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1.发明授权Complexes of metal salts of organic acids and beta-diketones and methods for producing same 失效有机酸和β-二酮的金属盐的复合物及其制备方法公开(公告)号：US06872854B2
公开(公告)日：2005-03-29
申请号：US10190130
申请日：2002-07-03
CPC分类号： C09K15/06 , C08K5/0091 , Y10T428/13 , Y10T428/273
摘要： Metal salts of organic acids complexed with β-diketone compounds are multifunctional complexes useful in the formulation of stabilizers for halogenated resins. These complexes may be used jointly with other low toxicity intermediates, such as zinc or magnesium intermediates, to form effective stabilizers that are non-toxic and exhibit better performance than other known stabilizers, including those containing toxic heavy metals such as cadmium or lead. The complex is prepared utilizing a Claisen condensation reaction and precipitation with water and heptane.
摘要翻译： 与β-二酮化合物络合的有机酸的金属盐是可用于配制卤化树脂稳定剂的多官能络合物。 这些络合物可以与其他低毒中间体如锌或镁中间体一起使用，以形成无毒的有效稳定剂，并且比其它已知的稳定剂（包括含有有毒重金属如镉或铅的稳定剂）具有更好的性能。 该复合物采用Claisen缩合反应制备，并用水和庚烷沉淀。
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2.发明授权Overbased metal carbonate/carboxylate microemulsions and halogen-containing polymers containing same 失效高碱性金属碳酸盐/羧酸盐微乳液和含有其的含卤素聚合物公开(公告)号：US06835328B2
公开(公告)日：2004-12-28
申请号：US10669955
申请日：2003-09-24
申请人： Julius Fakinlede , Michael H. Fisch , Ulrich Stewen , Radu Bacaloglu , Shah Mukund , Ilze Bacaloglu , Wahib I. Farahat
发明人： Julius Fakinlede , Michael H. Fisch , Ulrich Stewen , Radu Bacaloglu , Shah Mukund , Ilze Bacaloglu , Wahib I. Farahat
IPC分类号： C09K1506
摘要： A metal carbonate/carboxylate microemulsion imparting static and dynamic thermal stability to a halogen-containing polymer is provided which comprises (a) a metal carbonate/carboxylate obtained from the reaction of an oxide and/or hydroxide of a metal selected from the group consisting of sodium, potassium, calcium, magnesium, zinc and mixtures thereof and an aliphatic acid in which the aliphatic moiety contains up to about 30 carbon atoms and carbon dioxide in an oil; b) one or more non-phenolic compounds having about two or about three hydroxyl groups; and, c) one or more polyols, alcohol ethoxylates and/or alcohol propoxylates having from about 6 to about 24 carbon atoms in the alcohol and/or 0 to 3 ethylene oxide units and/or 0 to 3 propylene oxide units.
摘要翻译： 提供赋予含卤素聚合物静态和动态热稳定性的金属碳酸盐/羧酸盐微乳液，其包含（a）由氧化物和/或氢氧化物与选自以下的金属的反应得到的金属碳酸盐/羧酸盐： 钠，钾，钙，镁，锌及其混合物和其中脂族部分含有至多约30个碳原子的脂族酸和油中的二氧化碳; b）一种或多种具有约2或约3个 羟基; 和c）在醇和/或0-3个环氧乙烷单元和/或0-3个环氧丙烷单元中具有约6至约24个碳原子的一种或多种多元醇，醇乙氧基化物和/或醇丙氧基化物。
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3.发明申请Liquid microemulsion stabilizer composition for halogen-containing polymers 审中-公开含卤素聚合物的液体微乳液稳定剂组合物公开(公告)号：US20050101716A1
公开(公告)日：2005-05-12
申请号：US10712824
申请日：2003-11-12
申请人： Ilze Bacaloglu , Radu Bacaloglu , Michael Fisch , Ulrich Stewen , Stuart Brilliant , Kook Bae , Perry Reed , Julius Fakinlede , Wahib Farahat
发明人： Ilze Bacaloglu , Radu Bacaloglu , Michael Fisch , Ulrich Stewen , Stuart Brilliant , Kook Bae , Perry Reed , Julius Fakinlede , Wahib Farahat
CPC分类号： C08K5/57 , C08K5/0091 , C08L57/08
摘要： A liquid microemulsion stabilizer for chlorinated polymers composition for stabilizing halogen-containing polymer comprising: a) a microemulsion of an overbased metal carbonate/carboxylate obtained from the reaction of an oxide and/or hydroxide of a metal selected from the group consisting of sodium, potassium, calcium, magnesium, zinc and mixtures thereof, an aliphatic carboxylic acid in which the aliphatic moiety contains up to about 30 carbon atoms and carbon dioxide in the presence of a solvent for the aliphatic carboxylic acid, a promoter and a microemulsion-forming amount of surfactant; and, b) an organotin stabilizer.
