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公开(公告)号:US20100317895A1
公开(公告)日:2010-12-16
申请号:US12747295
申请日:2009-01-13
CPC分类号: C07C409/14 , C07C13/28 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C49/08 , C07C39/04
摘要: In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2:1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.
摘要翻译: 在生产环己基苯的方法中,将氢和含苯的液体原料引入反应区,并在加氢烷基化条件下在反应区中接触以制备环己基苯。 将包含环己基苯和未反应苯的流出物流从反应区除去,并分成至少第一和第二部分,其中流出物流第一部分与流出物流第二部分的质量比至少为2:1。 然后将流出物流第一部分冷却,将冷却的流出物流第一部分再循环至反应区。
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公开(公告)号:US08084648B2
公开(公告)日:2011-12-27
申请号:US12747295
申请日:2009-01-13
CPC分类号: C07C409/14 , C07C13/28 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C49/08 , C07C39/04
摘要: In a process for producing cyclohexylbenzene, hydrogen and a liquid feed comprising benzene are introduced into a reaction zone and are contacted in the reaction zone under hydroalkylation conditions to produce cyclohexylbenzene. An effluent stream comprising cyclohexylbenzene and unreacted benzene is removed from the reaction zone and is divided into at least first and second portions, wherein the mass ratio of the effluent stream first portion to the effluent stream second portion is at least 2:1. The effluent stream first portion is then cooled and the cooled effluent stream first portion is recycled to the reaction zone.
摘要翻译: 在生产环己基苯的方法中,将氢和含苯的液体原料引入反应区,并在加氢烷基化条件下在反应区中接触以制备环己基苯。 将包含环己基苯和未反应苯的流出物流从反应区除去,并分成至少第一和第二部分,其中流出物流第一部分与流出物流第二部分的质量比至少为2:1。 然后将流出物流第一部分冷却,将冷却的流出物流第一部分再循环至反应区。
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公开(公告)号:US20110105805A1
公开(公告)日:2011-05-05
申请号:US12996219
申请日:2009-07-14
IPC分类号: C07C37/08
CPC分类号: C07C37/06 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要: In a process for producing phenol, cyclohexylbenzene is oxidized to produce cyclohexylbenzene hydroperoxide and then the resultant cyclohexylbenzene hydroperoxide is cleaved to produce an effluent stream comprising phenol and cyclohexanone. At least a portion of the effluent stream is then fed to at least one dehydrogenation reaction zone, where the effluent stream portion is contacted with a dehydrogenation catalyst under conditions effective to convert at least part of the cyclohexanone in the effluent portion into phenol and hydrogen.
摘要翻译: 在生产苯酚的方法中,将环己基苯氧化生产环己基苯氢过氧化物,然后将所得的环己基苯氢过氧化物切割以产生包含苯酚和环己酮的流出物流。 然后将至少一部分流出物流送入至少一个脱氢反应区,其中流出物流部分与脱氢催化剂在有效地将流出物部分中的至少一部分环己酮转化为酚和氢的条件下接触。
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公开(公告)号:US08487140B2
公开(公告)日:2013-07-16
申请号:US12996219
申请日:2009-07-14
CPC分类号: C07C37/06 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要: In a process for producing phenol, cyclohexylbenzene is oxidized to produce cyclohexylbenzene hydroperoxide and then the resultant cyclohexylbenzene hydroperoxide is cleaved to produce an effluent stream comprising phenol and cyclohexanone. At least a portion of the effluent stream is then fed to at least one dehydrogenation reaction zone, where the effluent stream portion is contacted with a dehydrogenation catalyst under conditions effective to convert at least part of the cyclohexanone in the effluent portion into phenol and hydrogen.
