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1.发明授权Amorphous metal alloy compositions for reversible hydrogen storage and electrodes made therefrom 失效用于可逆储氢的无定形金属合金组合物和由其制成的电极
公开(公告)号：US4923770A
公开(公告)日：1990-05-08
申请号：US243109
申请日：1988-09-02
CPC分类号： C01B3/0052 , C01B3/0031 , C01B3/0047 , C01B3/0057 , C22C45/10 , H01M10/345 , H01M4/383 , Y02E60/327 , Y10S420/90
摘要： The present invention provides a novel amorphous metal alloy composition which reversibly stores hydrogen and is useful as the hydrogen storage electrode in an energy storage device. The amorphous metal alloy is made up of at least three elements with at least one element of Ag, Hg, or Pt; at least one element of Pb, Cu, Cr, Mo, W, Ni, Al, Co, Fe, Zn, Cd, Ru or Mn: and at least one element of Ca, Mg, Ti, Zr, Hf, Nb, V or Ta.
摘要翻译： 本发明提供了一种新颖的非晶态金属合金组合物，其可逆地储存氢气，并且可用作储能装置中的储氢电极。 无定形金属合金由至少三种元素与至少一种元素Ag，Hg或Pt组成; Pb，Cu，Cr，Mo，W，Ni，Al，Co，Fe，Zn，Cd，Ru或Mn中的至少一种元素：Ca，Mg，Ti，Zr，Hf，Nb， 或Ta。
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公开(公告)号：US4609442A
公开(公告)日：1986-09-02
申请号：US748023
申请日：1985-06-24
申请人： Michael A. Tenhover , Richard S. Henderson , Jonathan H. Harris , Robert K. Grasselli , Michael D. Ward
发明人： Michael A. Tenhover , Richard S. Henderson , Jonathan H. Harris , Robert K. Grasselli , Michael D. Ward
CPC分类号： C25B11/04 , C25B11/0447
摘要： Amorphous metal alloys have the formulaM.sup.1.sub.a M.sup.2.sub.b M.sup.3.sub.cwhereM.sup.1 is Fe, Co, Ni, Pd and combination thereof;M.sup.2 is Ti, Zr, Hf, V, Nb, Ta and combination thereof;M.sup.3 is Rh, Os, Ir, Pt and combinations thereof;a ranges from about 0 to 60;b ranges from about 10 to 70; andc ranges from about 5 to 70, with the proviso that a+b+c=100.These alloys have utility as anodes in electrolytic processes and a process for the generation of halogens from halide-containing solutions includes a step of conducting electrolysis of the solutions in an electrolytic cell having an amorphous metal alloy anode of the formulaM.sup.1.sub.a M.sup.2.sub.b M.sup.3.sub.c.
摘要翻译： 无定形金属合金具有式M1aM2bM3c，其中M1是Fe，Co，Ni，Pd及其组合; M2是Ti，Zr，Hf，V，Nb，Ta及其组合; M3是Rh，Os，Ir，Pt及其组合; a范围为约0至60; b的范围为约10至70; 且c的范围为约5至70，条件是a + b + c = 100。 这些合金在电解方法中具有阳极的用途，并且从含卤素溶液中产生卤素的方法包括在具有式M1aM2bM3c的非晶金属合金阳极的电解池中进行电解电解的步骤。
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3.发明授权Compositionally graded amorphous metal alloys and process for the synthesis of same 失效组成分级非晶态金属合金及其合成方法
公开(公告)号：US4859413A
公开(公告)日：1989-08-22
申请号：US129029
申请日：1987-12-04
CPC分类号： B22F9/023 , B22F9/04 , C01B3/0031 , C01B3/0047 , C01B3/0052 , C01B3/0057 , C01B3/0078 , H01M4/383 , B22F2009/041 , Y02E60/327
摘要： The present invention is directed to a process for the synthesis of a compositionally graded substantially amorphous metal alloy comprising:(a) combining a bulk hydrogen storage material with an A-containing material to obtain a mixture thereof;(b) sealing the mixture in a mechanical milling device under an inert atmosphere; and(c) milling the mixture.Alloys produced by this process are useful for the efficient cyclic storage and release of hydrogen in large quantities without becoming embrittled, inactivated or corroded.
