公开(公告)号：US06838570B2

公开(公告)日：2005-01-04

申请号：US10181984

申请日：2001-01-29

申请人： Jun Yamamoto ,  Junpei Tsuji

发明人： Jun Yamamoto ,  Junpei Tsuji

IPC分类号： B01J21/06 ,  B01J21/08 ,  B01J35/10 ,  B01J37/00 ,  B01J29/06

CPC分类号： B01J21/063 ,  B01J21/08 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0018

摘要： A titanium-containing silicon oxide molded catalyst satisfying all of the following conditions (1) to (4): (1) an average pore diameter is 10 Å or more, (2) 90% or more of the whole pore volume have pore diameters of 5 to 200 Å, (3) a specific pore volume is 0.2 cm3/g or more, and (4) it is obtained by using as a template a quaternary ammonium ion of the following general formula (I) or an amine of the following general formula (II), then, removing the template. [NR1R2R3R4]+  (I) (in the formula (I), R1 represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R2 to R4 represent an alkyl group having 1 to 6 carbon atoms.) NR5R6R7  (II) (in the formula (II), R5 represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R6 and R7 represent hydrogen or an alkyl group having 1 to 6 carbon atoms.).

摘要翻译： 满足以下条件（1）〜（4）：（1）的平均孔径的含钛氧化硅成型催化剂为10以上，（2）整个孔体积的90％以上具有孔径 为5〜200埃，（3）比孔体积为0.2cm 3 / g以上，（4）以下述通式（I）表示的季铵离子或 （II）的胺，然后除去模板（式（I）中，R 1表示碳原子数2〜36的直链状或支链状的烃基，R 2〜 （式中，R 5表示碳原子数为2〜36的直链状或支链状的烃基，R 6和R 7表示碳原子数1〜6的烷基。 代表氢或具有1至6个碳原子的烷基。

公开(公告)号：US06323147B1

公开(公告)日：2001-11-27

申请号：US09364268

申请日：1999-07-30

申请人： Jun Yamamoto ,  Junpei Tsuji

发明人： Jun Yamamoto ,  Junpei Tsuji

IPC分类号： B01J2906

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1066 ,  B01J35/108 ,  C07D303/04 ,  Y02P20/52

摘要： A titanium-containing silicon oxide catalyst satisfying all of the following conditions (1) to (4): (1): an average pore size of 10 Å or more, (2): a pore size of 90% or more of the total pore volume of 5 to 200 Å, (3): a specific pore volume of 0.2 cm3/g or more, and (4): a quarternary ammonium ion represented by the following general formula (I) is used as a template and then said template is removed by solvent extraction operation; [NR1R2R3R4]+  (I) wherein, R1 represents a linear or branched hydrocarbon chain having 2 to 36 carbon atoms, and R2 to R4 represent an alkyl group having 1 to 6 carbon atoms, a method for producing said catalyst, and a method for producing propylene oxide by reacting propylene with a hydroperoxide, except for ethylbenzene hydroperoxide, in the presence of said catalyst.

摘要翻译： 满足以下所有条件（1）〜（4）：（1）的含钛氧化硅催化剂：平均孔径为10以上，（2）：孔径为总计的90％以上 孔体积为5〜200，（3）：比孔体积为0.2cm 3 / g以上，（4）：以下述通式（I）表示的季铵离子作为模板， 通过溶剂萃取操作除去模板;其中，R1表示碳原子数2〜36的直链或支链烃链，R2〜R4表示碳原子数1〜6的烷基，所述催化剂的制造方法， 用于在所述催化剂存在下，通过丙烯与氢过氧化物反应制备环氧丙烷，除了乙苯氢过氧化物。

公开(公告)号：US06512128B2

公开(公告)日：2003-01-28

申请号：US09967982

申请日：2001-10-02

申请人： Jun Yamamoto ,  Junpei Tsuji

发明人： Jun Yamamoto ,  Junpei Tsuji

IPC分类号： C07D30119

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1066 ,  B01J35/108 ,  C07D303/04 ,  Y02P20/52

摘要： A titanium-containing silicon oxide catalyst satisfying all of the following conditions (1) to (4): (1): an average pore size of 10 Å or more, (2): a pore size of 90% or more of the total pore volume of 5 to 200 Å, (3): a specific pore volume of 0.2 cm3/g or more, and (4): a quarternary ammonium ion represented by the following general formula (I) is used as a template and then said template is removed by solvent extraction operation; [NR1R2R3R4]+  (I) wherein, R1 represents a linear or branched hydrocarbon chain having 2 to 36 carbon atoms, and R2 to R4 represent an alkyl group having 1 to 6 carbon atoms, a method for producing said catalyst, and a method for producing propylene oxide by reacting propylene with a hydroperoxide, except for ethylbenzene hydroperoxide, in the presence of said catalyst.