摘要翻译: 在生产苯酚的方法中,将环己基苯氧化生产环己基苯氢过氧化物,然后将所得的环己基苯氢过氧化物切割以产生包含苯酚和环己酮的流出物流。 然后将至少一部分流出物流送入至少一个脱氢反应区,其中流出物流部分与脱氢催化剂在有效地将流出物部分中的至少一部分环己酮转化为酚和氢的条件下接触。
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公开(公告)号:US08519194B2
公开(公告)日:2013-08-27
申请号:US13145007
申请日:2009-11-24
CPC分类号: B01J29/7676 , B01J29/7476 , C07C2/76 , Y02P20/52 , C07C13/28
摘要: In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone comprising a catalyst system which comprises a molecular sieve and at least one hydrogenation metal. The MCM-22 family molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and the hydrogenation metal is selected from the group consisting of palladium, ruthenium, nickel, zinc, tin, cobalt, and combinations of any two or more thereof. Hydroalkylation conditions of temperature and pressure are selected to produce a hydroalkylation conversion in a range of from about 15% to about 75% The benzene and hydrogen are then contacted in the at least one reaction zone under said selected hydroalkylation condition to produce an effluent containing cyclohexylbenzene.
摘要翻译: 在生产环己基苯的方法中,将苯和氢气进料至至少一个包含催化剂体系的反应区,该催化剂体系包含分子筛和至少一种氢化金属。 具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值的X射线衍射图的MCM-22族分子筛,氢化金属选自钯, 钌,镍,锌,锡,钴及其任何两种或更多种的组合。 选择温度和压力的烷基化条件以产生约15%至约75%的加氢烷基转化率。然后在所述选择的加氢烷基化条件下,使苯和氢在至少一个反应区中接触,以产生含有环己基苯 。
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公开(公告)号:US20110288341A1
公开(公告)日:2011-11-24
申请号:US13145007
申请日:2009-11-24
CPC分类号: B01J29/7676 , B01J29/7476 , C07C2/76 , Y02P20/52 , C07C13/28
摘要: In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone comprising a catalyst system which comprises a molecular sieve and at least one hydrogenation metal. The MCM-22 family molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and the hydrogenation metal is selected from the group consisting of palladium, ruthenium, nickel, zinc, tin, cobalt, and combinations of any two or more thereof Hydroalkylation conditions of temperature and pressure are selected to produce a hydroalkylation conversion in a range of from about 15% to about 75% The benzene and hydrogen are then contacted in the at least one reaction zone under said selected hydroalkylation condition to produce an effluent containing cyclohexylbenzene.
摘要翻译: 在生产环己基苯的方法中,将苯和氢气进料至至少一个包含催化剂体系的反应区,该催化剂体系包含分子筛和至少一种氢化金属。 具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃的d间距最大值的X射线衍射图的MCM-22族分子筛,氢化金属选自钯, 钌,镍,锌,锡,钴及其任何两种或更多种的组合选择温度和压力的压缩烷基化条件以产生约15%至约75%的加氢烷基转化率。然后将苯和氢气接触 在所述选择的加氢烷基化条件下的至少一个反应区中,以产生含有环己基苯的流出物。
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公开(公告)号:US20140187821A1
公开(公告)日:2014-07-03
申请号:US13989903
申请日:2011-10-25
申请人: Kun Wang , Jihad M. Dakka , Stephen Zushma , James R. Lattner , Christopher L. Becker , Tan-Jen Chen
发明人: Kun Wang , Jihad M. Dakka , Stephen Zushma , James R. Lattner , Christopher L. Becker , Tan-Jen Chen
CPC分类号: C07C2/74 , C07C37/08 , C07C45/53 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要: In a process for producing a cycloalkylaromatic compound, an aromatic compound and a cyclic olefin are contacted with a first catalyst under conditions effective to produce a reaction product comprising the cycloalkylaromatic compound and at least one non-fused bicyclic by-product. The at least one non-fused bicyclic by-product is then contacted with a second catalyst under conditions effective to convert at least a portion of the at least one non-fused bicyclic by-product to a converted by-product.
