Nucleating agents for polyhydroxyalkanoates

    公开(公告)号:US20060058498A1

    公开(公告)日:2006-03-16

    申请号:US11224805

    申请日:2005-09-13

    IPC分类号: C08G63/02

    摘要: The present invention provides a process for crystallizing a polymer having at least 20 mole percent of hydroxyalkanoate repeat units, comprising admixing the polymer and a compound of the formula R1—C(O)N(R2)2, R1—C(O)NH—(R3)—NHC(O)—R1, R1—NHC(O)NH—(R3)—NHC(O)NH—R1, R1—NHC(O)—R2, R1—NHC(O)—(R3)—C(O)NH—R1, R1—C(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—NHC(O)—R1, or a combination thereof, at a first temperature, which is from about 5° C. to about 15° C. above the melting point of the polymer; and cooling the polymer at a second temperature, which is from about the glass transition temperature of the polymer to about the melting point of the compound. The present invention also provides a composition comprising a polymer having at least about 20 mole percent of hydroxyalkanoate repeat units, and a compound of the formula R1—C(O)N(R2)2, R1—C(O)NH—(R3)—NHC(O)—R1, R1—NHC(O)NH—(R3)—NHC(O)NH—R1, R1—NHC(O)—R2, R1—NHC(O)—(R3)—C(O)NH—R1, R1—C(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—NHC(O)—R1, or a combination thereof.