公开(公告)号：US20100280178A1

公开(公告)日：2010-11-04

申请号：US12776598

申请日：2010-05-10

申请人： Kaoru IKEDA ,  Shinji Tai ,  Kouta Isoyama ,  Tomoyuki Watanabe

发明人： Kaoru IKEDA ,  Shinji Tai ,  Kouta Isoyama ,  Tomoyuki Watanabe

IPC分类号： C08F16/06

CPC分类号： C08F8/00 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/1359 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/139 ,  Y10T428/31551 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31855 ,  C08F216/06 ,  C08F8/18 ,  C08F8/40 ,  C08F8/42 ,  C08F8/34

摘要： Provided is a modified ethylene-vinyl alcohol copolymer (C) having an ethylen content of 5 to 55 mol %, which contains a specific structural unit (I) in an amount of 0.3 to 40 mol % and may be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500. This can be produced by a method for producing the modified ethylene-vinyl alcohol copolymer (C) which comprises melting and kneading an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) in an extruder. The modified ethylene-vinyl alcohol copolymer (C) is superior to a unmodified ethylene-vinyl alcohol copolymer (A) in transparency, stretchability, flexibility and flexing resistance due to the specific structural unit (I) incorporated therein, and thus, can be used as a barrier material in various applications requiring the above performance capabilities.

摘要翻译： 提供乙烯含量为5〜55摩尔％的改性乙烯 - 乙烯醇共聚物（C），其含有0.3〜40摩尔％的特定结构单元（I），可以通过使乙烯 - 乙烯醇共聚物（A）与单官能环氧化合物（B）的分子量不大于500.这可以通过改性乙烯 - 乙烯醇共聚物（C）的制备方法制备，该方法包括熔融和捏合乙烯 - 乙烯醇共聚物（A）与单官能环氧化合物（B）的混合物。 改性乙烯 - 乙烯醇共聚物（C）由于其中结合有特定结构单元（I）而在透明性，拉伸性，柔软性和挠曲性方面优于未改性的乙烯 - 乙烯醇共聚物（A），因此可以使用 作为需要上述性能的各种应用中的阻挡材料。

公开(公告)号：US07534829B2

公开(公告)日：2009-05-19

申请号：US10503586

申请日：2003-02-20

申请人： Shinji Tai ,  Kaoru Ikeda ,  Haruhisa Masuda ,  Tomoyuki Watanabe ,  Kouta Isoyama

发明人： Shinji Tai ,  Kaoru Ikeda ,  Haruhisa Masuda ,  Tomoyuki Watanabe ,  Kouta Isoyama

IPC分类号： C08L29/04 ,  C08F8/00 ,  C08F16/06 ,  C08L21/00 ,  C08L53/02 ,  C08J3/24

CPC分类号： B32B27/08 ,  B32B27/28 ,  B32B27/30 ,  B32B27/302 ,  B32B27/304 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B2325/00 ,  B32B2327/06 ,  B32B2367/00 ,  B32B2375/00 ,  B32B2377/00 ,  C08L23/0861 ,  C08L23/0876 ,  C08L29/04 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L53/025 ,  C08L2205/08 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/1393 ,  C08L2666/24

摘要： Provided is a resin composition comprising 1-99% by weight of a modified ethylene-vinyl alcohol copolymer (C) having an ethylene content of 5-55 mol %, which contains a specific structural unit (I) in an amount of 0.3-40 mol % and can be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500, and 1-99% by weight of a thermoplastic resin (T1) other than (C). Moreover, a multilayer structure in which the resin composition and a thermoplastic resin (T2) are laminated is also provided. Thus, a resin composition superior in barrier properties, transparency, stretchability, flexibility, flexing resistance and interlayer adhesiveness and various kinds of molded articles made thereof are provided.

