摘要:
Provided is a negative electrode active material that contains silicon clathrate II and that is suitable for a negative electrode of a lithium ion secondary battery. The negative electrode active material includes a silicon material in which silicon clathrate II represented by composition formula NaxSi136 (0≤x≤10) is contained and a volume of a pore having a diameter of not greater than 100 nm is not less than 0.025 cm3/g.
摘要:
Provided is a novel production method for producing silicon clathrate II. In the production method for producing silicon clathrate II, in a reaction system in which a Na—Si alloy containing Na and Si and an Na getter agent coexist so as not to be in contact with each other, the Na—Si alloy is heated and Na evaporated from the Na—Si alloy is thus caused to react with the Na getter agent to reduce an amount of Na in the Na—Si alloy.
摘要:
A main object of the present disclosure is to provide an active material whose volume variation due to charge and discharge is small. The present disclosure achieves the object by providing an active material comprising a primary particle including at least one crystal phase of a Type I silicon clathrate and a Type II silicon clathrate, and the primary particle includes a void inside thereof.
摘要:
When a layered rock-salt type cathode active material and a sulfide solid electrolyte are mixed to be a cathode mixture, and an all solid-state battery is obtained using this mixture, oxygen is released from the cathode active material when the battery is charged, and the sulfide solid electrolyte is oxidized, increasing the battery internal resistance. To increase the concentration of cobalt inside the active material, and at the same time to lower the concentration of cobalt of the surface of the cathode active material, to suppress oxygen release in charging, specifically, a cathode mixture includes: a cathode active material; and a sulfide solid electrolyte, wherein the cathode active material has a layered rock-salt crystal phase, and is made of a composite oxide containing Li, Ni, Co, and Mn, and the concentration of cobalt inside the cathode active material is higher than that of a surface of the cathode active material.
摘要:
An object of the present disclosure is to provide a cathode mixture with high energy density per volume. The present disclosure achieves the object by providing a cathode mixture to be used in an all solid state battery, the cathode mixture comprising: a first cathode active material, a second cathode active material, and a sulfide solid electrolyte; and a ratio of an average particle diameter of the first cathode active material to an average particle diameter of the second cathode active material is 2.0 or more and 4.3 or less.
摘要:
An all-solid battery having stacked therein, in order, a positive electrode laminate, an intermediate solid electrolyte layer, and a negative electrode laminate is manufactured by a first pressing step (i) of applying pressure to the positive electrode laminate, a second pressing step (ii) of applying pressure to the negative electrode laminate, and a third pressing step (iii) of applying pressure to the positive electrode laminate, the intermediate solid electrolyte layer, and the negative electrode laminate.
摘要:
A main object of the present disclosure is to provide a novel active material whose volume variation due to charge/discharge is small. The present disclosure achieves the object by providing an active material having a composition represented by NaxMySi46, wherein M is a metal element other than Na, x and y satisfy 0
摘要:
A solid-state battery comprising a stack including at least one unit cell including a positive electrode layer including a positive electrode active material, a negative electrode layer including a negative electrode active material, and a solid electrolyte layer laminated between the positive and negative electrode layers, and an outer covering accommodating the stack, wherein the solid-state battery further including a pressure receiving member provided on at least a part of a periphery of the outer covering, and wherein the pressure receiving member has a thickness of less than a total thickness of the stack and the outer covering in a stacking direction of the unit cell.
摘要:
A manufacturing method of an all-solid battery includes fabricating a single battery including a positive electrode layer, a negative electrode layer, and a solid electrolyte layer arranged between the positive electrode layer and the negative electrode layer; fabricating a plurality of battery packs including the plurality of single batteries; confining a plurality of battery packs by an equal confining pressure; measuring the electrical characteristics of the plurality of confined battery packs; determining the battery pack whose measured electrical characteristics are the worst of the plurality of battery packs; reducing the confining pressures of the other battery packs so that the electrical characteristics of the other battery packs are equal to that of the battery pack whose electrical characteristics have been determined to be the worst; and electrically connecting in parallel the battery packs.
摘要:
An objective of the present invention is to provide a charging system, capable of increasing the rapid charging capacity of an on-vehicle all-solid-state battery, and reducing the effect of confining pressure on the all-solid-state battery. This is achieved by a charging system for an all-solid-state battery to be mounted in a vehicle, the charging system comprising: a charging section that charges an all-solid-state battery, a pressing section that applies confining pressure to the all-solid-state battery, and a pressure control section that controls the confining pressure, wherein the pressure control section directs the pressing section so that the confining pressure during charging is higher than the confining pressure during discharging.