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    Laminated Thermoplastic Resin Film and Laminated Thermoplastic Resin Film Roll
    4.
    发明申请
    Laminated Thermoplastic Resin Film and Laminated Thermoplastic Resin Film Roll 有权
    层压热塑性树脂膜和层压热塑性树脂膜卷

    公开(公告)号：US20080131704A1

    公开(公告)日：2008-06-05

    申请号：US11791767

    申请日：2005-11-28

    申请人： Naoki Mizuno ,  Shigenori Iwade ,  Hideki Sugihara ,  Chikao Morishige ,  Yasuhiro Nishino ,  Katsuhiko Nose ,  Toshitake Suzuki

    发明人： Naoki Mizuno ,  Shigenori Iwade ,  Hideki Sugihara ,  Chikao Morishige ,  Yasuhiro Nishino ,  Katsuhiko Nose ,  Toshitake Suzuki

    IPC分类号： B32B27/40

    CPC分类号： B32B27/36 ,  B32B27/40 ,  Y10T428/24802 ,  Y10T428/25 ,  Y10T428/31551 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31573 ,  Y10T428/31576 ,  Y10T428/31725 ,  Y10T428/31736 ,  Y10T428/31786 ,  Y10T428/31797

    摘要： [PROBLEMS] The present invention provides a laminated thermoplastic resin film which is excellent in adhesion and blocking resistance. [MEANS FOR SOLVING PROBLEMS] A laminated thermoplastic resin film has a covering layer containing a copolymerized polyester resin and a polyurethane resin on one side or both sides of a thermoplastic resin film, characterized in that the covering layer has a microphase-separated or nanophase-separated structure in PEs phase A comprising a copolymerized PE resin as a main component and PU phase B comprising a PU resin as a main component, and when the covering layer is observed by a scanning probe microscopy in phase measurement mode, an area ratio (surface fraction of PEs) of PEs phase A (which indicates a dark phase in phase image) of the surface of the covering layer defined by following formula (1) is 35% or more and less than 90% per a measurement area of 5 μm×5 μm. Surface fraction of PEs(%)=(area of PEs phase A/measurement area)×100   (1)

    摘要翻译： 本发明提供粘合性和耐粘连性优异的层压热塑性树脂膜。 解决问题的手段层压热塑性树脂膜在热塑性树脂膜的一面或两面具有包含共聚聚酯树脂和聚氨酯树脂的覆盖层，其特征在于，所述覆盖层具有微相分离或纳米相 - 在以共聚PE树脂为主要成分的PE相A中分离结构，以PU树脂为主要成分的PU相B，通过相位测定模式的扫描型显微镜观察覆盖层的面积比（面 由下式（1）定义的覆盖层表面的PE相A（表示相图中的暗相）的PE的分数为5mum×5mum的测量面积的35％以上且小于90％ 。 <？in-line-formula description =“In-line Formulas”end =“lead”？> PE的表面分数（％）=（PEs相A /测量面积的面积）×100（1） 公式描述=“内联公式”end =“tail”？>

    Laminated polyester film
    5.
    发明授权
    Laminated polyester film 失效
    层压聚酯薄膜

    公开(公告)号：US06306492B1

    公开(公告)日：2001-10-23

    申请号：US08997459

    申请日：1997-12-23

    申请人： Koji Yamada ,  Yasushi Sasaki ,  Toshitake Suzuki ,  Shinya Higashiura ,  Chikao Morishige

    发明人： Koji Yamada ,  Yasushi Sasaki ,  Toshitake Suzuki ,  Shinya Higashiura ,  Chikao Morishige

    IPC分类号： B32B518

    CPC分类号： C08J7/047 ,  B32B27/36 ,  C08J2367/02 ,  C08J2451/00 ,  Y10S428/91 ,  Y10T428/249985 ,  Y10T428/249992 ,  Y10T428/265 ,  Y10T428/273 ,  Y10T428/31786

    摘要： A laminated polyester film comprising a polyester base film and a layer comprising a polyester graft copolymer and which is formed at least on one surface of said polyester base film, said polyester graft copolymer comprising a hydrophobic copolymerizable polyester resin and an acid anhydride having at least one double bond grafted to said polyester resin. The laminated polyester film of the present invention exhibits good adhesive property, water resistance and resistance to blocking, particularly excellent adhesive property, by applying a specific polyester graft copolymer to a polyester base film.