摘要翻译： 提供一种树脂组合物，其包含1-99重量％的乙烯含量为5-55摩尔％的改性乙烯 - 乙烯醇共聚物（C），其含有0.3-40重量％的特定结构单元（I） mol％，可以通过使乙烯 - 乙烯醇共聚物（A）与分子量不大于500的单官能环氧化合物（B）和其他1-99重量％的热塑性树脂（T1）反应而得到 比（C）。 此外，还提供了其中层压树脂组合物和热塑性树脂（T2）的多层结构。 因此，提供了阻隔性，透明性，拉伸性，柔软性，抗弯曲性和层间粘合性优异的树脂组合物和由其制成的各种成型体。

公开(公告)号：US08329818B2

公开(公告)日：2012-12-11

申请号：US12776598

申请日：2010-05-10

申请人： Kaoru Ikeda ,  Shinji Tai ,  Kouta Isoyama ,  Tomoyuki Watanabe

发明人： Kaoru Ikeda ,  Shinji Tai ,  Kouta Isoyama ,  Tomoyuki Watanabe

IPC分类号： C08F8/00 ,  C08F16/06 ,  C08F18/08

CPC分类号： C08F8/00 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/1359 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/139 ,  Y10T428/31551 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31855 ,  C08F216/06 ,  C08F8/18 ,  C08F8/40 ,  C08F8/42 ,  C08F8/34

摘要： Provided is a modified ethylene-vinyl alcohol copolymer (C) having an ethylen content of 5 to 55 mol %, which contains a specific structural unit (I) in an amount of 0.3 to 40 mol % and may be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500. This can be produced by a method for producing the modified ethylene-vinyl alcohol copolymer (C) which comprises melting and kneading an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) in an extruder. The modified ethylene-vinyl alcohol copolymer (C) is superior to a unmodified ethylene-vinyl alcohol copolymer (A) in transparency, stretchability, flexibility and flexing resistance due to the specific structural unit (I) incorporated therein, and thus, can be used as a barrier material in various applications requiring the above performance capabilities.

摘要翻译： 提供乙烯含量为5〜55摩尔％的改性乙烯 - 乙烯醇共聚物（C），其含有0.3〜40摩尔％的特定结构单元（I），可以通过使乙烯 - 乙烯醇共聚物（A）与单官能环氧化合物（B）的分子量不大于500.这可以通过改性乙烯 - 乙烯醇共聚物（C）的制备方法制备，该方法包括熔融和捏合乙烯 - 乙烯醇共聚物（A）与单官能环氧化合物（B）的混合物。 改性乙烯 - 乙烯醇共聚物（C）由于其中结合有特定结构单元（I）而在透明性，拉伸性，柔软性和挠曲性方面优于未改性的乙烯 - 乙烯醇共聚物（A），因此可以使用 作为需要上述性能的各种应用中的阻挡材料。

公开(公告)号：US07600546B2

公开(公告)日：2009-10-13

申请号：US10692950

申请日：2003-10-27

申请人： Kentaro Fujino ,  Shinji Tai ,  Kaoru Ikeda ,  Tomoyuki Watanabe ,  Kouta Isoyama

发明人： Kentaro Fujino ,  Shinji Tai ,  Kaoru Ikeda ,  Tomoyuki Watanabe ,  Kouta Isoyama

IPC分类号： B60C5/14

CPC分类号： B60C5/14 ,  B60C1/0008 ,  C08F8/02 ,  C08F2800/10 ,  Y10S152/16 ,  C08F216/06

摘要： Disclosed is an innerliner for pneumatic tires, wherein the innerliner comprises a modified ethylene-vinyl alcohol copolymer (C) obtained by reacting 1-50 parts by weight of an epoxy compound (B) with 100 parts by weight of an ethylene-vinyl alcohol copolymer (A) having an ethylene content of 25-50 mol %. A pneumatic tire with the innerliner can greatly improve the internal pressure retainabilities before and after driving without increasing the weight of the tire.

摘要翻译： 公开了一种充气轮胎的内衬，其中内衬层包括通过使1-50重量份的环氧化合物（B）与100重量份的乙烯 - 乙烯醇共聚物（C）反应获得的改性乙烯 - 乙烯醇共聚物（C） （A）的乙烯含量为25〜50摩尔％。 具有内衬的充气轮胎可以大大提高驾驶前后的内部压力保持性，而不增加轮胎的重量。

公开(公告)号：US20050147778A1

公开(公告)日：2005-07-07

申请号：US10503586

申请日：2003-02-20

申请人： Shinji Tai ,  Kaoru Ikeda ,  Haruhisa Masuda ,  Tomoyuki Watanabe ,  Kouta Isoyama

发明人： Shinji Tai ,  Kaoru Ikeda ,  Haruhisa Masuda ,  Tomoyuki Watanabe ,  Kouta Isoyama

IPC分类号： B32B27/08 ,  B32B27/28 ,  B32B27/30 ,  C08L23/08 ,  C08L29/04 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  B32B1/08

