公开(公告)号：US20050064325A1

公开(公告)日：2005-03-24

申请号：US10937336

申请日：2004-09-10

申请人： Ippei Nakamura ,  Kazuo Maemoto

发明人： Ippei Nakamura ,  Kazuo Maemoto

IPC分类号： G03F7/004 ,  B41C1/10 ,  G03F7/00 ,  G03C1/76

CPC分类号： B41C1/1008 ,  B41C1/1016 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/12 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/262 ,  B41C2210/264 ,  B41C2210/266

摘要： The planographic printing plate precursor of the invention includes a recording layer capable of forming an image upon irradiation with infrared rays, wherein the recording layer comprises (A) an alkali-soluble resin having, in a main chain, a structural unit containing at least one type of bond selected from an amide bond, urea bond, urethane bond and ester bond and having at least one type of acid group selected from a phenolic hydroxyl group, sulfonamide group and active imide group, and (B) an infrared absorbing agent. The invention provides a positive-working planographic printing plate precursor excellent in printing durability and chemical resistance.

摘要翻译： 本发明的平版印刷版原版包括能够在用红外线照射时形成图像的记录层，其中记录层包含（A）碱溶性树脂，其主链中含有至少一个 选自酰胺键，脲键，氨基甲酸酯键和酯键的键的键，并且具有至少一种选自酚羟基，磺酰胺基和活性酰亚胺基的酸基，和（B）红外吸收剂。 本发明提供了印刷耐久性和耐化学性优异的正性平版印刷版前体。

公开(公告)号：US06576397B2

公开(公告)日：2003-06-10

申请号：US09729350

申请日：2000-12-05

申请人： Nobuyuki Kita ,  Kazuo Maemoto

发明人： Nobuyuki Kita ,  Kazuo Maemoto

IPC分类号： G03F7038

CPC分类号： B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24

摘要： A heat-sensitive lithographic printing plate precursor, comprising a support having a hydrophilic surface on which (1) a thermal polymerization layer comprising an aqueous alkali-soluble polymer having addition polymerizable unsaturated bonds at its side chains and a thermal polymerization initiator and (2) a water-soluble overcoat layer comprising a water-soluble polymer and a compound capable of converting light into heat are provided in this order.

摘要翻译： 一种热敏性平版印刷版原版，其特征在于，具有亲水性表面的载体，（1）热聚合层，其包含在侧链具有加聚性不饱和键的水溶性聚合物水溶性聚合引发剂和（2） 依次提供包含水溶性聚合物和能够将光转化成热的化合物的水溶性外涂层。

公开(公告)号：US06114083A

公开(公告)日：2000-09-05

申请号：US152517

申请日：1998-09-14

申请人： Koichi Kawamura ,  Kazuo Maemoto ,  Sumiaki Yamasaki ,  Tadahiro Sorori ,  Hiroshi Tashiro ,  Kiyotaka Fukino

发明人： Koichi Kawamura ,  Kazuo Maemoto ,  Sumiaki Yamasaki ,  Tadahiro Sorori ,  Hiroshi Tashiro ,  Kiyotaka Fukino

IPC分类号： B41C1/10 ,  B41M5/36 ,  G03F7/004

CPC分类号： B41M5/368 ,  B41C1/1041

摘要： A radiation-sensitive planographic printing plate which is excellent in terms of durability wherein development with water, or direct production of the plate from digital data through infrared laser recording in particular such that a special process is not necessary, is possible, by forming on a support a photosensitive layer containing a reaction product of a compound having in a molecule thereof a functional group X and a functional group Y and a compound represented by a formula (1) stated below, or alternatively, containing a polymerization product of a compound having the functional group X and a compound represented by the formula (1) stated below. Further by incorporating water-insoluble particles in this photosensitive layer, many voids are formed in the photosensitive layer, further improving sensitivity and discrimination. The functional group X is a group selected from among a sulfonic acid ester group, a disulfone group, a sulfonimide group, and an alkoxyalkyl ester group and the functional group Y is a group selected from among --OH, --NH.sub.2, --COOH, --NH--CO--R.sub.3, and --Si(OR.sub.4).sub.3 [wherein R.sub.3 and R.sub.4 each represents an alkyl group or an aryl group].(R.sub.1).sub.n --X--(OR.sub.2).sub.4-n (1)wherein R.sub.1 and R.sub.2 each represents an alkyl group or an aryl group; X represents Si, Al, ti, or Zr; and n represents an integer from 0 to 2.

