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公开(公告)号：US07968004B2
公开(公告)日：2011-06-28
申请号：US12250770
申请日：2008-10-14
CPC分类号： C08G61/12 , C08G2261/3142 , C08G2261/3162 , C08G2261/411 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1033 , H01L51/0039 , H01L51/5016 , H05B33/10 , H05B33/14 , Y10S428/917 , Y10T428/31504
摘要： Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies >2.10 eV are required.
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公开(公告)号：US08940411B2
公开(公告)日：2015-01-27
申请号：US13093038
申请日：2011-04-25
IPC分类号： H01L51/54 , C09K11/06 , C08G75/32 , C07C43/205 , C08G79/00 , C08G61/12 , H01L51/00 , C08K5/00 , C08L65/00 , H01L51/50
CPC分类号： C08G61/123 , C08G2261/12 , C08G2261/3142 , C08G2261/3246 , C08G2261/3247 , C08G2261/411 , C08G2261/95 , C08K5/0091 , H01L51/0039 , H01L51/0043 , H01L51/5012 , H01L51/5016 , Y10S428/917 , C08L65/00
摘要： Energy efficient optoelectronic devices include an electroluminescent layer containing a polymer made up of structural units of formula I and II; wherein R1 and R2 are independently C22-44 hydrocarbyl, C22-44 hydrocarbyl containing one or more S, N, O, P, or Si atoms, oxaalkylaryl, or a combination thereof; R3 and R4 are independently H, C1-44 hydrocarbyl or C1-44 hydrocarbyl containing one or more S, N, O, P, or Si atoms, or R3 and R4, taken together, form a C2-10 monocyclic or bicyclic ring containing up to three S, N, O, P, or Si heteroatoms; and X is S, Se, or a combination thereof.
摘要翻译： 能量效率的光电器件包括含有由式I和II的结构单元构成的聚合物的电致发光层; 其中R1和R2独立地为C22-44烃基，含有一个或多个S，N，O，P或Si原子的C22-44烃基，氧杂烷基芳基或其组合; R 3和R 4独立地是H，C 1-4烃基或含有一个或多个S，N，O，P或Si原子的C 1-4烃基，或者R 3和R 4一起形成含有C 1-10的单环或双环 最多三个S，N，O，P或Si杂原子; X是S，Se或它们的组合。
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3.发明授权Organic light emitting device with outcoupling layer for improved light extraction 有权具有外耦合层的有机发光器件，用于改进光提取公开(公告)号：US08269214B2
公开(公告)日：2012-09-18
申请号：US12846236
申请日：2010-07-29
CPC分类号： H01L51/5268 , H01L2251/5369
摘要： An organic light emitting device comprises an outcoupling layer having relatively high aspect ratio nanowires imbedded within an optically thick transparent high optical index film. The incorporation of nanowires increases the optical index of a light emitting assembly and provides a means for extracting light from a light emitting assembly of the organic light emitting device.
摘要翻译： 有机发光器件包括嵌入在光学厚的透明高光学折射率膜内的相对高的纵横比的纳米线的外耦合层。 纳入线的并入增加了发光组件的光学折射率，并且提供了用于从有机发光器件的发光组件提取光的装置。
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公开(公告)号：US08052892B2
公开(公告)日：2011-11-08
申请号：US12250765
申请日：2008-10-14
CPC分类号： C08G61/02 , C07C43/21 , C07C2603/18 , C07D295/088 , C08G2261/1424 , C08G2261/143 , C08G2261/148 , C08G2261/226 , C08G2261/3142 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1048 , C09K2211/1096 , H01L51/0039 , H01L51/5016 , H05B33/14 , Y10S428/917
摘要： Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies >2.10 eV are required.
摘要翻译： 在芴的2和5位上具有大量（10-100％）芴的聚芴聚合物和共聚物可用作需要三元组能量> 2.10eV的OLED器件中的有源层。
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5.发明授权公开(公告)号：US06500914B1
公开(公告)日：2002-12-31
申请号：US09682724
申请日：2001-10-10
IPC分类号： C08G6400
摘要： A method for end-capping polycarbonate resins, comprising the step of processing a mixture comprising a polycarbonate having free hydroxyl-end groups and an end-capping reagent in a melt transesterification reaction to produce a polycarbonate resin, wherein the end-capping reagent comprises a mixture of:(a) at least one species of a symmetrical activated aromatic carbonate, and (b) at least one species of a symmetrical non-activated aromatic carbonate, whereby said end-capping reagent reacts with at least some of the free hydroxyl end-groups of the polycarbonate to produce an end-capped polycarbonate resin.
摘要翻译： 一种封端聚碳酸酯树脂的方法，包括在熔融酯交换反应中处理包含游离羟基端基的聚碳酸酯和封端剂的混合物以制备聚碳酸酯树脂的步骤，其中封端剂包括 混合物：（a）至少一种对称活性芳族碳酸酯，和（b）至少一种对称非活化芳族碳酸酯，其中所述封端剂与至少一些游离羟基末端反应 的聚碳酸酯组，以制备端封聚碳酸酯树脂。
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公开(公告)号：US06252035B1
公开(公告)日：2001-06-26
申请号：US09451033
申请日：1999-11-29
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： The present invention relates to a method for the preparation of polycarbonate comprising preparing a polycarbonate by a melt process by reacting a diphenol and a diaryl carbonate in the presence of a catalytically effective amount of one or more alkali and or alkali earth metal salts of chelating agents. Suitable chelating agents include nitrilotriacetate and EDTA.