摘要翻译： 一种用于稳定含卤素聚合物的氯化聚合物组合物的液体微乳液稳定剂，包括：a）从金属的氧化物和/或氢氧化物的反应获得的高碱性金属碳酸盐/羧酸盐的微乳液，其选自钠，钾 ，钙，镁，锌及其混合物，其中脂族部分含有至多约30个碳原子的脂族羧酸和二醇在脂族羧酸的溶剂存在下，促进剂和微乳液形成量 表面活性剂 和b）有机锡稳定剂。
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公开(公告)号：US07282527B2
公开(公告)日：2007-10-16
申请号：US10643800
申请日：2003-08-19
申请人： Edward Krainer , Radu Bacaloglu , Mukund Shah , Michael H. Fisch , Peter Frenkel , Kook Jin Bae
发明人： Edward Krainer , Radu Bacaloglu , Mukund Shah , Michael H. Fisch , Peter Frenkel , Kook Jin Bae
摘要： A method is disclosed for stabilizing a halogen-containing polymer wherein the method comprises adding to said polymer a thermally stabilizing amount of a mixture comprising at least one polyalkylene glycol and at least one metal salt of a strong acid selected from the group consisting of perchloric acid, trifluoroacetic acid, trifluoromethanesulfonic acid, alkylsulfuric acid, phosphotungstic acid, HPF6, HBF4, and HSbF6.
摘要翻译： 公开了用于稳定含卤素聚合物的方法，其中所述方法包括向所述聚合物中加入热稳定量的包含至少一种聚亚烷基二醇和至少一种强酸金属盐的混合物，所述强酸金属盐选自高氯酸 三氟乙酸，三氟甲磺酸，烷基硫酸，磷钨酸，HPF 6，HBF 4和HSbF 6。
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5.发明授权公开(公告)号：US06756431B2
公开(公告)日：2004-06-29
申请号：US10119443
申请日：2002-04-09
申请人： Mukund Shah , Michael H. Fisch , Ulrich Stewen , Radu Bacaloglu
发明人： Mukund Shah , Michael H. Fisch , Ulrich Stewen , Radu Bacaloglu
IPC分类号： C08K534
CPC分类号： C08K5/5442 , C08L27/06
摘要： Heterocyclic tin compounds, useful as flame retardants and/or as smoke suppressants for halogen-containing polymers, e.g., polyvinyl chloride resins having application as wire and cable coatings, are obtained by reacting a trisubstituted triazine such as melamine with a tin-containing compound such as tin tetrachloride.
摘要翻译： 通过使诸如三聚氰胺的三取代三嗪与含锡化合物反应，得到用作含卤素聚合物的阻燃剂和/或作为阻燃剂的杂环锡化合物，例如作为电线和电缆涂层的应用的聚氯乙烯树脂， 作为四氯化锡。
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6.发明授权公开(公告)号：US06410795B1
公开(公告)日：2002-06-25
申请号：US09769429
申请日：2001-01-26
申请人： Michael H. Fisch , Edward Krainer , Radu Bacaloglu
发明人： Michael H. Fisch , Edward Krainer , Radu Bacaloglu
IPC分类号： C07C4572
CPC分类号： C07C45/455 , C07C29/70 , C07C2601/14 , Y02P20/582 , C07C49/76 , C07C49/14 , C07C49/792 , C07C49/784 , C07C31/30 , C07C35/46 , C07C33/22 , C07C33/24
摘要： A method for the preparation of 1,3-diketones is disclosed wherein the method comprises the steps of: (A) mixing an alkali metal base with a hindered alcohol in an aromatic hydrocarbon solvent; (B) boiling the mixture and azeotropically distilling water formed by the reaction between the base and the alcohol, whereby a solution of a hindered alkali metal alkoxide is formed in situ in the solvent; (C) mixing an ester with the solution of the hindered alkali metal alkoxide in the aromatic hydrocarbon solvent; and then (D) adding a ketone to the mixture.