摘要翻译： 一种辐射敏感的平版印刷版，其耐久性优异，可以用水进行显影，或者通过红外激光记录从数字数据直接生产印版，特别是通过特殊工艺不需要，可以通过在 支持含有分子中具有官能团X和官能团Y的化合物和由下式（1）表示的化合物的反应产物的感光层，或者包含具有下式的化合物的聚合产物： 官能团X和下述式（1）表示的化合物。 此外，通过在该感光层中引入水不溶性颗粒，在感光层中形成许多空隙，进一步提高了敏感性和鉴别性。 官能团X是选自磺酸酯基，二砜基，磺酰亚胺基和烷氧基烷基酯基的基团，官能团Y是选自-OH，-NH 2，-COOH， - NH-CO-R3和-Si（OR4）3 [其中R3和R4各自表示烷基或芳基]。 （R1）n-X-（OR2）4-n（1）其中R1和R2各自表示烷基或芳基; X表示Si，Al，Ti或Zr; n表示0〜2的整数。

公开(公告)号：US4629680A

公开(公告)日：1986-12-16

申请号：US695503

申请日：1985-01-28

申请人： Masayuki Iwasaki ,  Minoru Maeda ,  Fumiaki Shinozaki ,  Kazuo Maemoto

发明人： Masayuki Iwasaki ,  Minoru Maeda ,  Fumiaki Shinozaki ,  Kazuo Maemoto

IPC分类号： C08F2/48 ,  C08F2/50 ,  G03F7/033 ,  G03C1/68 ,  C08F8/00

CPC分类号： C08F2/48 ,  G03F7/033 ,  Y10S430/111

摘要： A photopolymerizable composition is described, comprising an addition polymerizable unsaturated compound having at least two ethylenically unsaturated double bonds in the molecule, a photopolymerzation initiator, and a binder, said binder being a copolymer composed of at least one recurring unit of group (A), at least one recurring unit of group (B), and at least can recurring unit of group (C), and having a weight average molecular weight of 5,000 to 5,000,000, wherein(A) is a methacrylate or benzyl methacrylate unit having a glass transition point of the homopolymer of higher than 50.degree. C. and having an alkyl group having from 3 to 10 carbon atoms,(B) is an acrylate unit having a glass transition point of the homopolymer of lower than 110.degree. C. and having an alkyl group having from 1 to 6 carbon atoms, and(C) is an .alpha.,.beta.-ethylenically unsaturated carboxylic acid unit, and whereinthe content of the component of group (A) is from 5 to 70 mol %, the content of the component of group (B) is from 5 to 70 mol %, and the content of the component of group (C) is from 20 to 60 mol %, provided that the total content of the components of groups (A), (B) and (C) is 100 mol %.

摘要翻译： 描述了一种可光聚合组合物，其包含在分子中具有至少两个烯键式不饱和双键的加成聚合的不饱和化合物，光聚合引发剂和粘合剂，所述粘合剂是由至少一个组（A）的重复单元， （B）的至少一个重复单元，和至少可以是（C）组的重复单元，并且具有5,000至5,000,000的重均分子量，其中（A）是具有玻璃化转变的甲基丙烯酸酯或甲基丙烯酸苄酯单元 的均聚物的高分子量点，具有3〜10个碳原子的烷基，（B）是具有低于110℃的均聚物的玻璃化转变点的丙烯酸酯单元，具有烷基 具有1至6个碳原子的基团，和（C）是α，β-烯键式不饱和羧酸单元，其中组分（A）的组分含量为5-70mol％，组分的含量 （B）成分的总含量为5〜70摩尔％，组（C）的成分的含量为20〜60摩尔％，条件是（A），（B） 和（C）为100摩尔％。

