公开(公告)号：US5324548A

公开(公告)日：1994-06-28

申请号：US968874

申请日：1992-10-30

申请人： Kazufumi Ogawa ,  Hideharu Tamura ,  Norihisa Mino

发明人： Kazufumi Ogawa ,  Hideharu Tamura ,  Norihisa Mino

IPC分类号： G11B7/26 ,  B05D1/18 ,  B41M5/26 ,  G03C1/73 ,  G11B7/24 ,  G11B7/244 ,  G11B7/245 ,  B05D3/06

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y10/00 ,  B82Y40/00 ,  G11B7/245

摘要： A method for making an optical recording medium having an optically responsive polydiacetylene monomolecular film or monomolecular built-up film is provided. In the method, a substrate having a hydrophilic surface is immersed in a solution, in organic solvent, of a substance containing a diacetylene group and an --Si--Cl group to form a monomolecular film of the substance on the substrate by chemical adsorption. The diacetylene groups are polymerized by energy beam irradiation to obtain the optically responsive polydiacetylene film. This medium is usable as a write-once or rewriteable medium.

摘要翻译： 提供了一种制备具有光学响应的​​聚二乙炔单分子膜或单分子组合膜的光学记录介质的方法。 在该方法中，将具有亲水性表面的基材浸渍在含有二乙炔基和-Si-Cl基的物质的有机溶剂的溶液中，通过化学吸附在基板上形成物质的单分子膜。 通过能量束照射使乙炔基聚合，得到光学响应性聚二乙炔膜。 该介质可用作一次写入或可重写介质。

公开(公告)号：US4996075A

公开(公告)日：1991-02-26

申请号：US287090

申请日：1988-12-21

申请人： Kazufumi Ogawa ,  Hideharu Tamura ,  Norihisa Mino

发明人： Kazufumi Ogawa ,  Hideharu Tamura ,  Norihisa Mino

IPC分类号： G03F7/075 ,  G03F7/26

CPC分类号： B82Y30/00 ,  G03F7/0757 ,  G03F7/265

摘要： A responsive film containing a responsible group occuring a chemical reaction by energy beam is formed on an insulated substrate, and energy beam is irradiated in a pattern, and part of the responsive group is selectively deactivated or activated, and only the remaining portion of the responsive group of the responsive film is coupled with a chemical substance containing metal in a later process, and an ultrafine pattern of metal film is formed.

公开(公告)号：US5196227A

公开(公告)日：1993-03-23

申请号：US389395

申请日：1989-08-04

申请人： Kazufumi Ogawa ,  Hideharu Tamura ,  Norihisa Mino

发明人： Kazufumi Ogawa ,  Hideharu Tamura ,  Norihisa Mino

IPC分类号： G11B7/26 ,  B05D1/18 ,  B41M5/26 ,  G03C1/73 ,  G11B7/24 ,  G11B7/244 ,  G11B7/245

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y10/00 ,  B82Y40/00 ,  G11B7/245

摘要： A method for making an optical recording medium having an optically responsive polydiacetylene monomolecular film or monomolecular built-up film is provided. In the method, a substrate having a hydrophilic surface is immersed in a solution, in organic solvent, of a substance containing a diacetylene group and an --Si--Cl group to form a monomolecular film of the substance on the substrate by chemical adsorption. The diacetylene groups are polymerized by energy beam irradiation to obtain the optically responsive polydiacetylene film. This medium is usable as a write-once or rewriteable medium.

摘要翻译： 提供了一种制备具有光学响应的​​聚二乙炔单分子膜或单分子组合膜的光学记录介质的方法。 在该方法中，将具有亲水性表面的基材浸渍在含有二乙炔基和-Si-Cl基的物质的有机溶剂的溶液中，通过化学吸附在基板上形成物质的单分子膜。 通过能量束照射使乙炔基聚合，得到光学响应性聚二乙炔膜。 该介质可用作一次写入或可重写介质。

公开(公告)号：US5515190A

公开(公告)日：1996-05-07

申请号：US859875

申请日：1992-03-30

申请人： Kazufumi Ogawa ,  Norihisa Mino ,  Hideharu Tamura

发明人： Kazufumi Ogawa ,  Norihisa Mino ,  Hideharu Tamura

IPC分类号： G02F1/1337

CPC分类号： B82Y30/00 ,  G02F1/133719

摘要： An alignment film for liquid crystal formed by monomolecular film comprising silane-type compounds with a linear hydrocarbon chain and method for production of said film, as well as liquid crystal display units utilizing said film and method for production of said display unit are disclosed.

