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1.发明授权Overbased metal carbonate/carboxylate microemulsions and halogen-containing polymers containing same 失效高碱性金属碳酸盐/羧酸盐微乳液和含有其的含卤素聚合物公开(公告)号：US06835328B2
公开(公告)日：2004-12-28
申请号：US10669955
申请日：2003-09-24
申请人： Julius Fakinlede , Michael H. Fisch , Ulrich Stewen , Radu Bacaloglu , Shah Mukund , Ilze Bacaloglu , Wahib I. Farahat
发明人： Julius Fakinlede , Michael H. Fisch , Ulrich Stewen , Radu Bacaloglu , Shah Mukund , Ilze Bacaloglu , Wahib I. Farahat
IPC分类号： C09K1506
摘要： A metal carbonate/carboxylate microemulsion imparting static and dynamic thermal stability to a halogen-containing polymer is provided which comprises (a) a metal carbonate/carboxylate obtained from the reaction of an oxide and/or hydroxide of a metal selected from the group consisting of sodium, potassium, calcium, magnesium, zinc and mixtures thereof and an aliphatic acid in which the aliphatic moiety contains up to about 30 carbon atoms and carbon dioxide in an oil; b) one or more non-phenolic compounds having about two or about three hydroxyl groups; and, c) one or more polyols, alcohol ethoxylates and/or alcohol propoxylates having from about 6 to about 24 carbon atoms in the alcohol and/or 0 to 3 ethylene oxide units and/or 0 to 3 propylene oxide units.
摘要翻译： 提供赋予含卤素聚合物静态和动态热稳定性的金属碳酸盐/羧酸盐微乳液，其包含（a）由氧化物和/或氢氧化物与选自以下的金属的反应得到的金属碳酸盐/羧酸盐： 钠，钾，钙，镁，锌及其混合物和其中脂族部分含有至多约30个碳原子的脂族酸和油中的二氧化碳; b）一种或多种具有约2或约3个 羟基; 和c）在醇和/或0-3个环氧乙烷单元和/或0-3个环氧丙烷单元中具有约6至约24个碳原子的一种或多种多元醇，醇乙氧基化物和/或醇丙氧基化物。
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2.发明授权Complexes of metal salts of organic acids and beta-diketones and methods for producing same 失效有机酸和β-二酮的金属盐的复合物及其制备方法公开(公告)号：US06872854B2
公开(公告)日：2005-03-29
申请号：US10190130
申请日：2002-07-03
CPC分类号： C09K15/06 , C08K5/0091 , Y10T428/13 , Y10T428/273
摘要： Metal salts of organic acids complexed with β-diketone compounds are multifunctional complexes useful in the formulation of stabilizers for halogenated resins. These complexes may be used jointly with other low toxicity intermediates, such as zinc or magnesium intermediates, to form effective stabilizers that are non-toxic and exhibit better performance than other known stabilizers, including those containing toxic heavy metals such as cadmium or lead. The complex is prepared utilizing a Claisen condensation reaction and precipitation with water and heptane.
摘要翻译： 与β-二酮化合物络合的有机酸的金属盐是可用于配制卤化树脂稳定剂的多官能络合物。 这些络合物可以与其他低毒中间体如锌或镁中间体一起使用，以形成无毒的有效稳定剂，并且比其它已知的稳定剂（包括含有有毒重金属如镉或铅的稳定剂）具有更好的性能。 该复合物采用Claisen缩合反应制备，并用水和庚烷沉淀。
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3.发明授权公开(公告)号：US06756431B2
公开(公告)日：2004-06-29
申请号：US10119443
申请日：2002-04-09
申请人： Mukund Shah , Michael H. Fisch , Ulrich Stewen , Radu Bacaloglu
发明人： Mukund Shah , Michael H. Fisch , Ulrich Stewen , Radu Bacaloglu
IPC分类号： C08K534
CPC分类号： C08K5/5442 , C08L27/06
摘要： Heterocyclic tin compounds, useful as flame retardants and/or as smoke suppressants for halogen-containing polymers, e.g., polyvinyl chloride resins having application as wire and cable coatings, are obtained by reacting a trisubstituted triazine such as melamine with a tin-containing compound such as tin tetrachloride.
