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公开(公告)号：US4379896A
公开(公告)日：1983-04-12
申请号：US333886
申请日：1981-12-23
CPC分类号： C08G73/14 , C07C51/31 , C07C65/34 , C08G10/02 , Y10T428/31721
摘要： This invention relates to thermally stable resins and provides such a resin made from cheaply available coal-derived materials, whereas presently available resins are made from increasingly expensive oil-derived materials.The resin comprises the condensation product of a reaction between an aromatic diamine and a phenanthrene-formaldehyde reaction product, which product has been oxidized to produce keto groups bridging the phenanthrene moieties and carboxy groups. The condensation product is a poly-(amine-imide).The invention also includes a method of making the resin and varnishes containing the resin.The resin will find use for instance as a high temperature insulator or in glass or asbestos laminates in compressor blades.
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2.发明授权Method of producing an improved poly-(amide-imide) resin by reacting a phenanthrene with formaldehyde followed by oxidizing to produce a polycarboxylated product followed by reaction with an aromatic diamine 失效通过使菲与甲醛反应生成改进的聚（酰胺 - 酰亚胺）树脂的方法，然后氧化以产生多羧基化产物，然后与芳族二胺反应
公开(公告)号：US4352922A
公开(公告)日：1982-10-05
申请号：US240025
申请日：1981-03-03
摘要： According to the present invention, there is provided an improved method of producing a poly-(amide-imide) resin comprising the steps of:(1) reacting a phenanthrene with formaldehyde or a formaldehyde donor in the presence of an acid catalyst to give a phenanthreneformaldehyde reaction product having substantially only methylene bridges;(2) removing from the reaction product unreacted phenanthrene;(3) treating the reaction product with formaldehyde or a formaldehyde donor in the presence of an acid catalyst to give a high molecular weight product having substantially only methylene bridges;(4) oxidizing the high molecular weight product to break the 9, 10 bond in the phenanthrene moieties to produce a polycarboxylated reaction product;(5) reacting the polycarboxylated reaction product with an aromatic diamine to produce a poly-(amide-imide) resin.The resin would find use as a lamp capping cement, as a high temperature insulator, in copper clad high temperature printed circuits, in electrical heater panels, in transformers and in glass or asbestos laminates for use as compressor blades.
摘要翻译： 根据本发明，提供一种生产聚（酰胺 - 酰亚胺）树脂的改进方法，包括以下步骤：（1）在酸催化剂存在下，使菲与甲醛或甲醛供体反应，得到 菲甲醛反应产物基本上只有亚甲基桥; （2）从反应产物中除去未反应的菲; （3）在酸催化剂存在下用甲醛或甲醛供体处理反应产物，得到基本上只有亚甲基桥的高分子量产物; （4）氧化高分子量产物以破坏菲部分中的9,10键以产生多羧化反应产物; （5）使多羧化反应产物与芳族二胺反应，生成聚（酰胺 - 酰亚胺）树脂。 该树脂可用作铜包覆水泥，高温绝缘子，铜包覆高温印刷电路，电加热器板，变压器和用作压缩机叶片的玻璃或石棉层压板中。
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公开(公告)号：US4394499A
公开(公告)日：1983-07-19
申请号：US290089
申请日：1981-08-04
CPC分类号： C08G73/0672 , Y10T428/31721
摘要： This invention relates to an improved polyimide resin and to a method of its production.The improved polyimide resin is made from phenanthrene which is converted via a 9, 10-diol to oligomers of diphenic anhydride units linked by keto bridges. The oligomers are reacted with from 0.1 to 0.6 of an equivalent quantity of an aromatic primary diamine. The remaining anhydride groups are reacted with a monofunctional amine to give a polyimide of low cross-link density.The resin will find use for instance in forming glasscloth laminates.
