摘要:
A polyester resin for metal plate coating which contains a dimer acid in an amount of 2 to 10 mol %, as a dicarboxylic acid component and has a weight average molecular weight (Mw) ranging from 70,000 to 160,000. Thus, there can be provided a polyester resin for metal plate coating that has not only excellent film forming capability and corrosion resistance but also excellent impact resistance. Further, there can be provided a resin-coated metal plate excelling in properties, such as corrosion resistance, impact resistance (dent resistance), workability and flavor, and provided, fabricated from the resin-coated metal plate, a metal can and can lid.
摘要:
A resin-coated seamless can of the present invention is a resin-coated seamless can formed of a resin-coated metal sheet 1 which is produced by coating a polyester resin layer 3 containing polyethylene terephthalate onto a surface of a metal substrate 2, wherein the density of a polyester resin layer of a can inner surface side is set to equal to or more than 1.36 at a can barrel upper portion. Further, an infrared dichroic ratio (R1) of the polyester resin layer at the inner surface side of the can barrel portion which is expressed by a following formula (1) is set to equal to or more than 1.1. R1=Iw(⊥)/Iw(∥) . . . (1). In the formula (1), Iw(⊥) indicates an infrared absorption intensity of 973 cm−1 with respect to polarized infrared rays perpendicular to the can height direction at the can barrel portion, and Iw(∥) indicates an infrared absorption intensity of 973 cm−1 with respect to polarized infrared rays parallel to the can height direction at the can barrel portion.
摘要:
A polyester resin for metal plate coating which contains a dimer acid in an amount of 2 to 10 mol %, as a dicarboxylic acid component and has a weight average molecular weight (Mw) ranging from 70,000 to 160,000. Thus, there can be provided a polyester resin for metal plate coating that has not only excellent film forming capability and corrosion resistance but also excellent impact resistance. Further, there can be provided a resin-coated metal plate excelling in properties, such as corrosion resistance, impact resistance (dent resistance), workability and flavor, and provided, fabricated from the resin-coated metal plate, a metal can and can lid.
摘要:
Microprotein-inactivating ultrafine metal particles comprising ultrafine metal particles having a bond between an organic acid component and a metal, having an infrared absorption peak ascribable to the bond between the organic acid and the metal near 1518 cm−1, and capable of efficiently inactivating microproteins without impairing properties of the resin or formability thereof. When used in the form of a resin composition or a coating agent, the microprotein-inactivating ultrafine metal particles are capable of exhibiting an effect for inactivating microproteins.
摘要:
Adsorptive ultra-fine metal particles having a bond between an organic acid component and a metal, and exhibiting an infrared absorption peak derived from the bond between the organic acid component and the metal near 1518 cm−1. The adsorptive ultra-fine metal particles are capable of exhibiting excellent deodorizing property and VOC-adsorbing property without impairing properties and formability of the resin. The invention is further concerned to an adsorptive resin composition and an adsorptive coating material containing the adsorptive ultra-fine metal particles and are capable of forming shaped resin articles or coatings.
摘要:
A resin-coated seamless can of the present invention is a resin-coated seamless can formed of a resin-coated metal sheet 1 which is produced by coating a polyester resin layer 3 containing polyethylene terephthalate onto a surface of a metal substrate 2, wherein the density of a polyester resin layer of a can inner surface side is set to equal to or more than 1.36 at a can barrel upper portion. Further, an infrared dichroic ratio (R1) of the polyester resin layer at the inner surface side of the can barrel portion which is expressed by a following formula (1) is set to equal to or more than 1.1. R1=Iw(⊥)/Iw(∥) (1). In the formula (1), Iw(⊥) indicates an infrared absorption intensity of 973 cm−1 with respect to polarized infrared rays perpendicular to the can height direction at the can barrel portion, and Iw(∥) indicates an infrared absorption intensity of 973 cm−1 with respect to polarized infrared rays parallel to the can height direction at the can barrel portion.
摘要:
Microprotein-inactivating ultrafine metal particles comprising ultrafine metal particles having a bond between an organic acid component and a metal, having an infrared absorption peak ascribable to the bond between the organic acid and the metal near 1518 cm−1, and capable of efficiently inactivating microproteins without impairing properties of the resin or formability thereof. When used in the form of a resin composition or a coating agent, the microprotein-inactivating ultrafine metal particles are capable of exhibiting an effect for inactivating microproteins.
摘要:
A polyester resin for covering metal sheets, comprising an acid component chiefly consisting of a terephthalic acid and, further, containing 1 to 15 mol % of an isophthalic acid and 2 to 10 mol % of a dimeric acid; and an alcohol component chiefly consisting of an ethylene glycol; wherein the dimeric acid contains not less than 20 mol % of an aliphatic dimeric acid, and the molar ratio of the aliphatic dimeric acid and an alicyclic dimeric acid is in a range of 1:1 to 1:5. The polyester resin for covering metal sheets features excellent film-forming property, closely adhering property during the working and elution resistance.
摘要:
A fatty acid metal salt used for forming ultrafine metal particles satisfying at least one of that:(i) the water content is 200 ppm or less; (ii) the volume-cumulative particle diameter D90 is 80 μm or smaller as measured by the particle size distribution measuring method of the laser diffraction/scattering type; or (iii) a metal of an atomic weight of 50 to 200 is contained, and the amount of the unreacted substance or the by-product is 4.0 mol % or less when the fatty acid metal salt is formed. The fatty acid metal salt can be favorably used for forming ultrafine metal particles in a resin, or for forming a resin composition, a coating, a dispersion solution or a molded article containing the ultrafine metal particles.
摘要:
Adsorptive ultra-fine metal particles having a bond between an organic acid component and a metal, and exhibiting an infrared absorption peak derived from the bond between the organic acid component and the metal near 1518 cm−1. The adsorptive ultra-fine metal particles are capable of exhibiting excellent deodorizing property and VOC-adsorbing property without impairing properties and formability of the resin. The invention is further concerned to an adsorptive resin composition and an adsorptive coating material containing the adsorptive ultra-fine metal particles and are capable of forming shaped resin articles or coatings.