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    Catalyst and its preparation and use for the solution polymerization of conjugated dienes
    2.
    发明授权
    Catalyst and its preparation and use for the solution polymerization of conjugated dienes 失效
    催化剂及其制备和用途，用于共轭二烯的溶液聚合

    公开(公告)号：US4242232A

    公开(公告)日：1980-12-30

    申请号：US54632

    申请日：1979-07-03

    Applicant: Gerd Sylvester ,  Josef Witte ,  Gunter Marwede

    Inventor： Gerd Sylvester ,  Josef Witte ,  Gunter Marwede

    IPC: C08F4/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/72 ,  C08F36/00 ,  C08F36/04 ,  C08F4/12

    CPC classification number: C08F36/04

    Abstract: A catalyst comprising(a) a reaction mixture formed by reacting M(RCO.sub.2).sub.3 with AlR.sub.3'.sup.1(b) AlR.sub.3.sup.2 and / or HAlR.sub.2.sup.2 and(c) a Lewis acidwherein M denotes a trivalent rare earth element with an atomic number of 57 to 71, R denotes a saturated or unsaturated, straight chain or branched chain aliphatic hydrocarbon group having 1 to 20 C-atoms which may be substituted one or more times with cycloalkyl having 5 to 7-atoms and/or phenyl, the carboxyl group being attached to a primary, secondary or tertiary C-atom; a cycloalkyl group having 5 to 7 ring carbon atoms, which may be substituted one or more times with alkyl groups having from 1 to 5 C-atoms; or an aromatic group having from 6 to 10 ring carbon atoms, which may be substituted one or more times with alkyl groups having 1 to 5 C-atoms, and R.sup.1 and R.sup.2 are identical or different, straight chain or branched chain alkyl groups having from 1 to 10 C-atoms. Said catalyst may be used for polymerizing diene monomers in solution. Its production takes place by mixing the components in any order.

    Abstract translation: 一种催化剂，其包含（a）通过M（RCO 2）3与AlR 3'1（b）AlR 32和/或HA 1R 22反应形成的反应混合物和（c）路易斯酸，其中M表示原子序数为57的三价稀土元素 至71，R表示具有1至20个C原子的饱和或不饱和的直链或支链脂族烃基，其可以被具有5至7个原子的环烷基和/或苯基取代一次或多次，羧基为 连接到伯，仲或叔C原子上; 具有5至7个环碳原子的环烷基，其可以被具有1至5个C原子的烷基取代一次或多次; 或具有6至10个环碳原子的芳族基团，其可以被具有1至5个C原子的烷基取代一次或多次，并且R 1和R 2相同或不同，具有直链或支链烷基 1〜10个碳原子。 所述催化剂可用于在溶液中聚合二烯单体。 其生产通过以任何顺序混合组分进行。

    Solution polymerization of conjugated dienes
    3.
    发明授权
    Solution polymerization of conjugated dienes 失效
    共轭二烯的溶液聚合

    公开(公告)号：US4260707A

    公开(公告)日：1981-04-07

    申请号：US117523

    申请日：1980-02-01

    Applicant: Gerd Sylvester ,  Josef Witte ,  Gunter Marwede

    Inventor： Gerd Sylvester ,  Josef Witte ,  Gunter Marwede

    IPC: C08F4/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/72 ,  C08F36/00 ,  C08F36/04 ,  C08F4/52

    CPC classification number: C08F36/04

    Abstract: A catalyst comprising(a) a reaction mixture formed by reacting M(RCO.sub.2).sub.3 with AlR.sub.3.sup.1,(b) AlR.sub.3.sup.2 and/or HAlR.sub.2.sup.2 and(c) a Lewis acidwherein M denotes a trivalent rare earth element with an atomic number of 57 to 71, R denotes a saturated or unsaturated, straight chain or branched chain alkyl group having 1 to 20 C-atoms which may be substituted one or more times with cycloalkyl having 5 to 7-atoms and/or phenyl, the carboxyl group being attached to a primary, secondary or tertiary C-atom; a cycloalkyl group having 5 to 7 ring carbon atoms, which may be substituted one or more times with alkyl groups having from 1 to 5 C-atoms; or an aromatic group having from 6 to 10 ring carbon atoms, which may be substituted one or more times with alkyl groups having 1 to 5 C-atoms, and R.sup.1 and R.sup.2 are identical or different, straight chain or branched chain alkyl groups having from 1 to 10 C-atoms. Said catalyst may be used for polymerizing diene monomers in solution. Its production takes place by mixing the components in any order.