摘要翻译： 本发明涉及一种改进的聚酰亚胺树脂及其制备方法。 改进的聚酰亚胺树脂由菲衍生而成，其通过9,10-二醇转化成通过酮桥连接的二烯酸酐单元的低聚物。 低聚物与0.1至0.6当量的芳族伯胺反应。 剩余的酸酐基团与单官能胺反应，得到交联密度低的聚酰亚胺。 树脂将用于例如形成玻璃纤维层压板。
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公开(公告)号：US4346212A
公开(公告)日：1982-08-24
申请号：US174152
申请日：1980-07-31
CPC分类号： C08G73/14 , C07C51/31 , C07C65/34 , C08G10/02 , Y10T428/31721
摘要： This invention relates to thermally stable resins and provides such a resin made from cheaply available coal-derived materials, whereas presently available resins are made from increasingly expensive oil-derived materials.The resin comprises the condensation product of a reaction between an aromatic diamine and a phenanthrene-formaldehyde reaction product, which product has been oxidized to produce keto groups bridging the phenanthrene moieties and carboxy groups. The condensation product is a poly-(amide-imide).The invention also includes a method of making the resin and varnishes containing the resin.The resin will find use for instance as a high temperature insulator or in glass or asbestos laminates in compressor blades.
摘要翻译： 本发明涉及热稳定树脂，并且提供由廉价的煤源材料制成的这种树脂，而目前可用的树脂由越来越昂贵的石油衍生材料制成。 树脂包括芳族二胺和菲 - 甲醛反应产物之间的反应的缩合产物，该产物已被氧化以产生桥接菲部分和羧基的酮基。 缩合产物是聚（酰胺 - 酰亚胺）。 本发明还包括制备含树脂的树脂和清漆的方法。 该树脂将用作例如高温绝缘体或在压缩机叶片中的玻璃或石棉层压材料中。
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公开(公告)号：US4192824A
公开(公告)日：1980-03-11
申请号：US2173
申请日：1979-01-09
CPC分类号： C08G10/00 , C07C2/867 , C07C2527/125 , C07C2527/126
摘要： A method of producing a condensation product by reacting together an aromatic hydrocarbon with a carbonyl compound having more than one carbon atom (therefore excluding formaldehyde) in the presence of aluminium chloride or bromide, at a temperature of from 5.degree. to 90.degree. C. The aluminium chloride or bromide should be substantially anhydrous. The aromatic hydrocarbon should be mono- or bi-nuclear and may be alkylated. The carbonyl compound may be an aldehyde or a betone and may be albyl or aryl.
摘要翻译： 在5℃至90℃的温度下，在氯化铝或溴化银的存在下，通过使芳族烃与具有多于一个碳原子的羰基化合物（因此不包括甲醛）反应而制备缩合产物的方法。 氯化铝或溴化物应基本无水。 芳烃应该是单核或双核并可以烷基化。 羰基化合物可以是醛或betone，并且可以是albyl或芳基。
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公开(公告)号：US4526767A
公开(公告)日：1985-07-02
申请号：US560926
申请日：1983-12-13
CPC分类号： C01B39/40 , B01J29/40 , Y10S423/22
摘要： Catalysts of the ZSM-5 synthetic zeolite type can be prepared by heating a mixture of a precursor for an alumina hydrate, a precursor for silica hydrogel, an alkali metal hydroxide and water together with an organic templating agent selected from the group of carboxymethylcellulose, the condensation product of an alkanolamine and a fatty acid and cellulose hydroxyethyl ether and therafter heating the reaction product under autogeneous conditions. Unlike prior proposals ZSM-5 which is uncontaminated by other zeolites, is prepared in high yield.
