公开(公告)号：US20110053051A1

公开(公告)日：2011-03-03

申请号：US12618868

申请日：2009-11-16

申请人： Jung Ki Park ,  Wan Keun Kim ,  Kyung A Sung ,  Ki Yun Cho ,  In Chul Hwang ,  Nak Hyun Kwon

发明人： Jung Ki Park ,  Wan Keun Kim ,  Kyung A Sung ,  Ki Yun Cho ,  In Chul Hwang ,  Nak Hyun Kwon

IPC分类号： H01M4/86 ,  H01M4/88

CPC分类号： H01M4/8668 ,  H01M4/8828 ,  H01M4/8882 ,  H01M4/92 ,  H01M2008/1095

摘要： The present invention provides an electrode binder for a polymer electrolyte membrane fuel cell which includes a hydrocarbon-based polymer and a water-soluble polymer acting as a porogen, a porous hydrocarbon-based electrode catalyst layer including the electrode binder, and a method of manufacturing the same. Because of the use of the porogen, the pore size and porosity of the hydrocarbon-based binder catalyst layer are optimized, and bondability of a hydrocarbon-based membrane electrode assembly is enhanced. The present invention also features a fuel cell manufactured using the porogen.

摘要翻译： 本发明提供了一种用于聚合物电解质膜燃料电池的电极粘合剂，其包括烃基聚合物和用作致孔剂的水溶性聚合物，包含电极粘合剂的多孔烃类电极催化剂层，以及制造方法 一样。 由于使用致孔剂，优化了烃类粘合剂催化剂层的孔径和孔隙率，并且提高了烃系膜电极接合体的结合性。 本发明还特征在于使用致孔剂制造的燃料电池。

公开(公告)号：US08092952B2

公开(公告)日：2012-01-10

申请号：US12229302

申请日：2008-08-20

申请人： In Chul Hwang ,  Nak Hyun Kwon ,  Ki Yun Cho ,  Young Taek Kim ,  Hee Woo Rhee ,  Li Jin Ghil

发明人： In Chul Hwang ,  Nak Hyun Kwon ,  Ki Yun Cho ,  Young Taek Kim ,  Hee Woo Rhee ,  Li Jin Ghil

IPC分类号： H01M8/10 ,  B01J49/00 ,  C08J5/20

CPC分类号： C08J5/2275 ,  C08J2371/00 ,  C08J2381/06 ,  H01M8/1016 ,  H01M2300/0068 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02P70/56

摘要： The present invention relates to a polymer blend electrolyte membrane comprising an inorganic polymer having polydimethylsiloxane as a main chain, which has a pore structure at both ends formed by condensation reaction between 3-aminopropyltriethoxysilane and tetraethylorthosilicate, wherein phosphoric acid is chemically linked to an amino group of the pore structure; and a proton-conducting polymer having a cation exchange group at the side chain thereof, as well as a manufacturing method thereof. Generally, proton-conducting electrolyte membranes have significantly reduced ion conductivity at high temperatures. However, proton-conducting electrolyte membranes have advantages in terms of efficiency and cost, and thus it is needed to develop an electrolyte membrane, which has excellent ion conductivity even at high temperature. Accordingly, the present invention aims to provide a polymer blend electrolyte membrane for use at high temperature and a manufacturing method thereof.

摘要翻译： 本发明涉及一种聚合物共混电解质膜，其包含具有聚二甲基硅氧烷作为主链的无机聚合物，其具有通过3-氨基丙基三乙氧基硅烷和原硅酸四乙酯之间的缩合反应形成的两端的孔结构，其中磷酸与氨基化学连接 的孔结构; 以及其侧链具有阳离子交换基团的质子传导性聚合物及其制造方法。 通常，质子传导电解质膜在高温下具有显着降低的离子传导性。 然而，质子传导性电解质膜在效率和成本方面具有优点，因此需要开发即使在高温下也具有优异的离子传导性的电解质膜。 因此，本发明的目的在于提供一种高温使用的高分子混合电解质膜及其制造方法。

公开(公告)号：US20090208848A1

公开(公告)日：2009-08-20

申请号：US12229302

申请日：2008-08-20

申请人： Ki Yun Cho ,  In Chul Hwang ,  Nak Hyun Kwon ,  Young Taek Kim ,  Hee Woo Rhee ,  Li Jin Ghil

发明人： Ki Yun Cho ,  In Chul Hwang ,  Nak Hyun Kwon ,  Young Taek Kim ,  Hee Woo Rhee ,  Li Jin Ghil

IPC分类号： H01M6/18

CPC分类号： C08J5/2275 ,  C08J2371/00 ,  C08J2381/06 ,  H01M8/1016 ,  H01M2300/0068 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02P70/56