摘要翻译： 满足以下所有条件（1）〜（4）：（1）的含钛氧化硅催化剂：平均孔径为10以上，（2）：孔径为总计的90％以上 孔体积为5〜200，（3）：比孔体积为0.2cm 3 / g以上，（4）：以下述通式（I）表示的季铵离子作为模板， 通过溶剂萃取操作除去模板;其中，R1表示碳原子数2〜36的直链或支链烃链，R2〜R4表示碳原子数1〜6的烷基，所述催化剂的制造方法， 用于在所述催化剂存在下，通过丙烯与氢过氧化物反应制备环氧丙烷，除了乙苯氢过氧化物。

公开(公告)号：US06887823B2

公开(公告)日：2005-05-03

申请号：US10470381

申请日：2002-01-25

申请人： Jun Yamamoto ,  Junpei Tsuji

发明人： Jun Yamamoto ,  Junpei Tsuji

IPC分类号： C07D301/19 ,  B01J21/06 ,  B01J21/08 ,  B01J29/03 ,  B01J29/89 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C01B39/00 ,  C07B61/00 ,  C07D303/04

CPC分类号： B01J35/10 ,  B01J21/063 ,  B01J29/0308 ,  B01J29/89 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0018

摘要： A process for producing a titanium-containing silicon oxide catalyst satisfying the following conditions, which comprises the following steps: (1): an average pore diameter of 10 Å or more, (2): a pore diameter of 90% or more of the total pore volume of 5 to 200 Å, (3): a specific pore volume of 0.2 cm3/g or more, and (4): a quaternary ammonium ion represented by the following general formula (I) is used as the template and then the template is removed by solvent extraction, [NR1R2R3R4]+  (I) (wherein, R1 represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R2 to R4 represent an alkyl group having 1 to 6 carbon atoms); first step: a step for obtaining a solid containing a catalyst component and a template by mixing and stirring a silica source, a titanium source and a template in liquid phase, second step: a step of drying the solid obtained in the first step under a condition of a temperature of 120° C. or less, and third step: a step of removing the template by subjecting the solid dried in the second step to solvent extraction.

摘要翻译： 一种满足以下条件的含钛氧化硅催化剂的制造方法，包括以下步骤：（1）平均孔径为10以上，（2）：孔径为90％以上的孔径 总孔体积为5〜200，（3）：比孔容为0.2cm 3 / g以上，（4）：下述通式（I）表示的季铵离子 ）作为模板，然后通过溶剂萃取去除模板，<？in-line-formula description =“In-line Formulas”end =“lead”？> [NR <1> （I）在线公式描述=“在线 （式中，R 1表示碳原子数2〜36的直链状或支链状的烃基，R 2，R 2，R 2， 4表示具有1至6个碳原子的烷基）; 第一步骤：通过在液相中混合和搅拌二氧化硅源，钛源和模板来获得含有催化剂组分和模板的固体的步骤;第二步：在第一步骤中获得的固体的干燥步骤 温度为120℃以下的条件，第三工序：通过将第二工序中干燥的固体进行溶剂萃取而除去模板的工序。

公开(公告)号：US06639085B2

公开(公告)日：2003-10-28

申请号：US10221357

申请日：2002-09-12

申请人： Junpei Tsuji ,  Jun Yamamoto

发明人： Junpei Tsuji ,  Jun Yamamoto

IPC分类号： C07D30119

CPC分类号： C07D301/19

摘要： A process for producing propylene oxide, which comprises steps described below, wherein the concentration of water in a solution containing isopropylbenzene hydroperoxide to be supplied to the epoxidation step is 1% by weight or less: oxidation step; a step in which isopropylbenzene is oxidized to obtain isopropylbenzene hydroperoxide, epoxidation step; a step in which isopropylbenzene hydroperoxide obtained in the oxidation step is reacted with propylene to obtain propylene oxide and cumyl alcohol, and hydrogenolysis step; a step in which cumyl alcohol obtained in the epoxidation step is subjected to hydrogenolysis to obtain isopropylbenzene, and said isopropylbenzene is recycled to the oxidation step as a raw material for the oxidation step.

