公开(公告)号：US20150183931A1

公开(公告)日：2015-07-02

申请号：US14409126

申请日：2013-06-25

Applicant: KANEKA CORPORATION

Inventor： Mari Fujii ,  Shinji Ozawa ,  Tomohiro Abo

IPC: C08G73/10 ,  C08G69/00

CPC classification number: C08G73/1042 ,  C08G69/00 ,  C08G73/1053 ,  C08G73/1082 ,  C08G73/16 ,  C09D179/08

Abstract: The object of the present invention is to obtain the polyimide and the polyamic acid excellent in heat resistance, low thermal expansion property, and transparency and achieve low birefringence and to provide a product or a member, demanded to have high heat resistance and transparency, by using the polyimide or the polyamic acid. In particular, the object is to provide a product and a member in which the polyimide or the polyamic acid of the present invention is formed on a surface of an inorganic substance such as glass, metal, a metal oxide, or a single crystal silicon. The objects are attained by introducing a rigid structure and an alicyclic structure into a skeleton and using a monomer having a fluorene skeleton together.

Abstract translation: 本发明的目的是获得耐热性，低热膨胀性和透明性优异的聚酰亚胺和聚酰胺酸，并且实现低双折射并提供要求具有高耐热性和透明性的产品或部件，通过 使用聚酰亚胺或聚酰胺酸。 特别是，本发明的目的在于提供一种在玻璃，金属，金属氧化物或单晶硅等无机物质的表面上形成本发明的聚酰亚胺或聚酰胺酸的物质和成分。 通过将刚性结构和脂环结构引入骨架并使用具有芴骨架的单体在一起来实现。

公开(公告)号：US10435510B2

公开(公告)日：2019-10-08

申请号：US14764639

申请日：2014-01-29

Applicant: KANEKA CORPORATION

Inventor： Takahiro Akinaga ,  Yuki Takiguchi ,  Shinji Ozawa

IPC: C08G69/48 ,  B32B27/28 ,  B32B38/10 ,  B32B27/06 ,  B32B27/34 ,  B32B27/08 ,  C08G73/10 ,  B32B7/06 ,  C09D179/08 ,  B32B17/06

Abstract: The present invention provides (A) a polyamic acid solution which can be (i) used to form a film that does not peel off even in a case where the film has a large thickness, and (ii) stably stored at a room temperature, and (B) a laminate that can be suitably used for production of a flexible device. An alkoxysilane-modified polyamic acid solution of the present invention can be obtained by reacting (a) an alkoxysilane compound containing the amino group and (b) a polyamic acid solution, and has a molar ratio of 0.980 or more and 0.9995 or less, which molar ratio is obtained by dividing a total number of moles of an aromatic tetracarboxylic dianhydride by a total number of moles of an aromatic diamine.

公开(公告)号：US10308767B2

公开(公告)日：2019-06-04

申请号：US15502706

申请日：2015-07-15

Applicant: KANEKA CORPORATION

Inventor： Takahiro Akinaga ,  Yuki Takiguchi ,  Shinji Ozawa

IPC: C08G73/10 ,  B32B27/34 ,  B32B27/28 ,  H05K1/03 ,  H05K3/00 ,  C09D179/08

Abstract: Provided are a polyamic acid solution that can be formed into a film without peeling even when the film is thick and can be stably stored at room temperature, and a laminate that can be suitably used for production of a flexible device. In the alkoxysilane-modified polyamic acid solution according to the present invention, an additive amount of an alkoxysilane compound that contains an amino group is more than 0.050 parts by weight and less than 0.100 parts by weight.

公开(公告)号：US09353223B2

公开(公告)日：2016-05-31

申请号：US14409126

申请日：2013-06-25

Applicant: KANEKA CORPORATION

Inventor： Mari Fujii ,  Shinji Ozawa ,  Tomohiro Abo

IPC: C08G73/10 ,  B29C41/24 ,  C08G73/16 ,  C08G69/00 ,  C09D179/08

CPC classification number: C08G73/1042 ,  C08G69/00 ,  C08G73/1053 ,  C08G73/1082 ,  C08G73/16 ,  C09D179/08

Abstract: The object of the present invention is to obtain the polyimide and the polyamic acid excellent in heat resistance, low thermal expansion property, and transparency and achieve low birefringence and to provide a product or a member, demanded to have high heat resistance and transparency, by using the polyimide or the polyamic acid. In particular, the object is to provide a product and a member in which the polyimide or the polyamic acid of the present invention is formed on a surface of an inorganic substance such as glass, metal, a metal oxide, or a single crystal silicon. The objects are attained by introducing a rigid structure and an alicyclic structure into a skeleton and using a monomer having a fluorene skeleton together.

Abstract translation: 本发明的目的是获得耐热性，低热膨胀性和透明性优异的聚酰亚胺和聚酰胺酸，并且实现低双折射并提供要求具有高耐热性和透明性的产品或部件，通过 使用聚酰亚胺或聚酰胺酸。 特别是，本发明的目的在于提供一种在玻璃，金属，金属氧化物或单晶硅等无机物质的表面上形成本发明的聚酰亚胺或聚酰胺酸的物质和成分。 通过将刚性结构和脂环结构引入骨架并使用具有芴骨架的单体在一起来实现。

公开(公告)号：US20150368402A1

公开(公告)日：2015-12-24

申请号：US14764639

申请日：2014-01-29

Applicant: KANEKA CORPORATION

Inventor： Takahiro Akinaga ,  Yuki Takiguchi ,  Shinji Ozawa

IPC: C08G69/48 ,  B32B27/28 ,  B32B38/10 ,  B32B27/06

CPC classification number: C08G69/48 ,  B32B7/06 ,  B32B17/064 ,  B32B27/06 ,  B32B27/08 ,  B32B27/281 ,  B32B27/34 ,  B32B38/10 ,  B32B2307/308 ,  B32B2307/558 ,  B32B2307/702 ,  B32B2307/748 ,  B32B2457/20 ,  C08G73/1017 ,  C08G73/1067 ,  C08G73/1078 ,  C09D179/08 ,  Y10T156/10 ,  Y10T428/31721

Abstract: The present invention provides (A) a polyamic acid solution which can be (i) used to form a film that does not peel off even in a case where the film has a large thickness, and (ii) stably stored at a room temperature, and (B) a laminate that can be suitably used for production of a flexible device. An alkoxysilane-modified polyamic acid solution of the present invention can be obtained by reacting (a) an alkoxysilane compound containing the amino group and (b) a polyamic acid solution, and has a molar ratio of 0.980 or more and 0.9995 or less, which molar ratio is obtained by dividing a total number of moles of an aromatic tetracarboxylic dianhydride by a total number of moles of an aromatic diamine.

Abstract translation: 本发明提供（A）聚酰胺酸溶液，其可以（i）用于形成即使在膜具有大厚度的情况下也不会剥离的膜，和（ii）在室温下稳定地储存， 和（B）可以适用于生产挠性装置的层压体。 本发明的烷氧基硅烷改性聚酰胺酸溶液可以通过（a）含氨基的烷氧基硅烷化合物与（b）聚酰胺酸溶液的摩尔比为0.980以上且0.9995以下， 摩尔比通过将芳族四羧酸二酐的总摩尔数除以芳族二胺的总摩尔数获得。