Catalyst pretreatment for olefin hydration
    6.
    发明授权
    Catalyst pretreatment for olefin hydration 失效
    催化剂预处理烯烃水合

    公开(公告)号:US5012014A

    公开(公告)日:1991-04-30

    申请号:US515029

    申请日:1990-04-26

    摘要: A process for production of alcohol or ether by hydration of olefinic feedstock containing at least one lower alkene by contacting the olefinic feedstock and water in a hydration zone with porous solid metal oxide acidic olefin hydration catalyst under olefins hydration conditions. The process is characterized by the step of pretreating porous solid catalyst, such as acid zeolite, prior to contacting with the olefinic feedstock with a wetting agent containing at least one polar aliphatic oxygenated hydrocarbon to substantially wet said solid catalyst and sorb said wetting agent into pores of said solid catalyst. After initiating hydration reaction by feeding the olefinic feedstock and water, increased catalytic activity is obtained. The process is particularly useful for making isopropanol and DIPE from propene and water.

    Dual stage process for the production of ethers
    9.
    发明授权
    Dual stage process for the production of ethers 失效
    用于生产醚的双阶段工艺

    公开(公告)号:US4935552A

    公开(公告)日:1990-06-19

    申请号:US296112

    申请日:1989-01-12

    摘要: Light olefins are catalytically converted to ethers, e.g., propylene is converted to diisopropyl ether, in a dual stage process in which product ether is recycled to a first stage reaction zone to significantly reduce the operating temperature of the olefin hydration/etherification reactions taking place in that zone. Alcohol produced in the first stage reaction zone undergoes conversion in the second stage reaction zone, e.g., by etherification with light olefin or by catalytic distillation, to provide additional product ether. The process contemplates the use of zeolites as olefin hydration/etherification catalysts.

    摘要翻译: 将轻质烯烃催化转化为醚,例如,丙烯转化为二异丙醚,在双阶段方法中,将产物醚再循环至第一阶段反应区,以显着降低烯烃水合/醚化反应的操作温度,发生在 那个区域。 在第一阶段反应区中产生的醇在第二阶段反应区中经历转化,例如通过与轻烯烃醚化或通过催化蒸馏来提供另外的产物醚。 该方法考虑使用沸石作为烯烃水合/醚化催化剂。

    Single path alkylation method employing reduced acid inventory
    10.
    发明授权
    Single path alkylation method employing reduced acid inventory 失效
    单路烷基化方法采用减少酸库存

    公开(公告)号:US5258568A

    公开(公告)日:1993-11-02

    申请号:US965306

    申请日:1992-10-23

    IPC分类号: C07C2/62 C07C2/56 C07C2/58

    摘要: A single path process for alkylating a hydrocarbon feedstock containing an olefin and an isoparaffin is disclosed. The process includes dispersing an acid-based liquid alkylation catalyst into a reaction zone for contact with a continuous hydrocarbon phase. The process further includes separating the hydrocarbon phase from the acid catalyst upon completion of the alkylation reaction and providing a continuous on-line regeneration of the entire volume of catalyst once it has been separated from the hydrocarbon phase.

    摘要翻译: 公开了用于烷基化含有烯烃和异链烷烃的烃原料的单程方法。 该方法包括将酸基液体烷基化催化剂分散在与连续烃相接触的反应区中。 该方法还包括在烷基化反应完成时从酸催化剂中分离出烃相,并且一旦将其从烃相中分离出来,就提供了整个体积催化剂的连续在线再生。