    Abstract translation: 一种催化剂，其包含（a）通过使M（RCO 2）3与AlR 31反应形成的反应混合物，（b）AlR32和/或HAR1R22和（c）路易斯酸，其中M表示原子序数为57〜 71，R表示具有1〜20个碳原子的饱和或不饱和的直链或支链烷基，其可以被具有5至7个原子的环烷基和/或苯基取代一次或多次，羧基连接到 一级，二级或三级C原子; 具有5至7个环碳原子的环烷基，其可以被具有1至5个C原子的烷基取代一次或多次; 或具有6至10个环碳原子的芳族基团，其可以被具有1至5个C原子的烷基取代一次或多次，并且R 1和R 2相同或不同，具有直链或支链烷基 1〜10个C原子。 所述催化剂可用于在溶液中聚合二烯单体。 其生产通过以任何顺序混合组分进行。

    Process for the production of butadiene-propylene copolymers
    4.
    发明授权
    Process for the production of butadiene-propylene copolymers 失效
    生产丁二烯 - 丙烯共聚物的方法

    公开(公告)号：US4189558A

    公开(公告)日：1980-02-19

    申请号：US907185

    申请日：1978-05-18

    Applicant: Josef Witte ,  Gerd Sylvester ,  Gunter Marwede

    Inventor： Josef Witte ,  Gerd Sylvester ,  Gunter Marwede

    IPC: C07F9/00 ,  C08F210/06 ,  C08F236/06 ,  C08F4/68

    CPC classification number: C08F210/06 ,  C07F9/005 ,  C08F236/06

    Abstract: A process for the production of strictly alternating copolymers of trans-1,4-butadiene and propylene units by the solution copolymerization of butadiene and propylene with vanadium-containing organometallic mixed catalysts, wherein vanadyl dialkoxy halides of which the alkoxy groups are branched in the 2-position to the oxygen atom are used as the vanadium compounds.

    Abstract translation: 通过丁二烯和丙烯与含钒有机金属混合催化剂的溶液共聚制备反式1,4-丁二烯和丙烯单元的严格交替共聚物的方法，其中烷氧基在2位上分支的氧化二烷氧基卤化物 使用与氧原子的位置作为钒化合物。

    Polysegment copolymers
    5.
    发明授权
    Polysegment copolymers 失效
    聚段共聚物

    公开(公告)号：US4133845A

    公开(公告)日：1979-01-09

    申请号：US863083

    申请日：1977-12-22

    Applicant: Manfred Beck ,  Gunter Marwede ,  Rainer Fritz

    Inventor： Manfred Beck ,  Gunter Marwede ,  Rainer Fritz

    IPC: C08G81/02 ,  C08K3/30 ,  C08F297/04

    CPC classification number: C08G81/022 ,  C08K3/30

    Abstract: Polysegment copolymers with thermoelastomeric properties are obtained by a process, wherein block polymers of the idealised form S.sub.x -B.sub.y, in which S represents structural units derived from styrene, B represents structural units derived from a conjugated diene and x and y are integers, are reacted with sulphur chlorides.The products according to the invention are suitable for the production of shoe soles, hoses, industrial rubber articles and particularly hot melt adhesives.

    Abstract translation: 具有热弹性性质的聚段共聚物通过以下方法获得：其中S表示衍生自苯乙烯的结构单元，S表示衍生自共轭二烯的结构单元，x和y为整数的理想化形式的Sx-By的嵌段聚合物是整数， 与硫化氯。

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