公开(公告)号：US20130289200A1

公开(公告)日：2013-10-31

申请号：US13625106

申请日：2012-09-24

申请人： KOREA KUMHO PETROCHEMICAL CO., LTD. ,  INSTITUTE FOR RESEARCH & INDUSTRY COOPERATION, PN

发明人： Gwang Hoon Kwag ,  Jong Yeop Lee ,  Dong Hyuk Na ,  Jun Keol Choi ,  Hyun Jong Paik ,  Bong Soo Kim ,  Hee Jeong Kim

IPC分类号： C08F120/18 ,  C08K3/36 ,  C08L33/12 ,  C08F265/04

CPC分类号： C08F120/18 ,  C08C19/44 ,  C08F2/26 ,  C08F236/06 ,  C08F2/38

摘要： Disclosed are a novel chain transfer agent having a trichloromethyl functional group bonded at an end thereof, an end-modified styrene-butadiene copolymer prepared by using the chain transfer agent, and an organic-inorganic composite obtained by mixing the end-modified styrene-butadiene copolymer with silica. The disclosed end-modified styrene-butadiene copolymer has a high affinity with silica because its end is modified with a hydrophilic chain transfer agent. Thus, the organic-inorganic composite including the mixture of the copolymer with silica is useful as a material for the manufacture of rubber products such as a tire, a sole, a rubber hose, or a rubber belt.

摘要翻译： 公开了一种在其末端具有三氯甲基官能团的新型链转移剂，通过使用链转移剂制备的末端改性苯乙烯 - 丁二烯共聚物和通过将末端改性苯乙烯 - 丁二烯混合而获得的有机 - 无机复合物 与二氧化硅的共聚物。 所公开的末端改性苯乙烯 - 丁二烯共聚物与二氧化硅具有高亲和力，因为其末端用亲水性链转移剂改性。 因此，包括共聚物与二氧化硅的混合物的有机 - 无机复合材料可用作制造橡胶制品如轮胎，鞋底，橡胶软管或橡胶带的材料。

公开(公告)号：US09266981B2

公开(公告)日：2016-02-23

申请号：US14335078

申请日：2014-07-18

申请人： KOREA KUMHO PETROCHEMICAL CO., LTD

发明人： Dong Hyuk Na ,  Gwanghoon Kwag ,  Hanjoung Cho ,  Jun Keol Choi

IPC分类号： C08F30/00 ,  C08F236/00 ,  C08F30/08 ,  C08K3/04 ,  C08L43/04 ,  C08K3/36 ,  B60C1/00 ,  C08F236/06 ,  C08F236/10

CPC分类号： C08F30/08 ,  B60C1/00 ,  B60C1/0016 ,  C08F236/06 ,  C08F236/10 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08L9/00 ,  C08L19/006 ,  C08L43/04 ,  C08F2/28 ,  C08K3/0033 ,  C08F2230/085 ,  C08K3/013

摘要： Disclosed is a conjugated diene random copolymer having an alkoxysilane unit, which is prepared by subjecting a conjugated diene monomer, an aromatic vinyl monomer and an alkoxysilane monomer having a specific structure to emulsion polymerization, and in which the copolymer contains an alkoxysilane unit in the backbone thereof and is thus enhanced in the degree of dispersion and affinity to an inorganic reinforcing material such as carbon black or silica, and is useful as a rubber material for tires having superior mechanical and dynamic properties.

摘要翻译： 公开了具有烷氧基硅烷单元的共轭二烯无规共聚物，其通过共轭二烯单体，芳族乙烯基单体和具有特定结构的烷氧基硅烷单体进行乳液聚合制备，其中共聚物在主链中含有烷氧基硅烷单元 因此增强了对无机增强材料如炭黑或二氧化硅的分散度和亲和力，并且可用作具有优异的机械和动态特性的轮胎的橡胶材料。