CPC分类号： B32B27/08 ,  B32B27/28 ,  B32B27/30 ,  B32B27/302 ,  B32B27/304 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B2325/00 ,  B32B2327/06 ,  B32B2367/00 ,  B32B2375/00 ,  B32B2377/00 ,  C08L23/0861 ,  C08L23/0876 ,  C08L29/04 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L53/025 ,  C08L2205/08 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/1393 ,  C08L2666/24

摘要： Provided is a resin composition comprising 1-99% by weight of a modified ethylene-vinyl alcohol copolymer (C) having an ethylene content of 5-55 mol %, which contains a specific structural unit (I) in an amount of 0.3-40 mol % and can be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500, and 1-99% by weight of a thermoplastic resin (T1) other than (C). Moreover, a multilayer structure in which the resin composition and a thermoplastic resin (T2) are laminated is also provided. Thus, a resin composition superior in barrier properties, transparency, stretchability, flexibility, flexing resistance and interlayer adhesiveness and various kinds of molded articles made thereof are provided.

摘要翻译： 提供一种树脂组合物，其包含1-99重量％的乙烯含量为5-55摩尔％的改性乙烯 - 乙烯醇共聚物（C），其含有0.3-40重量％的特定结构单元（I） 摩尔％，可以通过使乙烯 - 乙烯醇共聚物（A）与分子量不大于500的单官能环氧化合物（B）和1-99重量％的热塑性树脂（T 1）反应获得， （C）以外。 此外，还提供了其中层压有树脂组合物和热塑性树脂（T 2）的多层结构。 因此，提供了阻隔性，透明性，拉伸性，柔软性，抗弯曲性和层间粘合性优异的树脂组合物和由其制成的各种成型体。

公开(公告)号：US07811646B2

公开(公告)日：2010-10-12

申请号：US10477710

申请日：2002-05-13

申请人： Kaoru Ikeda ,  Shinji Tai ,  Kouta Isoyama ,  Tomoyuki Watanabe

发明人： Kaoru Ikeda ,  Shinji Tai ,  Kouta Isoyama ,  Tomoyuki Watanabe

IPC分类号： B32B1/02 ,  B32B27/00 ,  B32B1/08

CPC分类号： C08F8/00 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/1359 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/139 ,  Y10T428/31551 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31855 ,  C08F216/06 ,  C08F8/18 ,  C08F8/40 ,  C08F8/42 ,  C08F8/34

摘要： Provided is a modified ethylene-vinyl alcohol copolymer (C) having an ethylen content of 5 to 55 mol %, which contains a specific structural unit (I) in an amount of 0.3 to 40 mol % and may be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500. This can be produced by a method for producing the modified ethylene-vinyl alcohol copolymer (C) which comprises melting and kneading an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) in an extruder. The modified ethylene-vinyl alcohol copolymer (C) is superior to a unmodified ethylene-vinyl alcohol copolymer (A) in transparency, stretchability, flexibility and flexing resistance due to the specific structural unit (I) incorporated therein, and thus, can be used as a barrier material in various applications requiring the above performance capabilities.

摘要翻译： 提供乙烯含量为5〜55摩尔％的改性乙烯 - 乙烯醇共聚物（C），其含有0.3〜40摩尔％的特定结构单元（I），可以通过使乙烯 - 乙烯醇共聚物（A）与单官能环氧化合物（B）的分子量不大于500.这可以通过改性乙烯 - 乙烯醇共聚物（C）的制备方法制备，该方法包括熔融和捏合乙烯 - 乙烯醇共聚物（A）与单官能环氧化合物（B）的混合物。 改性乙烯 - 乙烯醇共聚物（C）由于其中结合有特定结构单元（I）而在透明性，拉伸性，柔软性和挠曲性方面优于未改性的乙烯 - 乙烯醇共聚物（A），因此可以使用 作为需要上述性能的各种应用中的阻挡材料。

公开(公告)号：US09186873B2

公开(公告)日：2015-11-17

申请号：US13513354

申请日：2010-11-30

申请人： Shinji Tai ,  Hiroshi Kawai ,  Satoshi Yamakoshi ,  Kouta Isoyama ,  Masao Hikasa ,  Kentaro Yoshida

发明人： Shinji Tai ,  Hiroshi Kawai ,  Satoshi Yamakoshi ,  Kouta Isoyama ,  Masao Hikasa ,  Kentaro Yoshida

