯和未反应苯的流出物流从反应区除去,并分成至少第一和第二部分,其中流出物流第一部分与流出物流第二部分的质量比至少为2:1。 然后将流出物流第一部分冷却,将冷却的流出物流第一部分再循环至反应区。

    Process for producing cyclohexylbenzene
    2.
    发明授权
    Process for producing cyclohexylbenzene 有权
    生产环己基苯的方法

    公开(公告)号:US08084648B2

    公开(公告)日:2011-12-27

    申请号:US12747295

    申请日:2009-01-13

    IPC分类号: C07C45/53 C07C37/08 C07C2/68

    摘要: In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2:1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.

    摘要翻译: 在生产环己基苯的方法中,将氢和含苯的液体原料引入反应区,并在加氢烷基化条件下在反应区中接触以制备环己基苯。 将包含环己基苯和未反应苯的流出物流从反应区除去,并分成至少第一和第二部分,其中流出物流第一部分与流出物流第二部分的质量比至少为2:1。 然后将流出物流第一部分冷却,将冷却的流出物流第一部分再循环至反应区。

    Process for producing cyclohexylbenzene
    5.
    发明授权
    Process for producing cyclohexylbenzene 有权
    生产环己基苯的方法

    公开(公告)号:US08519194B2

    公开(公告)日:2013-08-27

    申请号:US13145007

    申请日:2009-11-24

    摘要: In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone comprising a catalyst system which comprises a molecular sieve and at least one hydrogenation metal. The MCM-22 family molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and the hydrogenation metal is selected from the group consisting of palladium, ruthenium, nickel, zinc, tin, cobalt, and combinations of any two or more thereof. Hydroalkylation conditions of temperature and pressure are selected to produce a hydroalkylation conversion in a range of from about 15% to about 75% The benzene and hydrogen are then contacted in the at least one reaction zone under said selected hydroalkylation condition to produce an effluent containing cyclohexylbenzene.

    摘要翻译: 在生产环己基苯的方法中,将苯和氢气进料至至少一个包含催化剂体系的反应区,该催化剂体系包含分子筛和至少一种氢化金属。 具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值的X射线衍射图的MCM-22族分子筛,氢化金属选自钯, 钌,镍,锌,锡,钴及其任何两种或更多种的组合。 选择温度和压力的烷基化条件以产生约15%至约75%的加氢烷基转化率。然后在所述选择的加氢烷基化条件下,使苯和氢在至少一个反应区中接触,以产生含有环己基苯 。

    Process For Producing Cyclohexylbenzene
    6.
    发明申请
    Process For Producing Cyclohexylbenzene 有权
    生产环己基苯的方法

    公开(公告)号:US20110288341A1

    公开(公告)日:2011-11-24

    申请号:US13145007

    申请日:2009-11-24

    IPC分类号: C07C45/60 C07C2/74

    摘要: In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone comprising a catalyst system which comprises a molecular sieve and at least one hydrogenation metal. The MCM-22 family molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and the hydrogenation metal is selected from the group consisting of palladium, ruthenium, nickel, zinc, tin, cobalt, and combinations of any two or more thereof Hydroalkylation conditions of temperature and pressure are selected to produce a hydroalkylation conversion in a range of from about 15% to about 75% The benzene and hydrogen are then contacted in the at least one reaction zone under said selected hydroalkylation condition to produce an effluent containing cyclohexylbenzene.

    摘要翻译: 在生产环己基苯的方法中,将苯和氢气进料至至少一个包含催化剂体系的反应区,该催化剂体系包含分子筛和至少一种氢化金属。 具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值的X射线衍射图的MCM-22族分子筛,氢化金属选自钯, 钌,镍,锌,锡,钴及其任何两种或更多种的组合选择温度和压力的压缩烷基化条件以产生约15%至约75%的加氢烷基转化率。然后将苯和氢气接触 在所述选择的加氢烷基化条件下的至少一个反应区中,以产生含有环己基苯的流出物。