摘要翻译： 公开了一种由含有直链烃链的硅烷型化合物和所述薄膜的制造方法的单分子膜形成的液晶取向膜，以及利用所述薄膜的液晶显示装置及其制造方法。

公开(公告)号：US5133895A

公开(公告)日：1992-07-28

申请号：US489248

申请日：1990-03-05

申请人： Kazufumi Ogawa ,  Norihisa Mino ,  Hideharu Tamura

发明人： Kazufumi Ogawa ,  Norihisa Mino ,  Hideharu Tamura

IPC分类号： G02F1/1337

CPC分类号： B82Y30/00 ,  G02F1/133719

摘要： An alignment film for liquid crystal formed by monomolecular film comprising silane-type compounds with a linear hydrocarbon chain and method for production of said film, as well as liquid crystal display units utilizing said film and method for production of said display unit are disclosed.

公开(公告)号：US4968524A

公开(公告)日：1990-11-06

申请号：US256619

申请日：1988-10-12

申请人： Kazufumi Ogawa ,  Hideharu Tamura ,  Norihisa Mino

发明人： Kazufumi Ogawa ,  Hideharu Tamura ,  Norihisa Mino

IPC分类号： B05D1/18 ,  C08F138/00 ,  G02F1/361 ,  H01L21/3205 ,  H01L51/30

CPC分类号： H01L51/0075 ,  B05D1/185 ,  B82Y10/00 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y40/00 ,  C08F138/00 ,  G02F1/3615 ,  G02F1/3618 ,  H01L21/32056 ,  H01L51/0041 ,  H01L51/0094

摘要： The present invention relates to an electric material, and particularly it relates to an organic substance having a polyacetylene linkage which exhibits electrical conductivity and nonlinear optical effect.More particularly, the present invention provides a process for producing an organic substance having a polyacetylene linkage which can be utilized, for example, as an electric material, said process comprising immersing a substrate having a hydrophilic surface in a solution of a substance containing an acetylene (--C.tbd.C--) group and a chlorosilane (--SiCl.sub.3) group dissolved in a nonaqueous organic solvent, thereby subjecting the substance containing an acetylene group and a chlorosilane group to chemical adsorption on the surface of the substrate, subjecting said substance to polymerization reaction by the use of radiation such as X-rays, electron beams, .gamma.-rays, or the like, and thereby producing a polyacetylene.

公开(公告)号：US07220468B2

公开(公告)日：2007-05-22

申请号：US11488994

申请日：2006-07-19

申请人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

发明人： Kazufumi Ogawa ,  Norihisa Mino ,  Shinichi Yamamoto

IPC分类号： C09K19/06

CPC分类号： H01L51/0545 ,  B82Y10/00 ,  G02F1/133711 ,  G02F1/133719 ,  G02F1/13378 ,  G02F1/133784 ,  G02F1/133788 ,  G02F2001/133796 ,  G02F2202/027 ,  H01B1/12 ,  H01B1/125 ,  H01B1/127 ,  H01L51/0012 ,  H01L51/0075 ,  H01L51/0508 ,  H01L51/0595 ,  H01L51/42 ,  H01L51/428 ,  Y02E10/549 ,  Y02P70/521 ,  Y10S428/91 ,  Y10T428/10 ,  Y10T428/1005 ,  Y10T428/1014 ,  Y10T428/31663

摘要： It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (ρ) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×105 S/cm, and preferably at least 1×107 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.

摘要翻译： 本发明的目的是提供一种具有有机分子的导电有机薄膜，该有机分子的一端包含共价结合到基材表面的端键合基团，位于有机分子的任何部分并且被聚合的共轭键合基团 与其它分子，以及不包括活性氢并且位于末端键合基团和共轭键合基团之间的任何部分的极性官能团，其中有机分子取向并且它们的共轭键合基团聚合，形成导电 网络。 导电有机薄膜在室温（25℃）下的电导率（rho）至少为5.5×10 -5 S / cm，优选至少为1×10 7 / S / cm，没有掺杂剂，具有比诸如金和银的金属显着更高的导电率。 特别地，通过电解氧化聚合而聚合的聚吡咯或聚噻吩键共轭键具有高导电性。

公开(公告)号：US06593000B2

公开(公告)日：2003-07-15

申请号：US10058220

申请日：2002-01-29

申请人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： B32B904

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  Y10T428/261 ,  Y10T428/31504 ,  Y10T428/31663

摘要： A highly dense chemically adsorbed film is formed by repeating the alternate process of adsorption reaction and washing. Adsorption reaction is directed by contacting the substrate surface, which has or is given an alkali metal or a functional group, with a chemical adsorbent, having halosilyl or alkoxysilyl groups at the end of molecules. An unreacted chemical adsorbent is then washed away from the substrate surface. The alternate treatment of adsorption reaction and washing is repeated, thereby covalently bonding a chemically adsorbed film to the substrate surface. As a result, a chemically adsorbed film is formed in which stem molecules are directly or indirectly covalently bonded to the substrate surface via at least one element chosen from the group consisting of Si, Ge, Sn, Ti, Zr, S or C and graft molecules are covalently bonded to at least one element chosen from Si, Ge, Sn, Ti, Zr, S or C via at least one bond chosen from —SiO—, —GeO—, SnO—, —TiO—, ZrO—, —SO2—, —SO— and —C—.