摘要翻译： 一种生产环氧丙烷的方法，其包括下述步骤，其中供给环氧化步骤的含有异丙苯氢过氧化物的溶液中的水的浓度为1重量％以下：氧化步骤; 异丙苯氧化得到异丙基苯氢过氧化物的步骤，环氧化步骤; 在氧化步骤中得到的异丙基苯氢过氧化物与丙烯反应得到环氧丙烷和枯
醇，并进行氢解步骤; 将在环氧化步骤中得到的异丙醇进行氢解以获得异丙基苯的步骤，并将所述异丙基苯循环到氧化步骤作为氧化步骤的原料。

公开(公告)号：US06211388B1

公开(公告)日：2001-04-03

申请号：US09414555

申请日：1999-10-08

申请人： Junpei Tsuji ,  Jun Yamamoto ,  Avelino Corma Canos ,  Fernando Rey Garcia

发明人： Junpei Tsuji ,  Jun Yamamoto ,  Avelino Corma Canos ,  Fernando Rey Garcia

IPC分类号： C07D30112

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1076 ,  B01J35/108 ,  Y02P20/52

摘要： A method for producing propylene oxide by reacting propylene with ethylbenzene hydroperoxide, wherein the reaction is conducted in the presence of a catalyst comprising a titanium-containing silicon oxide and satisfying all of the following conditions (1) to (6): (1) there is at least one peak showing a interplanar spacing (d) larger than 18 Å in X-ray diffraction; (2) an average pore size is 10 Å or more; (3) a pore size of 90% or more of the total pore volume is 5 to 200 Å; (4) a specific pore volume is 0.2 cm3/g or more; (5) a quaternary ammonium ion represented by the following general formula (I) is used as a template and then said template is removed by calcination operation: [NR1R2R3R4]+  (I) wherein R1 represents a linear or branched hydrocarbon chain having 2 to 36 carbon atoms, and R2 to R4 represent an alkyl group having 1 to 6 carbon atoms; and (6) The catalyst has been subjected to silylation treatment.

摘要翻译： 一种通过丙烯与氢过氧化苯反应生产环氧丙烷的方法，其中反应在包含含钛氧化硅的催化剂存在下进行，并满足以下所有条件（1）至（6）：（1） 是在X射线衍射中显示出大于18的晶面间距（d）的至少一个峰;（2）平均孔径为10埃以上;（3）总孔径的90％以上的孔径 体积为5〜200;（4）比孔体积为0.2cm 3 / g以上;（5）以下述通式（I）表示的季铵离子作为模板，将所述模板用 煅烧操作：其中R1表示具有2至36个碳原子的直链或支链烃链，R 2至R 4表示具有1至6个碳原子的烷基; 和（6）催化剂已进行甲硅烷基化处理。

公开(公告)号：US6096910A

公开(公告)日：2000-08-01

申请号：US364267

申请日：1999-07-30

申请人： Jun Yamamoto ,  Junpei Tsuji

发明人： Jun Yamamoto ,  Junpei Tsuji

IPC分类号： C07D303/00 ,  B01J29/89 ,  B01J35/10 ,  C07D301/19 ,  C07D303/04

CPC分类号： C07D301/19 ,  B01J29/89 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  C07D303/04 ,  Y02P20/52

摘要： A process for producing propylene oxide by reacting propylene with ethylbenzene hydroperoxide in the presence of a titanium-containing silicon oxide catalyst satisfying all of the following conditions (1) to (4):(1): an average pore size of 10 .ANG. or more,(2): a pore size of 90% or more of the total pore volume of 5 to 200 .ANG.,(3): a specific pore volume of 0.2 cm.sup.3 /g or more, and(4): a quarternary ammonium ion represented by the following general formula (I) is used as a template and then said template is removed by solvent extraction operation;[NR.sup.1 R.sup.2 R.sup.3 R.sup.4 ].sup.+ (I) wherein, R.sup.1 represents a linear or branched hydrocarbon chain having 2 to 36 carbon atoms, and R.sup.2 to R.sup.4 represent an alkyl group having 1 to 6 carbon atoms.