摘要： The present invention relates to a polymer blend electrolyte membrane comprising an inorganic polymer having polydimethylsiloxane as a main chain, which has a pore structure at both ends formed by condensation reaction between 3-aminopropyltriethoxysilane and tetraethylorthosilicate, wherein phosphoric acid is chemically linked to an amino group of the pore structure; and a proton-conducting polymer having a cation exchange group at the side chain thereof, as well as a manufacturing method thereof. Generally, proton-conducting electrolyte membranes have significantly reduced ion conductivity at high temperatures. However, proton-conducting electrolyte membranes have advantages in terms of efficiency and cost, and thus it is needed to develop an electrolyte membrane, which has excellent ion conductivity even at high temperature. Accordingly, the present invention aims to provide a polymer blend electrolyte membrane for use at high temperature and a manufacturing method thereof.

摘要翻译： 本发明涉及一种聚合物共混电解质膜，其包含具有聚二甲基硅氧烷作为主链的无机聚合物，其具有通过3-氨基丙基三乙氧基硅烷和原硅酸四乙酯之间的缩合反应形成的两端的孔结构，其中磷酸与氨基化学连接 的孔结构; 以及其侧链具有阳离子交换基团的质子传导性聚合物及其制造方法。 通常，质子传导电解质膜在高温下具有显着降低的离子传导性。 然而，质子传导性电解质膜在效率和成本方面具有优点，因此需要开发即使在高温下也具有优异的离子传导性的电解质膜。 因此，本发明的目的在于提供一种高温使用的高分子混合电解质膜及其制造方法。

公开(公告)号：US07825057B2

公开(公告)日：2010-11-02

申请号：US11985810

申请日：2007-11-16

申请人： Nak Hyun Kwon ,  Yung Eun Sung ,  In Su Park ,  Yong Hun Cho ,  In Chul Hwang ,  Il Hee Cho

发明人： Nak Hyun Kwon ,  Yung Eun Sung ,  In Su Park ,  Yong Hun Cho ,  In Chul Hwang ,  Il Hee Cho

IPC分类号： B01J23/40 ,  B01J23/74 ,  B01J23/00 ,  B01J23/42 ,  B01J23/44 ,  C22C5/04 ,  C22C30/00 ,  H01M4/88 ,  H01M4/00

CPC分类号： H01M4/921 ,  H01M4/926 ,  H01M2008/1095

摘要： The present invention relates to a process for preparing electrode catalyst materials for a polymer electrolyte membrane fuel cell (PEMFC), and particularly to a high-performance platinum-non-platinum mixed electrode catalyst (Pt—RuOs/C) having a physically mixed structure of RuOs alloy and platinum materials, which is prepared by adding a small amount of platinum (Pt) to RuOs alloy materials highly dispersed on a carbon support, where the amount of platinum used is drastically reduced as compared to the conventional platinum materials, thus lowering the manufacturing cost.

摘要翻译： 本发明涉及一种制备聚合物电解质膜燃料电池（PEMFC）的电极催化剂材料的方法，特别涉及具有物理混合结构的高性能铂 - 非铂混合电极催化剂（Pt-RuO / C） 的RuO合金和铂材料，其通过向高度分散在碳载体上的RuO合金材料添加少量铂（Pt）而制备，其中与常规铂材料相比，所使用的铂的量显着降低，因此降低 制造成本。

公开(公告)号：US20100086821A1

公开(公告)日：2010-04-08

申请号：US12361076

申请日：2009-01-28

申请人： Nak Hyun Kwon ,  Tae Won Lim ,  In Chul Hwang ,  Byung Ki Ahn ,  Jae Seung Lee ,  Ki Sub Lee

发明人： Nak Hyun Kwon ,  Tae Won Lim ,  In Chul Hwang ,  Byung Ki Ahn ,  Jae Seung Lee ,  Ki Sub Lee

IPC分类号： H01M8/10 ,  H01M4/00 ,  B05D3/00

CPC分类号： H01M4/8828 ,  H01M4/8814 ,  H01M4/8882 ,  H01M2008/1095

摘要： The present invention provides a method for manufacturing a membrane-electrode assembly (MEA) which is a core element of a polymer electrolyte membrane fuel cell for a vehicle and an electrode therefor. The method for manufacturing an MEA of the present invention is implemented to provide a highly-concentrated catalyst slurry which is uniformly dispersed, compared to conventional catalyst slurries, by a catalyst slurry manufacturing process including a vacuum defoaming process.