IPC分类号： B32B7/00 ,  B32B27/08 ,  B32B27/18 ,  B32B27/28 ,  B32B27/34 ,  B32B27/40 ,  B32B7/02 ,  B32B7/12 ,  B32B27/00 ,  B32B27/30 ,  B32B27/32

CPC分类号： B32B27/08 ,  B32B7/00 ,  B32B7/02 ,  B32B7/12 ,  B32B27/00 ,  B32B27/18 ,  B32B27/28 ,  B32B27/306 ,  B32B27/32 ,  B32B27/34 ,  B32B27/40 ,  B32B2307/7242 ,  Y10T428/24942 ,  Y10T428/24975

摘要： Disclosed is a multilayered structure that includes no less than 8 resin-layers, the resin-layer including a layer A constituted with a resin composition containing a gas barrier resin, and a layer B constituted with a resin composition containing a thermoplastic resin, at least one of the resin compositions included in the layer A and the layer B that are adjacent with each other containing a metal salt, the content of the metal salt being no less than 1 ppm and no greater than 10,000 ppm in terms of metal element equivalent, and an interlayer adhesive force between the layer A and the layer B being no less than 450 g/15 mm. The layer A and the layer B may be alternately laminated. Moreover, the average thickness of single layer of at least one selected from the layer A and the layer B is preferably no less than 0.01 μm and no greater than 10 μm.

摘要翻译： 公开了一种多层结构，其包括不少于8个树脂层，树脂层包括由含有阻气性树脂的树脂组合物构成的层A和由含有热塑性树脂的树脂组合物构成的层B，至少 包含在层A和B中彼此相邻的含有金属盐的树脂组合物之一，以金属元素当量计，金属盐的含量不小于1ppm且不大于10,000ppm， 层A和层B之间的层间粘合力不小于450g / 15mm。 层A和层B可以交替层压。 此外，从层A和层B中选择的至少一种以上的单层的平均厚度优选为0.01μm以上且10μm以下。

公开(公告)号：US20120237747A1

公开(公告)日：2012-09-20

申请号：US13513354

申请日：2010-11-30

申请人： Shinji Tai ,  Hiroshi Kawai ,  Satoshi Yamakoshi ,  Kouta Isoyama ,  Masao Hikasa ,  Kentaro Yoshida

发明人： Shinji Tai ,  Hiroshi Kawai ,  Satoshi Yamakoshi ,  Kouta Isoyama ,  Masao Hikasa ,  Kentaro Yoshida

IPC分类号： B32B7/02 ,  B29C47/06 ,  B32B27/08

CPC分类号： B32B27/08 ,  B32B7/00 ,  B32B7/02 ,  B32B7/12 ,  B32B27/00 ,  B32B27/18 ,  B32B27/28 ,  B32B27/306 ,  B32B27/32 ,  B32B27/34 ,  B32B27/40 ,  B32B2307/7242 ,  Y10T428/24942 ,  Y10T428/24975

摘要： Disclosed is a multilayered structure that includes no less than 8 resin-layers, the resin-layer including a layer A constituted with a resin composition containing a gas barrier resin, and a layer B constituted with a resin composition containing a thermoplastic resin, at least one of the resin compositions included in the layer A and the layer B that are adjacent with each other containing a metal salt, the content of the metal salt being no less than 1 ppm and no greater than 10,000 ppm in terms of metal element equivalent, and an interlayer adhesive force between the layer A and the layer B being no less than 450 g/15 mm. The layer A and the layer B may be alternately laminated. Moreover, the average thickness of single layer of at least one selected from the layer A and the layer B is preferably no less than 0.01 μm and no greater than 10 μm.

摘要翻译： 公开了一种多层结构，其包括不少于8个树脂层，树脂层包括由含有阻气性树脂的树脂组合物构成的层A和由含有热塑性树脂的树脂组合物构成的层B，至少 包含在层A和B中彼此相邻的含有金属盐的树脂组合物之一，以金属元素当量计，金属盐的含量不小于1ppm且不大于10,000ppm， 层A和层B之间的层间粘合力不小于450g / 15mm。 层A和层B可以交替层压。 此外，从层A和层B中选择的至少一种以上的单层的平均厚度优选为0.01μm以上且10μm以下。

