摘要:
A process for alkylation of isoparaffins and olefins employing a fixed bed of catalyst. The catalyst composition includes an unpromoted synthetic zeolite. The alkylate product contains highly branched paraffins and has an octane suitable for blending into motor gasolines. Alternatively multiple fixed beds can be employed with direct effluent recycle or split olefin feeds.
摘要:
A continuous alkylation process for the production of high octane gasoline comprising contacting a mixture of an isoparaffin and an olefin with a catalyst complex comprising BF3:H.sub.3 PO.sub.4 in a continuous hydrocarbon downflow reactor.
摘要翻译:包括用于生产高辛烷值汽油的连续烷基化方法,包括使异链烷烃和烯烃的混合物与包含BF 3 :H 3 PO 4的催化剂络合物在连续的烃下流反应器中接触。
摘要:
An improved continuous process for alkylation of isoparaffins with olefins to yield a product which includes a large proportion of highly branced paraffins for making gasoline having improved octane is taught. The improved process comprises contacting isoparaffins and olefins with a composite catalyst comprising a Lewis acid and a non-zeolitic inorganic oxide in the presence of a controlled amount of water. The process results in reduced catalyst aging and obviates environmental problems associated with prior art processes.
摘要:
An isoparaffin-olefin alkylation process is disclosed which improves alkylate quality by segregating the olefin feed into intermediate feedstreams which are enriched in propene, 1-butene, and/or 2-butenes with respect to the olefin feed, and alkylating these intermediate feedstreams in separate reaction zones at reaction temperatures specific to the olefin feed to increase the ratio of trimethylpentanes to dimethylhexanes in the resulting alkylate product.
摘要:
Isoparaffin-olefin alkylation is carried out in the presence of a Lewis acid-promoted catalyst, said catalyst comprising a synthetic porous crystalline material characterized in its calcined form by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要:
A process for production of alcohol or ether by hydration of olefinic feedstock containing at least one lower alkene by contacting the olefinic feedstock and water in a hydration zone with porous solid metal oxide acidic olefin hydration catalyst under olefins hydration conditions. The process is characterized by the step of pretreating porous solid catalyst, such as acid zeolite, prior to contacting with the olefinic feedstock with a wetting agent containing at least one polar aliphatic oxygenated hydrocarbon to substantially wet said solid catalyst and sorb said wetting agent into pores of said solid catalyst. After initiating hydration reaction by feeding the olefinic feedstock and water, increased catalytic activity is obtained. The process is particularly useful for making isopropanol and DIPE from propene and water.
摘要:
A process and apparatus are provided for the substantially uniform distribution of a two-phase feed in a chemical reaction zone. As applied, for example, to the hydration/etherification of light olefin to alcohol(s) and/or ether(s), the invention results in greater process control and in particular cases, to improved reaction product selectivities.
摘要:
A reactor system and process for conducting exothermic or endothermic chemical reactions achieves greater kinetic efficiency through transfer of heat between adjacent feed temperature modification and reaction zones.
摘要:
Light olefins are catalytically converted to ethers, e.g., propylene is converted to diisopropyl ether, in a dual stage process in which product ether is recycled to a first stage reaction zone to significantly reduce the operating temperature of the olefin hydration/etherification reactions taking place in that zone. Alcohol produced in the first stage reaction zone undergoes conversion in the second stage reaction zone, e.g., by etherification with light olefin or by catalytic distillation, to provide additional product ether. The process contemplates the use of zeolites as olefin hydration/etherification catalysts.
摘要:
A single path process for alkylating a hydrocarbon feedstock containing an olefin and an isoparaffin is disclosed. The process includes dispersing an acid-based liquid alkylation catalyst into a reaction zone for contact with a continuous hydrocarbon phase. The process further includes separating the hydrocarbon phase from the acid catalyst upon completion of the alkylation reaction and providing a continuous on-line regeneration of the entire volume of catalyst once it has been separated from the hydrocarbon phase.