    摘要翻译： 一种层叠聚酯膜，其包含聚酯基膜和包含聚酯接枝共聚物的层，并且其形成在所述聚酯基膜的至少一个表面上，所述聚酯接枝共聚物包含疏水性可共聚聚酯树脂和具有至少一个 双键接枝到所述聚酯树脂上。 本发明的层叠聚酯薄膜通过将特定的聚酯接枝共聚物涂布在聚酯基膜上，具有良好的粘合性，耐水性和耐粘连性，特别优异的粘合性。

    Laminated thermoplastic resin film and laminated thermoplastic resin film roll
    6.
    发明授权
    Laminated thermoplastic resin film and laminated thermoplastic resin film roll 有权
    复合热塑性树脂薄膜和层压热塑性树脂薄膜卷

    公开(公告)号：US07531238B2

    公开(公告)日：2009-05-12

    申请号：US11791767

    申请日：2005-11-28

    申请人： Naoki Mizuno ,  Shigenori Iwade ,  Hideki Sugihara ,  Chikao Morishige ,  Yasuhiro Nishino ,  Katsuhiko Nose ,  Toshitake Suzuki

    发明人： Naoki Mizuno ,  Shigenori Iwade ,  Hideki Sugihara ,  Chikao Morishige ,  Yasuhiro Nishino ,  Katsuhiko Nose ,  Toshitake Suzuki

    IPC分类号： B32B5/00 ,  B32B27/08 ,  B32B27/20 ,  B32B27/36 ,  B32B27/40

    CPC分类号： B32B27/36 ,  B32B27/40 ,  Y10T428/24802 ,  Y10T428/25 ,  Y10T428/31551 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31573 ,  Y10T428/31576 ,  Y10T428/31725 ,  Y10T428/31736 ,  Y10T428/31786 ,  Y10T428/31797

    摘要： The present invention provides a laminated thermoplastic resin film which is excellent in adhesion and blocking resistance. A laminated thermoplastic resin film has a covering layer containing a copolymerized polyester resin and a polyurethane resin on one side or both sides of a thermoplastic resin film, characterized in that the covering layer has a microphase-separated or nanophase-separated structure in polyester (PE) phase A comprising a copolymerized polyester resin as a main component and polyurethane (PU) phase B comprising a polyurethane resin as a main component, and when the covering layer is observed by a scanning probe microscopy in phase measurement mode, an area ration (surface fraction of PEs) of polyester phase A (which indicates a dark phase in phase image) of the surface of the covering layer defined by following the formula (1) is 35% or more and less than 90% per 20 a measurement area of 5 μm×5 μm. Surface fraction of PEs (%)=(area of PEs phase A/measurement area)×100.  (1)

    摘要翻译： 本发明提供粘合性和抗粘连性优异的层叠热塑性树脂膜。 层压热塑性树脂膜在热塑性树脂膜的一面或两面上具有包含共聚聚酯树脂和聚氨酯树脂的覆盖层，其特征在于，覆盖层在聚酯（PE）中具有微相分离或纳米相分离结构 ）相A包含以共聚聚酯树脂为主要成分的聚氨酯（PU）相B，以聚氨酯树脂为主要成分，当通过扫描型显微镜在相位测定模式下观察覆盖层时，面积比 由式（1）定义的覆盖层表面的聚酯相A（其表示相图中的暗相）的PE的分数为35％以上且小于90％，测定面积为5 妈妈妈妈 <？in-line-formula description =“In-line Formulas”end =“lead”？> PE的表面分数（％）=（PEs相A /测量面积的面积）×100。 （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>

    Film having fine voids and manufacture thereof
    9.
    发明授权
    Film having fine voids and manufacture thereof 失效
    薄膜具有细小的空隙及其制造

    公开(公告)号：US6004664A

    公开(公告)日：1999-12-21

    申请号：US110825

    申请日：1998-07-06

    申请人： Yasushi Sasaki ,  Ken-ichi Mori ,  Katsuya Ito ,  Toshitake Suzuki

    发明人： Yasushi Sasaki ,  Ken-ichi Mori ,  Katsuya Ito ,  Toshitake Suzuki

    IPC分类号： C08J5/18 ,  C08L23/02 ,  C08L25/08 ,  C08L67/02 ,  B32B27/06

    CPC分类号： C08J5/18 ,  C08L67/02 ,  C08J2367/02 ,  C08L23/02 ,  C08L25/08 ,  Y10S428/91 ,  Y10T428/249975 ,  Y10T428/249978 ,  Y10T428/249979

    摘要： A polyester film having fine voids, which comprises a polymer mixture comprising a polyester resin and a thermoplastic resin (B) incompatible with said polyester resin, and which has an apparent specific gravity of 0.6-1.3 and an inplane birefringence as determined from the equation:inplane birefringence=refractive index along lengthwise principal axis-refractive index along crosswise principal axis,of from -0.02 to +0.04, and manufacture thereof. A thermoplastic resin film having fine voids, which comprises a polymer mixture comprising a thermoplastic resin (A) and a thermoplastic resin (B) incompatible with said thermoplastic resin (A), and which has a ratio (L1/L2) of an average length (L1) of the voids at a cross section in the lengthwise direction of the film, to an average length (L2) of the voids at a cross section in the direction forming a right angle with said lengthwise direction, i.e., crosswise direction of the film, of 2/3-3/2, a thickness variation of the film of not more than 5%, and a void content of 5-50% by volume, and manufacture thereof. The polyester film having fine voids of the present invention has an extremely superior isotropy, excellent tear resistance, extremely superior water resistance, moisture absorption, dimensional stability, surface stability, gloss and vividness of printed matters, and mechanical strength, which have been particularly achieved by making apparent specific gravity and inplane birefringence fall within a specific range mentioned above. The thermoplastic resin film having fine voids of the present invention suffers less from curling by heat, which has been achieved by making (L1/L2), thickness variation and void content fall within a specific range mentioned above.

