公开(公告)号：US08644003B2

公开(公告)日：2014-02-04

申请号：US11921922

申请日：2006-06-02

申请人： Katsuhiko Naoi ,  Kenji Machida

发明人： Katsuhiko Naoi ,  Kenji Machida

IPC分类号： H01G9/02 ,  H01M6/04 ,  H01G9/00 ,  H01L21/20

CPC分类号： H01G9/0032 ,  H01G9/0036 ,  H01G9/042 ,  H01G9/07 ,  Y10T29/417

摘要： A process is provided for producing an electrolytic capacitor element that can uniformly form a highly electrically conductive polymer having a nano thickness level on a nano porous anode element substrate and suitable for use in high-capacitance electrolytic capacitors used in emergency power supplies and backup power supplies in electronic equipment. An oxide film and an electrically conductive polymer film are formed by pulsed constant current electrolysis of a monomer for an electrically conductive polymer and a nanoporous valve action metal in an electrolysis solution comprising an ionic liquid.

摘要翻译： 提供了一种制造电解电容器元件的方法，该电解电容器元件可以在纳米多孔阳极元件基板上均匀地形成具有纳米厚度水平的高导电性聚合物，并且适用于应用电源和备用电源中使用的高电容电解电容器 在电子设备中。 在包含离子液体的电解溶液中，通过电导率聚合物的单体和纳米多孔阀作用金属的脉冲恒流电解形成氧化物膜和导电聚合物膜。

公开(公告)号：US20090296317A1

公开(公告)日：2009-12-03

申请号：US11921922

申请日：2006-06-02

申请人： Katsuhiko Naoi ,  Kenji Machida

发明人： Katsuhiko Naoi ,  Kenji Machida

IPC分类号： H01G9/022 ,  C25D11/00

CPC分类号： H01G9/0032 ,  H01G9/0036 ,  H01G9/042 ,  H01G9/07 ,  Y10T29/417

摘要： A process is provided for producing an electrolytic capacitor element that can uniformly form a highly electrically conductive polymer having a nano thickness level on a nano porous anode element substrate and suitable for use in high-capacitance electrolytic capacitors used in emergency power supplies and backup power supplies in electronic equipment. An oxide film and an electrically conductive polymer film are formed by pulsed constant current electrolysis of a monomer for an electrically conductive polymer and a nanoporous valve action metal in an electrolysis solution comprising an ionic liquid.

摘要翻译： 提供了一种制造电解电容器元件的方法，该电解电容器元件可以在纳米多孔阳极元件基板上均匀地形成具有纳米厚度水平的高导电性聚合物，并且适用于应用电源和备用电源中使用的高电容电解电容器 在电子设备中。 在包含离子液体的电解溶液中，通过电导率聚合物的单体和纳米多孔阀作用金属的脉冲恒流电解形成氧化物膜和导电聚合物膜。

公开(公告)号：US20140022701A1

公开(公告)日：2014-01-23

申请号：US14002248

申请日：2012-03-01

申请人： Kenji Machida ,  Sekihiro Takeda ,  Ryo Muroi ,  Nozomu Kamiyama ,  Masashi Ozawa

发明人： Kenji Machida ,  Sekihiro Takeda ,  Ryo Muroi ,  Nozomu Kamiyama ,  Masashi Ozawa

IPC分类号： C25B3/10 ,  H01G9/15 ,  H01G9/042

CPC分类号： C25B3/10 ,  C08G2261/3223 ,  C08G2261/51 ,  C08G2261/592 ,  C08G2261/94 ,  C08K5/43 ,  H01B1/127 ,  H01G9/0036 ,  H01G9/028 ,  H01G9/042 ,  H01G9/15 ,  Y10T428/31533 ,  C08L65/00

摘要： Disclosed is a polymerization solution for electrolytic polymerization having a small environmental load, having excellent economic efficiency and capable of producing a conductive polymer exhibiting excellent heat resistance. The polymerization solution has: a solvent consisting of 100 to 80% by mass of water and 0 to 20% by mass of an organic solvent; at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes; and at least one organic non-sulfonate supporting electrolyte having an anion with the molecular weight of 200 or more. A conductive polymer film densely filled with polymer particles is obtained by performing electrolytic polymerization using the polymerization solution. A polymer electrode provided with the conductive polymer film exerts excellent heat resistance and the electrochemical activity of the polymer electrode will hardly deteriorate even when being subjected to high temperatures. Moreover, a solid electrolyte capacitor containing the conductive polymer layer obtained by performing electrolytic polymerization using the polymerization solution exhibits low dielectric loss and equivalent series resistance and exerts excellent heat resistance.

