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    Bimetallic cobalt-aluminum adduct catalyst system for preparing high trans-1,4-polybutadiene
    1.
    发明授权
    Bimetallic cobalt-aluminum adduct catalyst system for preparing high trans-1,4-polybutadiene 有权
    用于制备高反式1,4-聚丁二烯的双金属钴 - 铝加合催化剂体系

    公开(公告)号：US09487604B2

    公开(公告)日：2016-11-08

    申请号：US14089646

    申请日：2013-11-25

    申请人： Korea Kumho Petrochemical Co., Ltd.

    发明人： Hanbaek Lee ,  Gwanghoon Kwag ,  Hoochae Kim ,  Seunghyun Do ,  Bunyeoul Lee ,  Jihae Park ,  Ahreum Kim

    IPC分类号： C08F4/00 ,  C08F36/00 ,  C08F136/06

    CPC分类号： C08F136/06 ,  C08F4/7096

    摘要： The present invention relates to preparing high 1,4-trans-polybutadiene by polymerizing 1,3-butadiene or a butadiene derivative in a non-polar solvent in the presence of a catalyst system comprising a novel bimetallic cobalt-aluminum adduct, which makes it possible to prevent gel formation, control the molecular weight of the trans-polybutadiene and increase the trans content of the trans-polybutadiene. The catalyst system comprising the novel cobalt-aluminum adduct has a high oxidation state and structural stability, and the reactivity of the catalyst is controlled using novel activation systems comprising various allyloxy aluminum compounds.

    摘要翻译： 本发明涉及通过在包含新型双金属钴 - 铝加合物的催化剂体系的存在下，在非极性溶剂中聚合1,3-丁二烯或丁二烯衍生物来制备高1,4-反式聚丁二烯，这使得它 可能防止凝胶形成，控制反式聚丁二烯的分子量并增加反式聚丁二烯的反式含量。 包含新型钴 - 铝加合物的催化剂体系具有高氧化态和结构稳定性，并且使用包含各种烯丙氧基铝化合物的新型活化体系来控制催化剂的反应性。

    NOVEL BIMETALLIC COBALT-ALUMINUM ADDUCT CATALYST SYSTEM FOR PREPARING HIGH TRANS-1,4-POLYBUTADIENE
    4.
    发明申请
    NOVEL BIMETALLIC COBALT-ALUMINUM ADDUCT CATALYST SYSTEM FOR PREPARING HIGH TRANS-1,4-POLYBUTADIENE 有权
    用于制备高反式-1,4-聚丁二烯的新型双金属钴 - 铝加成催化剂体系

    公开(公告)号：US20150148503A1

    公开(公告)日：2015-05-28

    申请号：US14089646

    申请日：2013-11-25

    申请人： Korea Kumho Petrochemical Co., Ltd.

    发明人： Hanbaek Lee ,  Gwanghoon Kwag ,  Hoochae Kim ,  Seunghyun Do ,  Bunyeoul Lee ,  Jihae Park ,  Ahreum Kim

    IPC分类号： C08F136/06

    CPC分类号： C08F136/06 ,  C08F4/7096

    摘要： The present invention relates to preparing high 1,4-trans-polybutadiene by polymerizing 1,3-butadiene or a butadiene derivative in a non-polar solvent in the presence of a catalyst system comprising a novel bimetallic cobalt-aluminum adduct, which makes it possible to prevent gel formation, control the molecular weight of the trans-polybutadiene and increase the trans content of the trans-polybutadiene. The catalyst system comprising the novel cobalt-aluminum adduct has a high oxidation state and structural stability, and the reactivity of the catalyst is controlled using novel activation systems comprising various allyloxy aluminum compounds.

    摘要翻译： 本发明涉及通过在包含新型双金属钴 - 铝加合物的催化剂体系的存在下，在非极性溶剂中聚合1,3-丁二烯或丁二烯衍生物来制备高1,4-反式聚丁二烯，这使得它 可能防止凝胶形成，控制反式聚丁二烯的分子量并增加反式聚丁二烯的反式含量。 包含新型钴 - 铝加合物的催化剂体系具有高氧化态和结构稳定性，并且使用包含各种烯丙氧基铝化合物的新型活化体系来控制催化剂的反应性。

    SILOXANE COMPOUND, PREPARATION METHOD THEREOF, AND USE THEREOF
    5.
    发明公开
    SILOXANE COMPOUND, PREPARATION METHOD THEREOF, AND USE THEREOF 审中-公开

    公开(公告)号：US20240101788A1

    公开(公告)日：2024-03-28

    申请号：US18461521

    申请日：2023-09-06

    申请人： KOREA KUMHO PETROCHEMICAL CO., LTD.

    发明人： Daejune JOE ,  Min Sung KWON ,  Dae Hyung LEE ,  Gihyun SUNG ,  Hyeong Ho YOON ,  Gwanghoon Kwag ,  Jae Yeon An

    IPC分类号： C08K5/544 ,  C08F212/08 ,  C08F236/06

    CPC分类号： C08K5/544 ,  C08F212/08 ,  C08F236/06 ,  C08F2810/40

    摘要： One embodiment of the present specification provides a siloxane compound represented by Chemical Formula 1 below:




    In Chemical Formula 1, R1a and R1b are each independently a substituted or unsubstituted straight or branched-chain alkyl group having 1 to 16 carbon atoms, R2a and R2b are each independently a substituted or unsubstituted straight or branched-chain alkyl group having 1 to 16 carbon atoms, R3a and R3b are each independently a substituted or unsubstituted straight or branched-chain alkylene group having 1 to 16 carbon atoms, R4a, R4b, R5a, and R5b are each independently hydrogen, a substituted or unsubstituted straight or branched alkyl group having 1 to 16 carbon atoms, or a substituted or unsubstituted straight or branched-chain heteroalkyl group having 1 to 16 carbon atoms, m1 and m2 are each an integer from 0 to 2, and when m1 and m2 are each 0, a plurality of OR2a and OR2b are the same or different, and when m1 and m2 are each 2, a plurality of R1a and R1b are the same or different, and x is an integer from 1 to 5.