摘要翻译： 本发明涉及一种合成梯度的基本无定形金属合金的方法，包括：（a）将本体储氢材料与含A材料组合以获得其混合物; （b）在惰性气氛下将混合物密封在机械研磨装置中; 和（c）研磨该混合物。 通过该方法生产的合金可有效地大量循环储存和释放氢，而不会变脆，失活或腐蚀。
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公开(公告)号：US4902579A
公开(公告)日：1990-02-20
申请号：US242095
申请日：1988-09-08
CPC分类号： C22C45/10 , B22F9/004 , C01B3/0031 , C01B3/0047 , C01B3/0052 , C01B3/0057 , Y02E60/327 , Y10S420/90 , Y10T428/12458 , Y10T428/12806 , Y10T428/12875 , Y10T428/12944
摘要： Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
摘要翻译： 具有可逆储存氢能力的新型材料是式AaMbM'c的非晶金属合金，其中A是选自Ag，Au，Hg，Pd和Pt中的至少一种金属; M是选自Pb，Ru，Cu，Cr，Mo，Si，W，Ni，Al，Sn，Co，Fe，Zn，Cd，Ga和Mn中的至少一种金属; M'是选自Ca，Mg，Ti，Y，Zr，Hf，Nb，V，Ta和稀土中的至少一种金属; 并且其中a在大于0至约0.80的范围内; b范围从零到大约0.70; c在约0.08至约0.95的范围内; 其特征在于：（1）大部分的A设置在所述材料的表面上和/或（2）所述材料用作活性表面层，用于与包含可逆氢的大量储存材料一起吸附/解吸氢 储存材料。
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5.发明授权Electrolysis of halide-containing solutions with platinum based amorphous metal alloy anodes 失效用铂类非晶态金属合金阳极电解含卤化物溶液
公开(公告)号：US4560454A
公开(公告)日：1985-12-24
申请号：US705687
申请日：1985-02-26
IPC分类号： C02F1/461 , C02F1/467 , C22C45/00 , C25B11/04 , C25B11/08 , H01M4/86 , H01M4/90 , H01M4/92 , C25B1/24
CPC分类号： H01M4/928 , C02F1/46109 , C22C45/003 , C25B11/0478 , H01M4/90 , H01M4/92 , H01M4/925 , C02F1/4674 , C02F2001/46138 , H01M2004/8684
摘要： A process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having a platinum based amorphous metal alloy anode having the formulaPt.sub.p A.sub.a D.sub.dwhereA is Cr, Mo, W, Fe, Os, Cu, Ni, Ag, V, Au and mixtures thereof;D is B, Si, Al, Ge, P, As, Sb, Sn and mixtures thereof;p ranges from about 40 to 92;a ranges from about 0 to 40; andd ranges from about 8 to 60, with the proviso that p+a+d=100.Such amorphous metal alloy anodes are also based on the formulaPt.sub.p E.sub.e F.sub.fwhereE is Cr, Mo, W, Fe, Os, Ir, Cu, Ni, Rh, Pd, Ag, Ti, Ru, Nb, V, Ta, Au and mixtures thereof;F is B, Al, Ge, As, Sb, Sn and mixtures thereof;p ranges from about 40 to 92;e ranges from about 0 to 40; andf ranges from about 8 to 60, with the proviso that p+e+f=100.