摘要翻译： 公开了一种环境负荷小的电解聚合用聚合液，经济效益优异，能够制造具有优异耐热性的导电性聚合物。 聚合溶液具有：由100〜80质量％的水和0〜20质量％的有机溶剂构成的溶剂， 至少一种选自3,4-二取代噻吩的单体; 和至少一种具有分子量为200以上的阴离子的有机非磺酸盐担载电解质。 通过使用聚合溶液进行电解聚合，获得密实地填充有聚合物颗粒的导电聚合物膜。 设置有导电性聚合物膜的聚合物电极具有优异的耐热性，并且即使经受高温，聚合物电极的电化学活性也几乎不劣化。 此外，含有通过使用聚合溶液的电解聚合获得的导电聚合物层的固体电解质电容器具有低的介电损耗和等效的串联电阻，并且具有优异的耐热性。

公开(公告)号：US06859342B1

公开(公告)日：2005-02-22

申请号：US09504964

申请日：2000-02-16

申请人： Yasuhiko Shinjo ,  Morio Kondo ,  Akira Nakamura ,  Toshihiro Uehara ,  Naoto Hayashi ,  Kazutoshi Mutou ,  Kenji Machida ,  Junji Numazawa

发明人： Yasuhiko Shinjo ,  Morio Kondo ,  Akira Nakamura ,  Toshihiro Uehara ,  Naoto Hayashi ,  Kazutoshi Mutou ,  Kenji Machida ,  Junji Numazawa

IPC分类号： G11B5/39 ,  G11B5/58 ,  G11B5/187

CPC分类号： G11B5/581

摘要： A magnetic head device having excellent sliding contact between its slider surface and magnetic tape at the time of scanning is provided. This magnetic head device has a base member, a thin-film magnetic head formed in contact with the base member and accommodated in a non-magnetic layer with the top end of a magnetic gap being exposed, and an auxiliary member which sandwiches the non-magnetic layer between the auxiliary member and the base member. On the top ends of the base member, the non-magnetic layer, and the auxiliary member, a slider surface on which magnetic tape slides is formed in the aligning direction of the base member, the non-magnetic layer, and the auxiliary member, or in a direction inclined at a predetermined angle to the aligning direction. Accordingly, the non-magnetic layer can be made thin, and the area of the non-magnetic layer on the slider surface is small. Thus, the space between the magnetic head device and the magnetic tape can be made small, and the sliding contact of the magnetic head device can be improved.

摘要翻译： 提供了一种在扫描时其滑块表面和磁带之间具有优异的滑动接触的磁头装置。 该磁头装置具有：基部构件，形成为与基座构件接触并容纳在非磁性层中的薄膜磁头，其中磁隙的顶端被露出;以及辅助构件， 辅助构件和基座构件之间的磁性层。 在基部构件的顶端，非磁性层和辅助构件上，在基座构件，非磁性层和辅助构件的对准方向上形成有磁带滑动的滑块表面， 或者在相对于排列方向以预定角度倾斜的方向上。 因此，可以使非磁性层薄，并且滑块表面上的非磁性层的面积小。 因此，可以使磁头装置和磁带之间的空间小，并且可以提高磁头装置的滑动接触。

公开(公告)号：US09562293B2

公开(公告)日：2017-02-07

申请号：US14002248

申请日：2012-03-01

申请人： Kenji Machida ,  Sekihiro Takeda ,  Ryo Muroi ,  Nozomu Kamiyama ,  Masashi Ozawa

发明人： Kenji Machida ,  Sekihiro Takeda ,  Ryo Muroi ,  Nozomu Kamiyama ,  Masashi Ozawa

IPC分类号： H01G9/02 ,  H01G9/04 ,  H01G9/145 ,  H01G9/00 ,  C25B3/00 ,  C25B3/10 ,  H01G9/028 ,  H01G9/15 ,  C08K5/43 ,  H01B1/12 ,  H01G9/042

CPC分类号： C25B3/10 ,  C08G2261/3223 ,  C08G2261/51 ,  C08G2261/592 ,  C08G2261/94 ,  C08K5/43 ,  H01B1/127 ,  H01G9/0036 ,  H01G9/028 ,  H01G9/042 ,  H01G9/15 ,  Y10T428/31533 ,  C08L65/00