摘要翻译： 一种在满足以下所有条件（1）至（4）的含钛氧化硅催化剂的存在下，使丙烯与乙苯氢过氧化物反应生产环氧丙烷的方法：（1）：平均孔径为10以上 ，（2）：总孔体积的孔径为5〜200的孔径，（3）：比表面积体积为0.2cm 3 / g以上，（4）：表示的季铵离子 通过以下通式（I）作为模板，然后通过溶剂提取操作除去所述模板; [NR1R2R3R4] +（Ⅰ）其中，R1表示碳原子数2〜36的直链或支链烃链，R2表示 R 4表示碳原子数1〜6的烷基。

公开(公告)号：US09062663B2

公开(公告)日：2015-06-23

申请号：US13513913

申请日：2010-11-26

申请人： Tetsuo Hino ,  Jun Yamamoto ,  Sakae Suda ,  Sotomitsu Ikeda

发明人： Tetsuo Hino ,  Jun Yamamoto ,  Sakae Suda ,  Sotomitsu Ikeda

IPC分类号： H01L41/193 ,  F03G7/00

CPC分类号： F03G7/005

摘要： A difference is arisen in the electric potential of the electrode layer between a fixed end portion and a displacement end portion of an actuator. The electrode layer includes a bundle of polymer fibers containing a conductive material. Longitudinal directions of the polymer fibers are arranged parallel to a direction from the fixed portion to the displacement end portion of the actuator.

摘要翻译： 在致动器的固定端部和位移端部之间的电极层的电位出现差异。 电极层包括含有导电材料的聚合物纤维束。 聚合物纤维的纵向方向平行于从致动器的固定部分到位移端部分的方向。

公开(公告)号：US08558434B2

公开(公告)日：2013-10-15

申请号：US13326172

申请日：2011-12-14

申请人： Sakae Suda ,  Jun Yamamoto

发明人： Sakae Suda ,  Jun Yamamoto

IPC分类号： H01L41/08

CPC分类号： F03G7/005

摘要： Provided are an electrode having high conductivity and high durability to driving deformation, and an actuator including the electrode, the actuator having a large amount of displacement. The actuator includes a pair of electrodes arranged oppositely and an intermediate layer arranged between the pair of electrodes, the intermediate layer containing an electrolyte, and the actuator being deformed by applying a voltage to the pair of electrodes, in which at least one of the pair of electrodes includes a porous structure containing a first conductive material and having conductivity, a second conductive material, and an electrolyte, pores of the porous structure being filled with the second conductive material and the electrolyte.

摘要翻译： 提供一种具有高导电性和对驱动变形的高耐久性的电极，以及包括电极的致动器，致动器具有大的位移。 致动器包括相对布置的一对电极和布置在该对电极之间的中间层，中间层包含电解质，并且致动器通过向该对电极施加电压而变形，其中至少一对电极 的电极包括含有第一导电材料并具有导电性的多孔结构，第二导电材料和电解质，多孔结构的孔填充有第二导电材料和电解质。

公开(公告)号：US08294329B2

公开(公告)日：2012-10-23

申请号：US12975216

申请日：2010-12-21

申请人： Jun Yamamoto ,  Sotomitsu Ikeda

发明人： Jun Yamamoto ,  Sotomitsu Ikeda

IPC分类号： H02N11/00

CPC分类号： F03G7/005

摘要： This invention provides a polymer actuator having a structure such that voltage can be efficiently applied to two or more actuator electrodes without directly providing an electrical contact point to an expanding and contracting portion.An actuator has: an insulating base material 1; a first terminal 2 for energizing provided contacting the insulating base material; a first actuator electrode 4 provided contacting the first terminal; an electrolyte layer 5 provided contacting the first actuator electrode; a second actuator electrode 6 provided contacting the electrolyte layer; a second terminal 3 for energizing provided spaced apart from the first terminal and contacting the insulating base material; an energization preventing portion 7 for preventing energization of the first terminal and the second terminal; and a connecting portion 8 provided contacting the energization preventing portion in order to energize the second actuator electrode and the second terminal.

摘要翻译： 本发明提供了一种聚合物致动器，其结构使得能够有效地将电压施加到两个或更多个致动器电极上，而不会直接向扩展和收缩部分提供电接触点。 致动器具有绝缘基材1; 提供接触绝缘基材的激励的第一端子2; 设置成与第一端子接触的第一致动器电极4; 设置成与第一致动器电极接触的电解质层5; 设置成与电解质层接触的第二致动器电极6; 用于通电的第二端子3，其与第一端子间隔开并且与绝缘基材接触; 防止第一端子和第二端子通电的通电防止部7; 以及连接部8，其设置成与通电防止部接触，以使第二致动器电极和第二端子通电。