摘要翻译： 本发明提供一种制造作为车辆用聚合物电解质膜燃料电池的核心元件的膜电极接合体（MEA）的制造方法及其电极。 实施本发明的MEA的制造方法，通过包括真空消泡处理的催化剂浆料制造方法，与传统的催化剂浆料相比，提供均匀分散的高浓度催化剂浆料。

公开(公告)号：US20090041653A1

公开(公告)日：2009-02-12

申请号：US11999969

申请日：2007-12-07

申请人： In Chul Hwang ,  Jong Heop Yi ,  Ji Bong Joo ,  Nak Hyun Kwon ,  Pil Kim

发明人： In Chul Hwang ,  Jong Heop Yi ,  Ji Bong Joo ,  Nak Hyun Kwon ,  Pil Kim

IPC分类号： C01B31/04

CPC分类号： H01M4/926 ,  B82Y30/00 ,  C01B32/20 ,  H01M4/92

摘要： The present invention relates to a process for preparing a porous graphite carbon with high crystallinity, which comprises the steps of: (a) hydrothermally treating sucrose (i.e. carbon precursor), transitional metal precursor and uniform-sized silica particles at the same time to prepare a polymer; and (b) carbonizing the polymer, which can provide a porous graphite carbon with remarkably improved crystallinity suitable for a catalyst support for a fuel cell.

摘要翻译： 本发明涉及一种制备具有高结晶度的多孔石墨碳的方法，其包括以下步骤：（a）同时水解热处理蔗糖（即碳前体），过渡金属前体和均匀二氧化硅颗粒，以制备 聚合物 和（b）碳化聚合物，其可以提供适合于燃料电池的催化剂载体的显着改善的结晶度的多孔石墨碳。

公开(公告)号：US08178622B2

公开(公告)日：2012-05-15

申请号：US12885841

申请日：2010-09-20

申请人： Won Ho Jo ,  Tae-Ann Kim ,  In Chul Hwang ,  Nak Hyun Kwon

发明人： Won Ho Jo ,  Tae-Ann Kim ,  In Chul Hwang ,  Nak Hyun Kwon

IPC分类号： C08F8/00 ,  C08F12/30 ,  C08F28/02 ,  C08F20/44 ,  C08F12/02 ,  C08F112/06

CPC分类号： H01M8/1023 ,  C08F8/36 ,  C08F293/00 ,  C08G65/48 ,  C08G75/23 ,  C08G2261/722 ,  C08G2650/40 ,  C08L71/00 ,  C08L2205/05 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1044 ,  H01M8/1072 ,  H01M2300/0082 ,  Y02P70/56 ,  C08L25/06 ,  C08L25/04 ,  C08F293/005

摘要： The present invention provides an amphiphilic block copolymer, a method for manufacturing the same, and a fuel cell membrane using the same. According to preferred embodiments, the amphiphilic block copolymer may contain poly(arylene sulfone ether ketone) (PSEK) as a hydrophobic component and poly(sulfonated styrene-co-acrylonitrile) (PSSAN) as a hydrophilic component. According to other preferred embodiments, polymer electrolyte membrane manufactured using the amphiphilic block copolymer has certain advantages in that the hydrogen ion conductivity is not reduced even at a high temperature of more than 100° C. but is rather increased and the thermal and chemical dimensional stability is excellent.

摘要翻译： 本发明提供两亲性嵌段共聚物，其制造方法和使用其的燃料电池膜。 根据优选的实施方案，两亲嵌段共聚物可以含有作为疏水组分的聚（亚芳基砜醚酮）（PSEK）和作为亲水组分的聚（磺化苯乙烯 - 共 - 丙烯腈）（PSSAN）。 根据其它优选实施方案，使用两亲性嵌段共聚物制造的聚合物电解质膜具有某些优点，即即使在高于100℃的高温下，氢离子传导性也不降低，但是相当增加，并且热和化学尺寸稳定性 很好

公开(公告)号：US20100086450A1

公开(公告)日：2010-04-08

申请号：US12625531

申请日：2009-11-24

申请人： Nak Hyun Kwon ,  In Chul Hwang ,  Byung Ki Ahn ,  Tae Won Lim

发明人： Nak Hyun Kwon ,  In Chul Hwang ,  Byung Ki Ahn ,  Tae Won Lim

IPC分类号： B01J19/10

CPC分类号： H01M8/1004 ,  B01J23/42 ,  B01J35/0013 ,  B01J35/0033 ,  B01J37/0036 ,  B01J37/343 ,  H01M4/8828 ,  H01M2008/1095 ,  H01M2250/20 ,  Y02E60/521 ,  Y02P70/56 ,  Y02T90/32

摘要： The present invention relates to a method and apparatus for preparing a catalyst slurry for fuel cells, in which nano-sized catalyst particles are dispersed uniformly at a high concentration and the adsorption force between the catalyst and ionomer is maximized. The resulting catalyst slurry is suitable for the manufacture of a membrane-electrode assembly (MEA) of a polymer electrolyte (or proton exchange) membrane fuel cell (PEMFC).