摘要： Disclosed is a polymerization solution for electrolytic polymerization having a small environmental load, having excellent economic efficiency and capable of producing a conductive polymer exhibiting excellent heat resistance. The polymerization solution has: a solvent consisting of 100 to 80% by mass of water and 0 to 20% by mass of an organic solvent; at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes; and at least one organic non-sulfonate supporting electrolyte having an anion with the molecular weight of 200 or more. A conductive polymer film densely filled with polymer particles is obtained by performing electrolytic polymerization using the polymerization solution. A polymer electrode provided with the conductive polymer film exerts excellent heat resistance and the electrochemical activity of the polymer electrode will hardly deteriorate even when being subjected to high temperatures. Moreover, a solid electrolyte capacitor containing the conductive polymer layer obtained by performing electrolytic polymerization using the polymerization solution exhibits low dielectric loss and equivalent series resistance and exerts excellent heat resistance.

摘要翻译： 公开了一种环境负荷小的电解聚合用聚合液，经济效益优异，能够制造具有优异耐热性的导电性聚合物。 聚合溶液具有：由100〜80质量％的水和0〜20质量％的有机溶剂构成的溶剂， 至少一种选自3,4-二取代噻吩的单体; 和至少一种具有分子量为200以上的阴离子的有机非磺酸盐担载电解质。 通过使用聚合溶液进行电解聚合，获得密实地填充有聚合物颗粒的导电聚合物膜。 设置有导电性聚合物膜的聚合物电极具有优异的耐热性，并且即使经受高温，聚合物电极的电化学活性也几乎不劣化。 此外，含有通过使用聚合溶液的电解聚合获得的导电聚合物层的固体电解质电容器具有低的介电损耗和等效的串联电阻，并且具有优异的耐热性。

公开(公告)号：US09558891B2

公开(公告)日：2017-01-31

申请号：US14002281

申请日：2012-03-01

申请人： Kenji Machida ,  Sekihiro Takeda ,  Ryo Muroi ,  Nozomu Kamiyama ,  Masashi Ozawa

发明人： Kenji Machida ,  Sekihiro Takeda ,  Ryo Muroi ,  Nozomu Kamiyama ,  Masashi Ozawa

IPC分类号： H01G9/00 ,  H01G9/02 ,  H01G9/04 ,  H01G9/145 ,  H01G9/028 ,  H01G9/15

CPC分类号： H01G9/028 ,  C08G2261/3223 ,  C08G2261/51 ,  H01G9/0036 ,  H01G9/15

摘要： Disclosed is a polymerization solution for electrolytic polymerization containing borodisalicylic acid and/or a salt thereof as a supporting electrolyte, in which precipitation due to the hydrolysis of borodisalicylate ions is inhibited and which provides a conductive polymer exhibiting excellent heat resistance. The polymerization solution has: a solvent consisting of 100 to 80% by mass of water and 0 to 20% by mass of an organic solvent; at least one monomer having a π-conjugated double bond; at least one supporting electrolyte selected from the group consisting of borodisalicylic acid and borodisalicylic salts; and at least one stabilizing agent selected from the group consisting of nitrobenzene and nitrobenzene derivatives, and the content of the stabilizing agent content is more than ⅛ mol per 1 mol of the supporting electrolyte. A complex is formed by the stabilizing agent and borodisalicylic acid, and the formation of precipitation due to the hydrolysis of borodisalicylate ions is inhibited.

摘要翻译： 公开了一种含有双水杨酸和/或其盐作为支持电解质的电解聚合的聚合溶液，其中由于硼二水杨酸根离子的水解引起的沉淀被抑制并且提供了具有优异的耐热性的导电聚合物。 聚合溶液具有：由100〜80质量％的水和0〜20质量％的有机溶剂构成的溶剂， 至少一种具有π共轭双键的单体; 至少一种选自硼二水杨酸和硼二水杨酸盐的支持电解质; 和选自硝基苯和硝基苯衍生物的至少一种稳定剂，并且每1mol支持电解质的稳定剂含量的含量大于⅛mol。 络合物由稳定剂和双水杨酸形成，并且由于水杨酸水杨酸根离子形成沉淀物被抑制。