摘要翻译： 本发明涉及一种制备聚碳酸酯的方法，包括通过使催化有效量的一种或多种螯合剂的碱金属和/或碱土金属盐存在下使二酚和碳酸二芳基酯通过熔融法制备聚碳酸酯 。 合适的螯合剂包括次氮基三乙酸钠和EDTA。
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公开(公告)号：US06252013B1
公开(公告)日：2001-06-26
申请号：US09483959
申请日：2000-01-18
申请人： Timothy Edward Banach , Gary Charles Davis , Paul Michael Smigelski, Jr. , Patrick Joseph McCloskey
发明人： Timothy Edward Banach , Gary Charles Davis , Paul Michael Smigelski, Jr. , Patrick Joseph McCloskey
IPC分类号： C08F446
CPC分类号： C08G64/186 , C08G77/448
摘要： A melt condensation polymerization process for preparing siloxane copolycarbonates is provided. The process includes reacting an aromatic dihydroxy compound, carbonic acid diester, hydroxyaryl terminated polydiorganosiloxane and catalyst with a salt.
摘要翻译： 提供了制备硅氧烷共聚碳酸酯的熔融缩聚方法。 该方法包括使芳族二羟基化合物，碳酸二酯，羟基芳基封端的聚二有机硅氧烷和催化剂与盐反应。
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公开(公告)号：US06870025B2
公开(公告)日：2005-03-22
申请号：US10326933
申请日：2002-12-23
申请人： Patrick Joseph McCloskey , Jan Pleun Lens , James Anthony Cella , Jan Henk Kamps , Kathryn Lynn Longley , Narayan Ramesh , Warren William Reilly , Paul Michael Smigelski, Jr. , Marc Brian Wisnudel
发明人： Patrick Joseph McCloskey , Jan Pleun Lens , James Anthony Cella , Jan Henk Kamps , Kathryn Lynn Longley , Narayan Ramesh , Warren William Reilly , Paul Michael Smigelski, Jr. , Marc Brian Wisnudel
IPC分类号： C08G63/64 , C08G64/00 , C08G64/04 , C08G64/14 , C08G64/30 , C08L23/00 , C08L67/00 , C08L69/00
CPC分类号： C08G63/64 , C08G64/04 , C08G64/14 , C08G64/307 , C08L23/00 , C08L67/00 , C08L69/00 , C08L69/005 , C08L2666/18 , C08L2666/06
摘要： Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4′-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.
摘要翻译： 含有低或不可检测水平的弗里斯重排产物并且包含衍生自间苯二酚，氢醌，甲基氢醌，双酚A和4,4'-联苯酚中的一种或多种的重复单元的聚碳酸酯已经通过一种或多种上述 二羟基芳族化合物与酯取代的二芳基碳酸酯如碳酸双甲基水杨酸酯。 低产量或在许多情况下，不可检测的是，在由高效催化剂体系获得的产品聚碳酸酯中发现了油炸产品重排产物的水平，该催化剂体系抑制了Fries反应，并且相对于类似物所需的温度使用较低的熔体聚合温度 使用碳酸二苯酯的聚合反应
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公开(公告)号：US06184334B2
公开(公告)日：2001-02-06
申请号：US09411274
申请日：1999-10-04
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： The present invention relates to a method for the preparation of polycarbonate comprising preparing a polycarbonate by a melt process by reacting a diphenol and a diaryl carbonate in the presence of a catalytically effective amount of one or more alkali metal salts of oxoacids of sulfur.
摘要翻译： 本发明涉及一种制备聚碳酸酯的方法，包括通过在催化有效量的一种或多种含硫酸的硫酸的碱金属盐的存在下使二酚和碳酸二芳基酯通过熔融法制备聚碳酸酯。
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公开(公告)号：US07115700B2
公开(公告)日：2006-10-03
申请号：US11133827
申请日：2005-05-19
申请人： James Anthony Cella , Jan Henk Kamps , Jan Pleun Lens , Kathryn Lynn Longley , Patrick Joseph McCloskey , Narayan Ramesh , Warren William Reilly , Paul Michael Smigelski, Jr. , Marc Brian Wisnudel
发明人： James Anthony Cella , Jan Henk Kamps , Jan Pleun Lens , Kathryn Lynn Longley , Patrick Joseph McCloskey , Narayan Ramesh , Warren William Reilly , Paul Michael Smigelski, Jr. , Marc Brian Wisnudel
IPC分类号： C08G63/00
CPC分类号： C08G63/64 , C08G64/04 , C08G64/14 , C08G64/307 , C08L23/00 , C08L67/00 , C08L69/00 , C08L69/005 , C08L2666/18 , C08L2666/06
摘要： Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4′-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.
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