公开(公告)号：US09376636B2

公开(公告)日：2016-06-28

申请号：US13995800

申请日：2011-12-15

申请人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G45/04 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  C10G45/10 ,  B01J29/03 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  C10G45/06 ,  B01J27/195 ,  B01J27/198

CPC分类号： C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

摘要： A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.

摘要翻译： 至少一种汽油切割加氢脱硫的方法，其实施催化剂，其以其氧化物形式包含至少一种以至少一种形式存在的来自VIB族组分和/或至少一种来自元素周期表Ⅷ族的金属的金属 式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷，硅，硼，镍和钴的元素，M是选自钼，钨，镍和钴的一种或多种元素，h是整数 从0-12，x是0-4的整数，m是整数5,6,7,8,9,10,11,12和/或18，y是17-72的整数，q是 整数为1-20，多金属氧酸盐存在于孔径为1.5-50nm的介孔结构的氧化硅基质中，并且具有厚度为1-30nm的无定形壁，催化剂在该方法使用前被硫化。

公开(公告)号：US09321973B2

公开(公告)日：2016-04-26

申请号：US13996762

申请日：2011-12-15

申请人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G47/00 ,  B01J27/186 ,  B01J27/19 ,  C10G47/12 ,  B01J29/04 ,  B01J35/00 ,  B01J35/10 ,  B01J37/10 ,  C10G65/12 ,  C10G3/00 ,  B01J27/188 ,  B01J27/195 ,  B01J27/198 ,  B01J37/20

CPC分类号： C10G47/12 ,  B01J27/186 ,  B01J27/19 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4018 ,  Y02P30/20

摘要： A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q−, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

摘要翻译： 一种用于加氢裂化含烃原料的方法，其中至少50重量％的化合物的起始沸点高于340℃，最终沸点低于540℃，使用其氧化物中的催化剂 形成选自VIB族，VIII族和VB族金属中的至少一种金属，所述金属以至少一种式（HhXxMmOy）q-的多金属氧酸盐的形式存在，所述多金属氧酸盐存在于介孔结构基质中，基于 至少一个元素Y，所述基质的孔径在1.5至50nm之间并具有1至30nm厚度的非晶壁，所述催化剂在用于所述方法之前被硫化。

公开(公告)号：US20140183100A1

公开(公告)日：2014-07-03

申请号：US13995800

申请日：2011-12-15

申请人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Elodie Devers ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G45/10 ,  C10G45/04

CPC分类号： C10G45/10 ,  B01J27/186 ,  B01J27/188 ,  B01J27/19 ,  B01J29/0333 ,  B01J29/0341 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J37/033 ,  B01J37/10 ,  B01J37/20 ,  B01J2229/20 ,  C10G45/04 ,  C10G45/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2400/02

摘要： The invention relates to a process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus (P), silicon (Si), boron (B), nickel (Ni) and cobalt (Co), the said element being taken alone, M is one or more element(s) selected from molybdenum (Mo), tungsten (W), nickel (Ni) and cobalt (Co), O is oxygen, H is hydrogen, h is an integer within the range 0 to 12, x is an integer within the range 0 to 4, m is an integer equal to 5, 6, 7, 8, 9, 10, 11, 12 and 18, y is an integer within the range 17 to 72 and q is an integer within the range 1 to 20, the said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.5 to 50 nm and having amorphous walls of thickness within the range 1 to 30 nm, the said catalyst being sulphured before being implemented in the said process.

摘要翻译： 本发明涉及至少一种汽油馏分的加氢脱硫方法，其实施催化剂，其以其氧化物形式包含至少一种来自元素周期表的VIB族金属和/或至少一种来自元素周期第Ⅷ族的金属，其形式为 的至少一种式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷（P），硅（Si），硼（B），镍（Ni）和钴（Co）的元素，所述元素为 单独使用时，M是选自钼（Mo），钨（W），镍（Ni）和钴（Co）中的一种或多种元素，O为氧，H为氢，h为0 至12，x为0至4范围内的整数，m为等于5,6,7,8,9,10,11,12和18的整数，y为17至72的整数，q为 是1至20范围内的整数，所述多金属氧酸盐存在于孔径在1.5至50nm范围内且具有厚度的无定形壁的介孔结构氧化硅基质中 s在1至30nm的范围内，所述催化剂在被实施在所述方法之前被硫化。

公开(公告)号：US20130334099A1

公开(公告)日：2013-12-19

申请号：US13996762

申请日：2011-12-15

申请人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

发明人： Karin Marchand ,  Alexandra Chaumonnot ,  Audrey Bonduelle ,  Veronique Dufaud ,  Frederic Lefebvre ,  Manuela Bader ,  Susana Lopes Silva

IPC分类号： C10G47/12

CPC分类号： C10G47/12 ,  B01J27/186 ,  B01J27/19 ,  B01J29/041 ,  B01J29/044 ,  B01J29/045 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/10 ,  B01J37/20 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G65/12 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/4018 ,  Y02P30/20

摘要： A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340° C. and a final boiling point below 540° C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HhXxMmOy)q−, said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

摘要翻译： 一种用于加氢裂化含烃原料的方法，其中至少50重量％的化合物的起始沸点高于340℃，最终沸点低于540℃，使用其氧化物中的催化剂 形成选自VIB族，VIII族和VB族金属中的至少一种金属，所述金属以至少一种式（HhXxMmOy）q-的多金属氧酸盐的形式存在，所述多金属氧酸盐存在于介孔结构基质中，基于 至少一个元素Y，所述基质的孔径在1.5至50nm之间并具有1至30nm厚度的非晶壁，所述催化剂在用于所述方法之前被硫化。