公开(公告)号：US09184401B2

公开(公告)日：2015-11-10

申请号：US14008137

申请日：2012-03-31

申请人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

发明人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

IPC分类号： H01L51/44 ,  H01B1/12 ,  H01B1/20 ,  H01G9/20 ,  H01L51/00 ,  H01L51/42 ,  H01M14/00

CPC分类号： H01L51/442 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/792 ,  C08G2261/91 ,  H01B1/127 ,  H01B1/20 ,  H01G9/20 ,  H01G9/2004 ,  H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0006 ,  H01L51/0021 ,  H01L51/0037 ,  H01L51/0086 ,  H01L51/4226 ,  H01L51/441 ,  H01L2251/306 ,  H01L2251/308 ,  H01M14/005 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521

摘要： Disclosed is an electrode body for a solar cell, which is capable of being used as a component of both an organic thin-film solar cell and a dye-sensitized solar cell, and has excellent heat resistance. This electrode body for a solar cell is provided with a substrate with a conductive part at least on the surface and a conductive polymer layer located on the conductive part of the substrate, in which the conductive polymer layer includes: a polymer which is obtained by polymerizing a monomer selected from the group consisting of 3,4-disubstituted thiophenes; and an anion as a dopant to the polymer generated from at least one organic non-sulfonate compound having an anion with the molecular weight of 200 or more. Since the anion of the organic non-sulfonate compound is included as a dopant in the conductive polymer layer, the heat resistance of the conductive polymer layer is improved.

摘要翻译： 公开了一种用于太阳能电池的电极体，其能够用作有机薄膜太阳能电池和染料敏化太阳能电池的组分，并且具有优异的耐热性。 该太阳能电池用电极体具有至少在表面具有导电部的基板和位于基板的导电部的导电性聚合物层，导电性聚合物层中，导电性聚合物层包含：通过聚合而得到的聚合物 选自3,4-二取代噻吩的单体; 以及由具有分子量为200以上的阴离子的至少一种有机非磺酸盐化合物生成的聚合物作为聚合物的阴离子。 由于在导电聚合物层中包含有机非磺酸盐化合物的阴离子作为掺杂剂，所以导电聚合物层的耐热性得到改善。

公开(公告)号：US20130037411A1

公开(公告)日：2013-02-14

申请号：US13582282

申请日：2011-03-01

申请人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

发明人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

IPC分类号： C25D9/02 ,  B32B27/00 ,  C25D7/00

CPC分类号： H01G9/028 ,  C08G61/126 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/44 ,  H01B1/127 ,  H01G11/56 ,  H05B33/28 ,  Y02E60/13

摘要： Disclosed is a polymerization fluid for electropolymerization which exhibits a reduced environmental burden and excellent economic efficiency and which can yield a conductive polymer film that has high conductivity and that is dense and highly transparent. The polymerization fluid includes at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes which is dispersed as oil drops in surfactant-free water, and the polymerization fluid is transparent. The polymerization fluid can be produced by a method which includes: an addition step of adding the monomer to surfactant-free water to prepare a phase separation fluid where water and the monomer are phase-separated; a first dispersion step of irradiating the phase separation fluid with ultrasonic waves to make the monomer dispersed in the form of oil drops and thus prepare an opaque dispersion, and a second dispersion step of irradiating the opaque dispersion with ultrasonic waves having a frequency higher than that of the ultrasonic waves used in the first dispersion step to reduce the mean size of the oil drops of the monomer and thus prepare a transparent dispersion.

摘要翻译： 公开了用于电聚合的聚合流体，其具有降低的环境负担和优异的经济效率，并且可以产生具有高导电性并且致密和高度透明的导电聚合物膜。 聚合流体包括至少一种选自3,4-二取代噻吩的单体，其以油滴分散在不含表面活性剂的水中，聚合流体是透明的。 聚合流体可以通过以下方法制备：将单体添加到无表面活性剂的水中以制备其中水和单体相分离的相分离流体的添加步骤; 第一分散步骤，用超声波照射相分离液，使单体以油滴的形式分散，从而制备不透明的分散体;第二分散步骤，用频率高于其的频率的超声波照射不透明分散体。 的第一分散步骤中使用的超声波，以减少单体的油滴的平均尺寸，从而制备透明分散体。

公开(公告)号：US09419234B2

公开(公告)日：2016-08-16

申请号：US14007942

申请日：2012-03-31

申请人： Kenji Machida ,  Sekihiro Takeda ,  Ryo Muroi ,  Nozomu Kamiyama ,  Masashi Ozawa