摘要翻译： 公开了一种制备1,3-二酮的方法，其中所述方法包括以下步骤：（A）将碱金属碱与受阻醇在芳族烃溶剂中混合;（B）沸腾混合物并共沸蒸馏形成的水 通过碱和醇之间的反应，由此在溶剂中原位形成受阻碱金属醇盐溶液;（C）将酯与受阻碱金属醇盐的溶液在芳烃溶剂中混合; 然后（D）向混合物中加入酮。
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公开(公告)号：US20050043451A1
公开(公告)日：2005-02-24
申请号：US10643800
申请日：2003-08-19
申请人： Edward Krainer , Radu Bacaloglu , Mukund Shah , Michael Fisch , Peter Frenkel , Kook Bae
发明人： Edward Krainer , Radu Bacaloglu , Mukund Shah , Michael Fisch , Peter Frenkel , Kook Bae
摘要： A method is disclosed for stabilizing a halogen-containing polymer wherein the method comprises adding to said polymer a thermally stabilizing amount of a mixture comprising at least one polyalkylene glycol and at least one metal salt of a strong acid selected from the group consisting of perchloric acid, trifluoroacetic acid, trifluoromethanesulfonic acid, alkylsulfuric acid, phosphotungstic acid, HPF6, HBF4, and HSbF6
摘要翻译： 公开了用于稳定含卤素聚合物的方法，其中所述方法包括向所述聚合物中加入热稳定量的包含至少一种聚亚烷基二醇和至少一种强酸金属盐的混合物，所述强酸金属盐选自高氯酸 ，三氟乙酸，三氟甲磺酸，烷基硫酸，磷钨酸，HPF6，HBF4和HSbF6
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公开(公告)号：US5888427A
公开(公告)日：1999-03-30
申请号：US870968
申请日：1997-06-06
CPC分类号： C08K5/098
摘要： An overbased mixture of aliphatic and aromatic carboxylates salts useful in making low-fogging thermal stabilizers for PVC is made by reacting zinc oxide with fatty acid and such as stearic acid, then adding aromatic acids, and then adding and reacting one or both of magnesium oxide and calcium oxide, under controlled heating conditions to maintain fluidity while minimizing side reactions, and then conditioning the reaction product to remove volatiles.
摘要翻译： 通过使氧化锌与脂肪酸如硬脂酸反应，然后加入芳香酸，然后加入和反应一种或两种氧化镁，可制备用于制备PVC低雾热稳定剂的脂肪族和芳香族羧酸盐的高碱性混合物 和氧化钙，在受控的加热条件下保持流动性，同时使副反应最小化，然后调理反应产物以除去挥发物。
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公开(公告)号：US20060116447A1
公开(公告)日：2006-06-01
申请号：US11001558
申请日：2004-11-30
IPC分类号： C08L89/00
CPC分类号： C08L27/06 , C08J5/045 , C08J2327/06 , C08K5/005 , C08L33/02 , C08L97/02 , C08L2666/02 , C08L2666/04
摘要： Disclosed herein is a process for improving mechanical properties and thermal stability of composites of poly(vinyl chloride) and at least one natural fiber comprising including in said composite an agent comprising a polymer or copolymer comprising at least one alkali metal salt of at least one polymerized ethylenically unsaturated carboxylic acid. Articles of manufacture comprising the stabilized PVC are also disclosed.
摘要翻译： 本文公开了一种用于改善聚（氯乙烯）和至少一种天然纤维的复合材料的机械性能和热稳定性的方法，包括在所述复合材料中包含包含至少一种聚合的 烯属不饱和羧酸。 还公开了包含稳定的PVC的制品。
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公开(公告)号：US5656202A
公开(公告)日：1997-08-12
申请号：US492627
申请日：1995-06-20
CPC分类号： C08K5/098
摘要： An overbased mixture of aliphatic and aromatic carboxylates salts useful in making low-fogging thermal stabilizers for PVC is made by reacting zinc oxide with fatty acid and such as stearic acid, then adding aromatic acids, and then adding and reacting one or both of magnesium oxide and calcium oxide, under controlled heating conditions to maintain fluidity while minimizing side reactions, and then conditioning the reaction product to remove volatiles.
摘要翻译： 通过使氧化锌与脂肪酸如硬脂酸反应，然后加入芳香酸，然后加入和反应一种或两种氧化镁，可制备用于制备PVC低雾热稳定剂的脂肪族和芳香族羧酸盐的高碱性混合物 和氧化钙，在受控的加热条件下保持流动性，同时使副反应最小化，然后调理反应产物以除去挥发物。
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