摘要翻译： 本发明涉及一种制备用于燃料电池的催化剂浆料的方法和装置，其中纳米尺寸催化剂颗粒以高浓度均匀分散，并且催化剂和离聚物之间的吸附力最大化。 所得催化剂浆料适用于制造聚合物电解质（或质子交换）膜燃料电池（PEMFC）的膜 - 电极组件（MEA）。

公开(公告)号：US20110201756A1

公开(公告)日：2011-08-18

申请号：US12885841

申请日：2010-09-20

申请人： Won Ho Jo ,  Tae-ann Kim ,  In Chul Hwang ,  Nak Hyun Kwon

发明人： Won Ho Jo ,  Tae-ann Kim ,  In Chul Hwang ,  Nak Hyun Kwon

IPC分类号： C08F293/00

CPC分类号： H01M8/1023 ,  C08F8/36 ,  C08F293/00 ,  C08G65/48 ,  C08G75/23 ,  C08G2261/722 ,  C08G2650/40 ,  C08L71/00 ,  C08L2205/05 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1044 ,  H01M8/1072 ,  H01M2300/0082 ,  Y02P70/56 ,  C08L25/06 ,  C08L25/04 ,  C08F293/005

摘要： The present invention provides an amphiphilic block copolymer, a method for manufacturing the same, and a fuel cell membrane using the same. According to preferred embodiments, the amphiphilic block copolymer may contain poly(arylene sulfone ether ketone) (PSEK) as a hydrophobic component and poly(sulfonated styrene-co-acrylonitrile) (PSSAN) as a hydrophilic component. According to other preferred embodiments, polymer electrolyte membrane manufactured using the amphiphilic block copolymer has certain advantages in that the hydrogen ion conductivity is not reduced even at a high temperature of more than 100° C. but is rather increased and the thermal and chemical dimensional stability is excellent.

摘要翻译： 本发明提供两亲性嵌段共聚物，其制造方法以及使用其的燃料电池膜。 根据优选的实施方案，两亲嵌段共聚物可以含有作为疏水组分的聚（亚芳基砜醚酮）（PSEK）和作为亲水组分的聚（磺化苯乙烯 - 共 - 丙烯腈）（PSSAN）。 根据其它优选实施方案，使用两亲性嵌段共聚物制造的聚合物电解质膜具有某些优点，即即使在高于100℃的高温下，氢离子传导性也不降低，但是相当增加，并且热和化学尺寸稳定性 很好

公开(公告)号：US20110129759A1

公开(公告)日：2011-06-02

申请号：US12769119

申请日：2010-04-28

申请人： In Chul Hwang ,  Nak Hyun Kwon ,  Jae Seung Lee

发明人： In Chul Hwang ,  Nak Hyun Kwon ,  Jae Seung Lee

IPC分类号： H01M8/10 ,  H01M8/04 ,  B01J31/06

CPC分类号： H01M4/8605 ,  H01M4/8896 ,  H01M4/921 ,  H01M4/926

摘要： The present invention provides an electrode for a polymer electrolyte membrane fuel cell (PEMFC) and a method for forming a membrane-electrode assembly (MEA) using the same, in which carbon nanofibers are added to a catalyst layer to increase the mechanical strength of the catalyst layer and to maintain the thickness of the catalyst layer after operation for a long time, thus preventing a reduction in physical durability of the fuel cell, and cerium-zirconium oxide (CeZrO4) as a radical inhibitor is added to the catalyst layer, thus preventing a reduction in chemical durability of the fuel cell. As a result, it is possible to physically and chemically increase the performance and durability of the fuel cell membrane-electrode assembly in a robust manner and minimize the reduction in performance after operation for a long time.

摘要翻译： 本发明提供了一种高分子电解质膜燃料电池用电极（PEMFC）以及使用该电极组件（MEA）的方法，其中将碳纳米纤维加入到催化剂层中，以提高机械强度 催化剂层，并且在长时间操作之后保持催化剂层的厚度，从而防止燃料电池的物理耐久性降低，并且作为自由基抑制剂的铈锆氧化物（CeZrO 4）被加入到催化剂层中，因此 防止燃料电池的化学耐久性降低。 结果，可以以鲁棒的方式物理和化学地增加燃料电池膜 - 电极组件的性能和耐久性，并且可以使操作长时间后的性能降低最小化。