发明人： Kenji Machida ,  Sekihiro Takeda ,  Ryo Muroi ,  Nozomu Kamiyama ,  Masashi Ozawa

IPC分类号： H01G9/20 ,  H01L51/44 ,  H01L31/0224 ,  C08K5/43 ,  H01L51/00 ,  C08G61/12 ,  H01M14/00

CPC分类号： H01L51/442 ,  C08G61/126 ,  C08K5/43 ,  H01G9/20 ,  H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  H01L31/022425 ,  H01L51/0006 ,  H01L51/0021 ,  H01L51/0037 ,  H01L51/0086 ,  H01L51/441 ,  H01M14/005 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521 ,  C08L65/00

摘要： Disclosed is an electrode body for a solar cell, which is capable of being used as a component of both an organic thin-film solar cell and a dye-sensitized solar cell, and has excellent heat resistance. This electrode body for a solar cell is provided with a substrate with a conductive part at least on the surface and a conductive polymer layer located on the conductive part of the substrate, in which the conductive polymer layer includes: a polymer derived from at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes; and an anion as a dopant to the polymer generated from at least one organic non-sulfonate compound having an anion with the molecular weight of 200 or more. Additionally, the density of the conductive polymer layer is in the range of 1.15 to 1.80 g/cm3. The dense conductive polymer layer including the anion as a dopant exhibits excellent heat resistance.

摘要翻译： 公开了一种用于太阳能电池的电极体，其能够用作有机薄膜太阳能电池和染料敏化太阳能电池的组分，并且具有优异的耐热性。 该太阳能电池用电极体具有至少在表面具有导电性部分的基板和位于基板的导电性部分上的导电性高分子层，导电性高分子层中，导电性聚合物层包含：至少一种 选自3,4-二取代噻吩的单体; 以及由具有分子量为200以上的阴离子的至少一种有机非磺酸盐化合物生成的聚合物作为聚合物的阴离子。 此外，导电聚合物层的密度在1.15至1.80g / cm 3的范围内。 包含阴离子作为掺杂剂的致密导电聚合物层表现出优异的耐热性。

公开(公告)号：US08927683B2

公开(公告)日：2015-01-06

申请号：US13582282

申请日：2011-03-01

申请人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

发明人： Mahito Atobe ,  Koji Nakabayashi ,  Kenji Machida ,  Sekihiro Takeda

IPC分类号： C08G75/00 ,  H01G9/028 ,  C08G61/12 ,  H01B1/12 ,  H05B33/28 ,  H01G11/56

CPC分类号： H01G9/028 ,  C08G61/126 ,  C08G2261/1424 ,  C08G2261/3223 ,  C08G2261/44 ,  H01B1/127 ,  H01G11/56 ,  H05B33/28 ,  Y02E60/13

摘要： Disclosed is a polymerization fluid for electropolymerization which exhibits a reduced environmental burden and excellent economic efficiency and which can yield a conductive polymer film that has high conductivity and that is dense and highly transparent. The polymerization fluid includes at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes which is dispersed as oil drops in surfactant-free water, and the polymerization fluid is transparent. The polymerization fluid can be produced by a method which includes: an addition step of adding the monomer to surfactant-free water to prepare a phase separation fluid where water and the monomer are phase-separated; a first dispersion step of irradiating the phase separation fluid with ultrasonic waves to make the monomer dispersed in the form of oil drops and thus prepare an opaque dispersion, and a second dispersion step of irradiating the opaque dispersion with ultrasonic waves having a frequency higher than that of the ultrasonic waves used in the first dispersion step to reduce the mean size of the oil drops of the monomer and thus prepare a transparent dispersion.

摘要翻译： 公开了用于电聚合的聚合流体，其具有降低的环境负担和优异的经济效率，并且可以产生具有高导电性并且致密和高度透明的导电聚合物膜。 聚合流体包括至少一种选自3,4-二取代噻吩的单体，其以油滴分散在不含表面活性剂的水中，聚合流体是透明的。 聚合流体可以通过以下方法制备：将单体添加到无表面活性剂的水中以制备其中水和单体相分离的相分离流体的添加步骤; 第一分散步骤，用超声波照射相分离液，使单体以油滴的形式分散，从而制备不透明的分散体;第二分散步骤，用频率高于其的频率的超声波照射不透明分散体。 的第一分散步骤中使用的超声波，以减少单体的油滴的平均尺寸，从而制备透明分散体。