摘要翻译： 通过使诸如三聚氰胺的三取代三嗪与含锡化合物反应，得到用作含卤素聚合物的阻燃剂和/或作为阻燃剂的杂环锡化合物，例如作为电线和电缆涂层的应用的聚氯乙烯树脂， 作为四氯化锡。
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公开(公告)号：US07282527B2
公开(公告)日：2007-10-16
申请号：US10643800
申请日：2003-08-19
申请人： Edward Krainer , Radu Bacaloglu , Mukund Shah , Michael H. Fisch , Peter Frenkel , Kook Jin Bae
发明人： Edward Krainer , Radu Bacaloglu , Mukund Shah , Michael H. Fisch , Peter Frenkel , Kook Jin Bae
摘要： A method is disclosed for stabilizing a halogen-containing polymer wherein the method comprises adding to said polymer a thermally stabilizing amount of a mixture comprising at least one polyalkylene glycol and at least one metal salt of a strong acid selected from the group consisting of perchloric acid, trifluoroacetic acid, trifluoromethanesulfonic acid, alkylsulfuric acid, phosphotungstic acid, HPF6, HBF4, and HSbF6.
摘要翻译： 公开了用于稳定含卤素聚合物的方法，其中所述方法包括向所述聚合物中加入热稳定量的包含至少一种聚亚烷基二醇和至少一种强酸金属盐的混合物，所述强酸金属盐选自高氯酸 三氟乙酸，三氟甲磺酸，烷基硫酸，磷钨酸，HPF 6，HBF 4和HSbF 6。
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5.发明授权公开(公告)号：US06410795B1
公开(公告)日：2002-06-25
申请号：US09769429
申请日：2001-01-26
申请人： Michael H. Fisch , Edward Krainer , Radu Bacaloglu
发明人： Michael H. Fisch , Edward Krainer , Radu Bacaloglu
IPC分类号： C07C4572
CPC分类号： C07C45/455 , C07C29/70 , C07C2601/14 , Y02P20/582 , C07C49/76 , C07C49/14 , C07C49/792 , C07C49/784 , C07C31/30 , C07C35/46 , C07C33/22 , C07C33/24
摘要： A method for the preparation of 1,3-diketones is disclosed wherein the method comprises the steps of: (A) mixing an alkali metal base with a hindered alcohol in an aromatic hydrocarbon solvent; (B) boiling the mixture and azeotropically distilling water formed by the reaction between the base and the alcohol, whereby a solution of a hindered alkali metal alkoxide is formed in situ in the solvent; (C) mixing an ester with the solution of the hindered alkali metal alkoxide in the aromatic hydrocarbon solvent; and then (D) adding a ketone to the mixture.
摘要翻译： 公开了一种制备1,3-二酮的方法，其中所述方法包括以下步骤：（A）将碱金属碱与受阻醇在芳族烃溶剂中混合;（B）沸腾混合物并共沸蒸馏形成的水 通过碱和醇之间的反应，由此在溶剂中原位形成受阻碱金属醇盐溶液;（C）将酯与受阻碱金属醇盐的溶液在芳烃溶剂中混合; 然后（D）向混合物中加入酮。
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公开(公告)号：US5055606A
公开(公告)日：1991-10-08
申请号：US588476
申请日：1990-09-25
IPC分类号： C07C319/28 , C07C323/52
CPC分类号： C07C319/28
摘要： 3-alkylthiopropionic acids which are esterified with pentaerythritol are provided. The esters are solvent refined with especially effective organic solvent blends. Tetraesters thus processed are especially useful as stabilizers for polymer resins and polymers.