公开(公告)号：US06333074B1

公开(公告)日：2001-12-25

申请号：US09480252

申请日：2000-01-11

申请人： Kazufumi Ogawa ,  Yasuo Takebe ,  Norihisa Mino

发明人： Kazufumi Ogawa ,  Yasuo Takebe ,  Norihisa Mino

IPC分类号： B05D300

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  F28F17/005 ,  F28F2245/02 ,  Y10T428/2936 ,  Y10T428/2995 ,  Y10T428/31663 ,  Y10T428/31678

摘要： By forming a film that comprises a microcrystalline polymer having at least a fluorocarbon group and has a rough surface on a surface of a base material, super-water-repellency is provided, the dew condensation water of an air conditioner, for example, can be easily removed, and the freezing of the fin of the heat exchanger can be prevented. A fin that is made of aluminium is coated with a solution for forming a coating film, in which CF3(CF2)7—(CH2)2—SiCl3 is diluted with nonaqueous cyclohexamethyl trisiloxane at a concentration of 10 vol. % for preparation, to a thickness of 1 to 10 &mgr;m by a brush, and then the cyclohexamethyl trisiloxane is vaporized in an atmosphere having a relative humidity of about 75% at room temperature. CF3(CF2)7—(CH2)2—SiCl3 that remained on the fin is rapidly hydrolyzed with the moisture in the atmosphere, and the moisture in air and a —SiCl3 group dehydrochlorinated to form a microcrystalline polymer on the fin. As a result, a coating film having a surface roughness in the range of 1 to 40 &mgr;m and a contact angle of about 171° to water can be formed.

摘要翻译： 通过形成包含至少具有碳氟化合物基团并且在基材表面上具有粗糙表面的微晶聚合物的膜，提供超疏水性，例如空调的结露水可以是 容易地除去，并且可以防止热交换器的翅片的冻结。 用铝制成的翅片涂覆有形成涂膜的溶液，其中CF 3（CF 2）7 - （CH 2）2 -SiCl 3用10体积浓度的非水性环己甲基三硅氧烷稀释。 制备时，用刷子将其厚度设定为1〜10μm，然后在室温下在相对湿度为约75％的气氛中将环己甲基三硅氧烷蒸发。 残留在翅片上的CF 3（CF 2）7 - （CH 2）2 -SiCl 3随着大气中的水分，空气中的水分和-SiCl 3基团脱氯化氢而迅速水解，从而在翅片上形成微晶聚合物。 结果，可以形成表面粗糙度为1〜40μm，与水接触角为约171°的涂膜。

公开(公告)号：US5869136A

公开(公告)日：1999-02-09

申请号：US12753

申请日：1993-02-03

申请人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

发明人： Tadashi Ohtake ,  Norihisa Mino ,  Kazufumi Ogawa

IPC分类号： B05D1/18 ,  C03C23/00 ,  B05D1/36

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  C03C23/00

摘要： A chemically adsorbed multilayer film is formed through the process of replacing a halogen atom on the surface of a chemically adsorbed film with an alkaline metal or changing the halogen atom to a Grignard group by Grignard reaction. This manufacturing method does not disrupt the molecules of the chemically adsorbed film, is easy to perform, low in cost and is safe. After replacing the halogen (for example, Br) on the surface of the film with an alkaline metal such as Li, a condensation reaction including a dealkalihalide reaction is promoted by contacting the chemically adsorbed film with an adsorbent, such as a chemical adsorbent--containing a halosilane group at one end of a molecule--dissolved in a nonaqueous solvent. A chemically adsorbed multilayer film is then formed by reacting the chemically adsorbed film with chemical absorption composition and with water after removing unreacted adsorbents using a nonaqueous solution.

摘要翻译： 通过用碱金属代替化学吸附膜表面上的卤素原子或通过格利雅反应将卤素原子改变成格利雅特基团的方法形成化学吸附的多层膜。 该制造方法不会破坏化学吸附膜的分子，容易实施，成本低，安全。 用Li等碱性金属取代膜表面的卤素（例如Br）后，通过使化学吸附膜与吸附剂（如含化学吸附剂）接触来促进包括脱卤化物反应的缩合反应 分子一端的卤代硅烷基溶解在非水溶剂中。 然后通过使用非水溶液除去未反应的吸附剂，使化学吸附膜与化学吸收组合物和水反应形成化学吸附的多层膜。