摘要翻译: 在制备环烷基芳族化合物的方法中,芳族化合物和环状烯烃在有效产生包含环烷基芳族化合物和至少一种非稠合双环副产物的反应产物的条件下与第一催化剂接触。 然后至少一种非稠合双环副产物在有效将至少一部分非稠合双环副产物转化为转化副产物的条件下与第二催化剂接触。
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公开(公告)号:US09024078B2
公开(公告)日:2015-05-05
申请号:US13515104
申请日:2010-12-17
申请人: Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
发明人: Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
IPC分类号: C07C37/08 , C07C5/32 , C07C37/07 , C07C45/53 , C07C407/00
CPC分类号: C07C37/08 , B01J23/58 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/0203 , C07C5/367 , C07C37/07 , C07C45/53 , C07C407/00 , C07C2521/08 , C07C2523/42 , C07C2523/58 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C15/04
摘要: A dehydrogenation process for the dehydrogenation of at least one dehydrogenatable hydrocarbon, the process comprising contacting a feed comprising the at least one dehydrogenatable hydrocarbon under dehydrogenation conditions with a catalyst composition comprising a support and at least one dehydrogenation component wherein said conditions include a temperature of from 400° C. to 750° C. and a pressure of at least 50 psig (345 kPag).
摘要翻译: 用于脱氢至少一种可脱氢烃的脱氢方法,该方法包括在脱氢条件下使包含至少一种可脱氢烃的进料与包含载体和至少一种脱氢组分的催化剂组合物接触,其中所述条件包括 400℃至750℃,压力至少为50psig(345kPag)。
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公开(公告)号:US08884065B2
公开(公告)日:2014-11-11
申请号:US13989903
申请日:2011-10-25
申请人: Kun Wang , Jihad M. Dakka , Stephen Zushma , James R. Lattner , Christopher L. Becker , Tan-Jen Chen
发明人: Kun Wang , Jihad M. Dakka , Stephen Zushma , James R. Lattner , Christopher L. Becker , Tan-Jen Chen
IPC分类号: C07C45/53 , C07C15/067 , C07C37/08 , C07C2/74
CPC分类号: C07C2/74 , C07C37/08 , C07C45/53 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要: In a process for producing a cycloalkylaromatic compound, an aromatic compound and a cyclic olefin are contacted with a first catalyst under conditions effective to produce a reaction product comprising the cycloalkylaromatic compound and at least one non-fused bicyclic by-product. The at least one non-fused bicyclic by-product is then contacted with a second catalyst under conditions effective to convert at least a portion of the at least one non-fused bicyclic by-product to a converted by-product.
摘要翻译: 在制备环烷基芳族化合物的方法中,芳族化合物和环状烯烃在有效产生包含环烷基芳族化合物和至少一种非稠合双环副产物的反应产物的条件下与第一催化剂接触。 然后至少一种非稠合双环副产物在有效将至少一部分非稠合双环副产物转化为转化副产物的条件下与第二催化剂接触。
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公开(公告)号:US20120302798A1
公开(公告)日:2012-11-29
申请号:US13515104
申请日:2010-12-17
申请人: Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
发明人: Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
CPC分类号: C07C37/08 , B01J23/58 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/0203 , C07C5/367 , C07C37/07 , C07C45/53 , C07C407/00 , C07C2521/08 , C07C2523/42 , C07C2523/58 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C15/04
摘要: A dehydrogenation process for the dehydrogenation of at least one dehydrogenatable hydrocarbon, the process comprising contacting a feed comprising the at least one dehydrogenatable hydrocarbon under dehydrogenation conditions with a catalyst composition comprising a support and at least one dehydrogenation component wherein said conditions include a temperature of from 400° C. to 750° C. and a pressure of at least 50 psig (345 kPag).
摘要翻译: 用于脱氢至少一种可脱氢烃的脱氢方法,该方法包括在脱氢条件下使包含至少一种可脱氢烃的进料与包含载体和至少一种脱氢组分的催化剂组合物接触,其中所述条件包括 400℃至750℃,压力至少为50psig(345kPag)。
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