公开(公告)号：US08084536B2

公开(公告)日：2011-12-27

申请号：US11813840

申请日：2006-01-11

申请人： Kouta Isoyama ,  Hiroyuki Shindome ,  Naoki Kataoka ,  Tomoyuki Watanabe

发明人： Kouta Isoyama ,  Hiroyuki Shindome ,  Naoki Kataoka ,  Tomoyuki Watanabe

IPC分类号： C08L29/04

CPC分类号： B32B25/08 ,  B32B25/14 ,  B32B27/08 ,  B32B27/306 ,  B32B2270/00 ,  B32B2274/00 ,  B32B2307/54 ,  B32B2307/558 ,  B32B2307/7242 ,  B32B2439/46 ,  B32B2439/70 ,  C08L23/0861 ,  C08L23/26 ,  Y10T428/13 ,  Y10T428/1307 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31917 ,  Y10T428/31924 ,  Y10T428/31931 ,  C08L2666/04

摘要： A resin composition is provided which comprises from 50 to 95% by weight of a modified ethylene-vinyl alcohol copolymer (C) obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monovalent epoxy compound (B) having a molecular weight of 500 or less, and from 5 to 50% by weight of a soft resin (F) that has at least one functional group able to react with a hydroxyl group and has a Young's modulus at 23° C., 50% RH of 500 MPa or less, wherein the soft resin (F) is dispersed with an average particle diameter of 0.1 μm or less in a matrix of the modified ethylene-vinyl alcohol copolymer (C). This resin composition is excellent in barrier properties and also in flex resistance and impact resistance at low temperature.

摘要翻译： 提供一种树脂组合物，其包含50至95重量％的乙烯 - 乙烯醇共聚物（A）与分子量为1的环氧化合物（B）的乙烯 - 乙烯醇共聚物（A）反应获得的改性乙烯 - 乙烯醇共聚物（C） 500以下，5〜50重量％的软质树脂（F），其具有至少一个能够与羟基反应并且在23℃，50％RH下的杨氏模量为500MPa的官能团 或更低，其中所述软树脂（F）在改性乙烯 - 乙烯醇共聚物（C）的基体中以平均粒径为0.1μm以下分散。 该树脂组合物在低温下的阻隔性以及耐挠曲性和耐冲击性优异。

公开(公告)号：US20090012236A1

公开(公告)日：2009-01-08

申请号：US11813840

申请日：2006-01-11

申请人： Kouta Isoyama ,  Hiroyuki Shindome ,  Naoki Kataoka ,  Tomoyuki Watanabe

发明人： Kouta Isoyama ,  Hiroyuki Shindome ,  Naoki Kataoka ,  Tomoyuki Watanabe

IPC分类号： C08F16/06

CPC分类号： B32B25/08 ,  B32B25/14 ,  B32B27/08 ,  B32B27/306 ,  B32B2270/00 ,  B32B2274/00 ,  B32B2307/54 ,  B32B2307/558 ,  B32B2307/7242 ,  B32B2439/46 ,  B32B2439/70 ,  C08L23/0861 ,  C08L23/26 ,  Y10T428/13 ,  Y10T428/1307 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31917 ,  Y10T428/31924 ,  Y10T428/31931 ,  C08L2666/04

摘要： A resin composition is provided which comprises from 50 to 95% by weight of a modified ethylene-vinyl alcohol copolymer (C) obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monovalent epoxy compound (B) having a molecular weight of 500 or less, and from 5 to 50% by weight of a soft resin (F) that has at least one functional group able to react with a hydroxyl group and has a Young's modulus at 23° C., 50% RH of 500 MPa or less, wherein the soft resin (F) is dispersed with an average particle diameter of 0.1 μm or less in a matrix of the modified ethylene-vinyl alcohol copolymer (C). This resin composition is excellent in barrier properties and also in flex resistance and impact resistance at low temperature.

摘要翻译： 提供一种树脂组合物，其包含50至95重量％的乙烯 - 乙烯醇共聚物（A）与分子量为1的环氧化合物（B）的乙烯 - 乙烯醇共聚物（A）反应获得的改性乙烯 - 乙烯醇共聚物（C） 500以下，5〜50重量％的软质树脂（F），其具有至少一个能够与羟基反应并且在23℃，50％RH下的杨氏模量为500MPa的官能团 或更低，其中所述软树脂（F）在改性乙烯 - 乙烯醇共聚物（C）的基体中以平均粒径为0.1μm以下分散。 该树脂组合物在低温下的阻隔性以及耐挠曲性和耐冲击性优异。