摘要翻译： 用于从含卤素溶液中产生卤素的方法包括在具有式PtpAaDd的铂基非晶态金属合金阳极的电解池中进行电解电解的步骤，其中A是Cr，Mo，W，Fe，Os， Cu，Ni，Ag，V，Au及其混合物; D是B，Si，Al，Ge，P，As，Sb，Sn及其混合物; p范围为约40至92; a在约0至40的范围内; 并且d的范围为约8至60，条件是p + a + d = 100。 这种无定形金属合金阳极也基于式PtpEeFf，其中E是Cr，Mo，W，Fe，Os，Ir，Cu，Ni，Rh，Pd，Ag，Ti，Ru，Nb，V，Ta，Au和混合物 的; F是B，Al，Ge，As，Sb，Sn及其混合物; p范围为约40至92; e范围为约0至40; f为约8至60，条件是p + e + f = 100。
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公开(公告)号：US4952465A
公开(公告)日：1990-08-28
申请号：US237635
申请日：1988-08-26
IPC分类号： H01G9/00 , H01G9/155 , H01M4/02 , H01M4/24 , H01M4/38 , H01M4/48 , H01M6/10 , H01M10/34 , H01M10/52
CPC分类号： H01G9/155 , H01M10/34 , H01M10/52 , H01M4/24 , H01M4/383 , H01M4/481 , H01M10/526 , H01M2004/027 , H01M4/38 , H01M6/10 , Y02E60/13 , Y10S420/90
摘要： Novel additives are disclosed comprising a material capable of absorbing hydrogen and recombining oxygen, which additive is ideally suited for incorporation in sealed cells. The additive may be disposed in an energy storage device in several manners such as a coating on a negative electrode, a thin layer disposed between cell separators, an auxilliary electrode, and as one negative electrode in a device having a plurality of negative and positive electrodes.
摘要翻译： 公开了包含能够吸收氢并重新结合氧的材料的新型添加剂，该添加剂理想地适用于结合到密封的电池中。 添加剂可以以多种方式设置在能量存储装置中，例如负极上的涂层，设置在电池隔板之间的薄层，辅助电极以及具有多个负极和正极的装置中的一个负电极 。
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7.发明授权Method of forming amorphous metal alloy compositions for reversible hydrogen storage 失效形成用于可逆储氢的非晶态金属合金组合物的方法
公开(公告)号：US4814002A
公开(公告)日：1989-03-21
申请号：US143493
申请日：1988-01-13
CPC分类号： C01B3/0047 , B22F9/004 , C01B3/0031 , C01B3/0052 , C01B3/0057 , C22C45/10 , Y02E60/327 , Y10S420/90
摘要： Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; and M' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
摘要翻译： 具有可逆储存氢能力的新型材料是式AaMbM'c的非晶金属合金，其中A是选自Ag，Au，Hg，Pd和Pt中的至少一种金属; M是选自Pb，Ru，Cu，Cr，Mo，Si，W，Ni，Al，Sn，Co，Fe，Zn，Cd，Ga和Mn中的至少一种金属; M'是选自Ca，Mg，Ti，Y，Zr，Hf，Nb，V，Ta和稀土中的至少一种金属; 并且其中a在大于0至约0.80的范围内; b范围从零到大约0.70; c在约0.08至约0.95的范围内; 其特征在于：（1）大部分的A设置在所述材料的表面上和/或（2）所述材料用作活性表面层，用于与包含可逆氢的大量储存材料一起吸附/解吸氢 储存材料。
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公开(公告)号：US4728580A
公开(公告)日：1988-03-01
申请号：US717428
申请日：1985-03-29
CPC分类号： C01B3/0047 , B22F9/004 , C01B3/0031 , C01B3/0052 , C01B3/0057 , C22C45/10 , Y02E60/327 , Y10S420/90 , Y10T428/12458 , Y10T428/12806 , Y10T428/12875 , Y10T428/12944
摘要： Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co. Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