摘要翻译： ZSM-5合成沸石型催化剂可以通过将水合氧化铝的前体，二氧化硅水凝胶的前体，碱金属氢氧化物和水与选自羧甲基纤维素的有机模板剂， 链烷醇胺和脂肪酸的缩合产物和纤维素羟乙基醚，并在自发条件下加热反应产物。 不同于先前提出的未被其他沸石污染的ZSM-5以高产率制备。
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公开(公告)号：US4469814A
公开(公告)日：1984-09-04
申请号：US554246
申请日：1983-11-22
IPC分类号： C10G3/00 , B01J21/12 , B01J29/04 , C07B61/00 , C07C1/00 , C07C1/20 , C07C15/00 , C07C67/00 , B01J20/32 , B01J23/46 , B01J23/74
CPC分类号： C07C1/20 , B01J21/12 , C07C2521/12 , Y02P20/52 , Y02P30/20
摘要： An improved catalyst for conversion of oxygen-containing aliphatics to hydrocarbons is a silica xerogel having a layer of an aluminum compound chemically bonded onto its surface, having a maximum pore diameter of 1.1 nm and having substantially only protons and/or transition metal cations as electrical charge balancing species. The catalyst is very specific for the production of aromatics.
摘要翻译： 用于将含氧脂族烃转化为烃的改进的催化剂是具有化学键合到其表面上的铝化合物层的二氧化硅干凝胶，其最大孔径为1.1nm，并且基本上仅具有质子和/或过渡金属阳离子作为电 电荷平衡物种。 该催化剂非常专门用于生产芳族化合物。
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公开(公告)号：US4427578A
公开(公告)日：1984-01-24
申请号：US396132
申请日：1982-07-07
IPC分类号： B01J21/08 , B01J23/74 , B01J23/745 , B01J27/22 , B01J35/10 , B01J37/02 , C07C1/00 , C07C1/04 , C07C11/02 , C07C67/00
CPC分类号： B01J23/745 , B01J27/22 , B01J35/10 , B01J37/024 , C07C1/0425 , C07C1/0445 , B01J35/1023 , B01J35/1038 , B01J35/1057 , C07C2521/08 , C07C2523/745
摘要： This invention relates to a catalyst for use in the direct conversion of synthesis gas to olefinic hydrocarbons in good yield. It also relates to a process for producing the catalyst.The catalyst comprises a highly porous amorphous silica support on which is deposited one or more monolayers of silica. The catalyst is then impregnated with a transition metal. The monolayer of silica is formed by the hydrolysis of a compound such as ethyl orthosilicate while it is adsorbed onto the support.
摘要翻译： 本发明涉及用于以良好的收率将合成气直接转化为烯烃的催化剂。 它还涉及一种生产该催化剂的方法。 催化剂包括高度多孔的无定形二氧化硅载体，在其上沉积一个或多个二氧化硅单层。 然后用过渡金属浸渍催化剂。 二氧化硅的单层通过水解原料硅酸乙酯等化合物而被吸附在载体上形成。
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公开(公告)号：US4373089A
公开(公告)日：1983-02-08
申请号：US240007
申请日：1981-03-03
IPC分类号： C07C63/331 , C08G73/10
CPC分类号： C07C63/331 , C08G73/1003 , C08G73/1067 , Y10T428/31562
摘要： A polyimide resin is made by converting a phanthrene to its 9, 10 diol derivative, reacting the derivative with formaldehyde to give a methylene bridged reaction product, oxidizing the reaction product to produce a polycarboxylated product, and reacting the polycarboxylated product with an aromatic diamine to form the polyimide resin. The invention also includes the resin, the reaction product and the polycarboxylated product.The resin will be useful as a lamp capping cement, a high temperature insulator, in copper clad printed circuit boards, in glass or asbestos laminates for use as compressor blades.
摘要翻译： 通过将菲胺转化为其9,10二醇衍生物，使该衍生物与甲醛反应得到亚甲基桥接的反应产物，氧化该反应产物以产生多羧酸化的产物，并将该多羧基化产物与芳族二胺反应制成聚酰亚胺树脂 形成聚酰亚胺树脂。 本发明还包括树脂，反应产物和多羧基化产物。 该树脂可用作铜包覆印刷电路板中的灯头水泥，高温绝缘体，用于压缩机叶片的玻璃或石棉层压板中。
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