摘要翻译： 提供了用季戊四醇酯化的3-烷基硫代丙酸。 酯是用特别有效的有机溶剂混合物进行溶剂精制。 如此处理的四酯特别可用作聚合物树脂和聚合物的稳定剂。
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7.发明授权Preparation of a 2-aralkyl-5,5-dialkyl-1,3,2-dioxaphosphorinan-2-one from 2-aralkoxy-5,5-dialkyl-1,3,2-dioxaphosphorinane 失效由2-芳烷氧基-5,5-二烷基-1,3,2-二氧杂磷杂环己烷制备2-芳烷基-5,5-二烷基-1,3,2-二氧杂磷杂环己烷-2-酮
公开(公告)号：US4420437A
公开(公告)日：1983-12-13
申请号：US290532
申请日：1981-08-06
IPC分类号： C07F9/6571 , C07F9/6574 , C08K5/5357 , C07F9/40
CPC分类号： C08K5/5357 , C07F9/657181 , C07F9/65742
摘要： A process for preparing a 2-aralkyl-5,5-dialkyl-1,3,2-dioxaphosphorinan-2-one by heating a 2-aralkyloxy-5,5-dialkyl-1,3,2-dioxaphosphorinane such as the novel 2-benzyloxy-5,5-dimethyl-1,3,2-dioxaphosphorinane, with a catalytic quantity of an aralkyl halide. The aralkyl halide can be recovered and recycled.
摘要翻译： 通过加热2-芳烷氧基-5,5-二烷基-1,3,2-二氧杂磷杂环己烷如新颖的制备2-芳烷基-5,5-二烷基-1,3,2-二氧杂磷杂环己烷-2-酮的方法 2-苄氧基-5,5-二甲基-1,3,2-二氧杂磷杂环己烷与催化量的芳烷基卤化物反应。 可以回收和再循环芳烷基卤化物。
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公开(公告)号：US4374945A
公开(公告)日：1983-02-22
申请号：US242741
申请日：1981-03-11
申请人： Koei-Liang Liauw , Michael H. Fisch
发明人： Koei-Liang Liauw , Michael H. Fisch
IPC分类号： C07D303/16 , C08G59/30 , C08K5/378 , C07D407/12 , C07D303/42 , C07D303/44 , C08K5/36 , C08K5/56 , C08K5/57 , C08K5/58
CPC分类号： C08K5/378 , C07D303/16 , C08G59/302
摘要： Certain substituted thioglycolates and thiopropionates were found useful as secondary stabilizers for polymers, particularly polyvinyl chloride, when used in conjunction with metal octanoates, such as zinc octanoate, as the primary stabilizer. The specific thioglycolates and thiopropionates are those formed by thio adducts to the double bond of a monomer, such as the product of reacting isooctyl thioglycolate with glycidyl acrylate, to provide isooctyl S-2(glycidyloxycarbonyl)ethyl thioglycolate, as an example.
摘要翻译： 发现某些取代的巯基乙酸酯和硫代丙酸盐可用作聚合物的二级稳定剂，特别是聚氯乙烯，当与辛酸金属盐如辛酸锌一起用作主要的稳定剂时。 具体的巯基乙酸酯和硫代丙酸酯是通过硫代加合物与单体的双键形成的那些，例如巯基乙酸异辛酯与丙烯酸缩水甘油酯反应的产物，以提供巯基乙酸异辛酯S-2（缩水甘油氧基羰基）乙基酯为例。
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公开(公告)号：US5688847A
公开(公告)日：1997-11-18
申请号：US745010
申请日：1996-11-07
IPC分类号： C07F9/6574 , C08K5/527 , C07K5/51
CPC分类号： C08K5/527 , C07F9/65746 , C07F9/65748
摘要： Disclosed is a fluorophosphite compound of the formula ##STR1## This compound shows superior performance as a stabilizer in polymers, such as polypropylene, and polyvinyl chloride. Also disclosed is a process for making this compound.
摘要翻译： 公开了下式的氟亚磷酸酯化合物：（I）该化合物表现出作为聚合物如聚丙烯和聚氯乙烯的稳定剂的优异性能。 还公开了制备该化合物的方法。
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公开(公告)号：US5198486A
公开(公告)日：1993-03-30
申请号：US770991
申请日：1991-10-01
IPC分类号： C07C319/18 , C07C323/52 , C08K5/38
CPC分类号： C08K5/38 , C07C319/18
摘要： 3-alkylthiopropionic acids are provided which are a direct addition reaction product of an alkylmercaptan and acrylic acid or an alkali metal salt thereof, the reaction being carried out by heating the reactants in the presence of an aqueous alkaline solution having a pH of at least about 11. The acids can be esterified with pentaerythritol in order to form tetraesters which are especially useful as stabilizers for polymer resins and polymers.
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