摘要翻译： 具有可逆储存氢能力的新型材料是式AaMbM'c的非晶金属合金，其中A是选自Ag，Au，Hg，Pd和Pt中的至少一种金属; M是选自Pb，Ru，Cu，Cr，Mo，Si，W，Ni，Al，Sn，Co，Fe，Zn，Cd，Ga和Mn中的至少一种金属; M'是选自Ca，Mg，Ti，Y，Zr，Hf，Nb，V，Ta和稀土中的至少一种金属; 并且其中a在大于0至约0.80的范围内; b范围从零到大约0.70; c在约0.08至约0.95的范围内; 其特征在于：（1）大部分的A设置在所述材料的表面上和/或（2）所述材料用作活性表面层，用于与包含可逆氢的大量储存材料一起吸附/解吸氢 储存材料。
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9.发明授权Electrolytic processes employing platinum based amorphous metal alloy oxygen anodes 失效采用铂基非晶态金属合金氧阳极的电解工艺
公开(公告)号：US4781803A
公开(公告)日：1988-11-01
申请号：US874617
申请日：1986-06-16
CPC分类号： H01M4/928 , C22C45/003 , H01M4/92 , H01M4/925 , H01M2004/8684
摘要： Improved electrolytic processes employing oxygen anodes. The improvement comprises the step of conducting a electrolysis process in an electrolytic cell having a platinum based amorphous metal alloy oxygen anode having the formulaPt.sub.p A.sub.a D.sub.dwhereA is Cr, Mo, W, Fe, Os, Ir, Cu, Ni, Rh, Pd, Ag, Ti, Ru, Nb, V, Ta, Au and mixtures thereof;D is B, C, Si, Al, Ge, P, As, Sb, Sn and mixtures thereof;p ranges from about 40 to 92;a ranges from about 0 to 40; andd ranges from about 8 to 60, with the proviso that p+a+d=100.
摘要翻译： 使用氧阳极的改进的电解方法。 该改进包括在具有式PtpAaDd的铂基非晶态金属合金氧阳极的电解槽中进行电解处理的步骤，其中A是Cr，Mo，W，Fe，Os，Ir，Cu，Ni，Rh，Pd， Ag，Ti，Ru，Nb，V，Ta，Au及其混合物; D是B，C，Si，Al，Ge，P，As，Sb，Sn及其混合物; p范围为约40至92; a在约0至40的范围内; 并且d的范围为约8至60，条件是p + a + d = 100。
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10.发明授权Anodes containing iridium based amorphous metal alloys and use thereof as halogen electrodes 失效含有铱基非晶态金属合金的阳极及其作为卤素电极的用途
公开(公告)号：US4705610A
公开(公告)日：1987-11-10
申请号：US867782
申请日：1986-05-27
CPC分类号： C22C45/003 , C25B11/0478 , C25B11/0494
摘要： Anodes comprising substrate materials coated with iridium based amorphous metal alloys having the formulaeIr.sub.i D.sub.d E.sub.e F.sub.fandIr.sub.i Y.sub.y D.sub.d E.sub.e F.sub.fwhereY is yttriumD is Ti, Zr, Y, Nb, Ta, Ru, W, Mo and mixtures thereof;E is C, B, Si, P, Al, Ge, As, N, Sb and mixtures thereof;F is Rh, Pt, Pd and mixtures thereof;i is 35 to 96 or 50 to 96, respectively;y is 4 to 40;d is 0 to 40;e is 4 to 40;f is 0 to 45; andi+d+e+f=100, i+y+d+e+f=100, and if E is Si and/or P, then B is also present.A process for the use of the foregoing iridium based alloys as anodes for the electrolysis of halide-containing electrolyte solutions is also provided.
摘要翻译： 包含具有式IriDdEeFf和IriYyDdEeFf的铱基非晶态金属合金的基体材料的阳极，其中Y是钇D是Ti，Zr，Y，Nb，Ta，Ru，W，Mo及其混合物; E是C，B，Si，P，Al，Ge，As，N，Sb及其混合物; F是Rh，Pt，Pd及其混合物; 我分别是35到96或50到96; y为4〜40; d为0〜40; e是4到40; f为0〜45; 并且i + d + e + f = 100，i + y + d + e + f = 100，并且如果E是Si和/或P，则B也存在。 还提供了使用上述铱基合金作为用于电解含卤化物的电解质溶液的阳极的方法。
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