    摘要翻译： 一种具有微细空隙的聚酯膜，其包含聚酯混合物，其包含聚酯树脂和与所述聚酯树脂不相容的热塑性树脂（B），并且其表观比重为0.6-1.3，并且由下式确定的面内双折射： 平面双折射率=沿着横向主轴的纵向主轴折射率的折射率为-0.02至+0.04，并且其制造。 一种具有微细空隙的热塑性树脂膜，其包含含有热塑性树脂（A）和与所述热塑性树脂（A）不相容的热塑性树脂（B））的聚合物混合物，其具有平均长度（L1 / L2） （L1）在膜的长度方向上的截面处的空隙的长度方向，与沿着所述长度方向成直角的方向的截面的空隙的平均长度（L2），即 膜的2 / 3-3 / 2，膜的厚度变化不大于5％，空隙含量为5-50体积％，并且其制造。 具有本发明的微细空隙的聚酯膜具有非常优异的各向同性，优异的抗撕裂性，特别优异的耐水性，吸湿性，尺寸稳定性，表面稳定性，印刷物的光泽和鲜艳度以及机械强度。 通过使表观比重和面内双折射落入上述特定范围内。 本发明的具有微细空隙的热塑性树脂薄膜通过使（L1 / L2），厚度变化和空隙率落在上述特定范围内而实现的热量卷曲不足。

    Void-containing composite film of polyester type
    10.
    发明授权
    Void-containing composite film of polyester type 失效
    聚酯型空隙复合膜

    公开(公告)号：US5422175A

    公开(公告)日：1995-06-06

    申请号：US67813

    申请日：1993-05-27

    申请人： Katsuya Ito ,  Atsushi Taga ,  Katsufumi Kumano ,  Yasushi Sasaki ,  Toshitake Suzuki ,  Akito Hamano

    发明人： Katsuya Ito ,  Atsushi Taga ,  Katsufumi Kumano ,  Yasushi Sasaki ,  Toshitake Suzuki ,  Akito Hamano

    IPC分类号： B29C55/00 ,  B29C55/02 ,  B32B3/26 ,  B32B27/20 ,  B32B27/36 ,  B41M5/52 ,  G03C1/795

    CPC分类号： G03C1/7954 ,  B29C55/005 ,  B29C55/023 ,  B32B27/20 ,  B32B27/36 ,  B32B3/26 ,  B41M5/5272 ,  B29K2105/16 ,  Y10T428/24893 ,  Y10T428/249953 ,  Y10T428/249987 ,  Y10T428/249991 ,  Y10T428/31786 ,  Y10T428/31797

    摘要： A void-containing composite film including (A) a polyester base layer containing voids composed mainly of a polymer mixture of a polyester and a thermoplastic resin which is not compatible with the polyester and is selected from the group of polystyrene resins, polyolefin resins, polyacrylic resins, polycarbonate resins, polysulfone resins, cellulose resins, polysiloxane resins and silicone resins, and (B) at least one outer surface layer composed mainly of polyethylene terephthalate and formed on at least one side of the polyester base layer (A), the polyester base layer (A) and the at least one outer surface layer (B) being formed into a composite film by co-extrusion, followed by orientation in at least one direction, the void percentage of a surface portion having 3 .mu.m thickness from the surface of the polyester base layer (A) is 8% by volume or less, the average void percentage of the composite film is 10% to 50% by volume, and the composite film has substantially no voids at the interface between the polyester base layer (A) and the outer surface layer (B).

    摘要翻译： 一种含空隙复合膜，其包括（A）聚酯基层，其主要由聚酯与热塑性树脂的聚合物混合物构成，所述聚合物基层与聚酯不相容，并且选自聚苯乙烯树脂，聚烯烃树脂，聚丙烯酸 树脂，聚碳酸酯树脂，聚砜树脂，纤维素树脂，聚硅氧烷树脂和有机硅树脂，以及（B）主要由聚对苯二甲酸乙二醇酯构成的至少一个外表面层，形成在聚酯基层（A）的至少一面上，聚酯 基底层（A）和至少一个外表面层（B）通过共挤出形成复合膜，然后在至少一个方向上取向，从具有3μm厚度的表面部分的空隙率 聚酯基层（A）的表面为8体积％以下，复合膜的平均空隙率为10〜50体积％，复合膜在第 e接合在聚酯基层（A）和外表面层（B）之间。