公开(公告)号：US20070122743A1

公开(公告)日：2007-05-31

申请号：US11635481

申请日：2006-12-08

申请人： Kazuo Maemoto

发明人： Kazuo Maemoto

IPC分类号： G03C1/00

CPC分类号： B41C1/1016 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/10 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/262 ,  B41C2210/266 ,  Y10S430/107 ,  Y10S430/145

摘要： A planographic printing plate precursor includes a support having disposed thereon a recording layer containing a water-insoluble and alkali-soluble resin, a development inhibitor and an infrared absorber and exhibiting enhanced solubility in an aqueous alkali solution through light exposure. The recording layer may have either a mono-layer construction or a multi-layer construction containing a lower layer and an upper layer. In the case of the multi-layer construction, a layer containing the water-insoluble and alkali-soluble resin is used as the lower layer, and a layer containing the water-insoluble and alkali-soluble resin and the development inhibitor and exhibiting enhanced solubility in an aqueous alkali solution through light exposure is used as the upper layer, and at least one of the lower layer and the upper layer contains the infrared absorber.

摘要翻译： 平版印刷版原版包括其上设置有含有不溶于水和碱溶性树脂的记录层，显影抑制剂和红外吸收剂并且通过曝光显示出增强的在碱性水溶液中的溶解度的载体。 记录层可以具有单层结构或包含下层和上层的多层结构。 在多层结构的情况下，使用含有水不溶性和碱溶性树脂的层作为下层，含有水不溶性和碱溶性树脂和显影抑制剂的层，表现出增强的溶解性 在通过曝光的碱性水溶液中使用上层，并且下层和上层中的至少一层含有红外线吸收剂。

公开(公告)号：US20060257782A1

公开(公告)日：2006-11-16

申请号：US11390378

申请日：2006-03-28

申请人： Kazuo Maemoto

发明人： Kazuo Maemoto

IPC分类号： G03C1/00

CPC分类号： B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/266 ,  G03F7/027 ,  G03F7/035

摘要： A photosensitive lithographic printing plate comprising: an aluminum support; a photopolymerizable photosensitive layer; and an oxygen blocking layer in this order, wherein the photopolymerizable photosensitive layer contains (1) a polyurethane binder, (2) a polymerizable compound having a urethane bond and two ethylenically unsaturated bonds, (3) a polymerizable compound having a urethane bond and four or more ethylenically unsaturated bonds, and (4) a photopolymerization initiator.

摘要翻译： 一种光敏平版印刷版，包括：铝支架; 光聚合感光层; 和氧阻挡层，其中光聚合性感光层含有（1）聚氨酯粘合剂，（2）具有氨基甲酸酯键和两个烯键式不饱和键的聚合性化合物，（3）具有氨基甲酸酯键的聚合性化合物和四 或更多的烯属不饱和键，和（4）光聚合引发剂。

公开(公告)号：US07118848B2

公开(公告)日：2006-10-10

申请号：US10112729

申请日：2002-04-02

申请人： Hisashi Hotta ,  Yoshinori Hotta ,  Kazuo Maemoto

发明人： Hisashi Hotta ,  Yoshinori Hotta ,  Kazuo Maemoto

IPC分类号： G03F7/00

CPC分类号： B41N3/036 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/04 ,  B41C2201/06 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24 ,  Y10T428/24355 ,  Y10T428/265

摘要： This invention provides a support for a lithographic printing plate, and an original form of a heat-sensitive lithographic printing plate, which comprises a hydrophilic film formed on a metallic base whose surface has been roughened, said hydrophilic film having a heat conductivity of 0.05–0.5 W/(m·K) in the direction of its film thickness, which when used as the development on machine type, exhibits good on-press, or good non-treatment developability, a high sensitivity, a long press life and a preferable stain resistance and ink removal property upon printing and which, when used as a conventional thermal positive or negative type, makes efficient utilization of heat for the formation of image, has a high sensitivity and exhibits a long press life and a good stain resistance in a nonimage area, wherein the non-treatment in which the development is not performed.

公开(公告)号：US5395733A

公开(公告)日：1995-03-07

申请号：US697971

申请日：1991-05-10

申请人： Kazuo Maemoto ,  Kouichi Kawamura

发明人： Kazuo Maemoto ,  Kouichi Kawamura

IPC分类号： G03F7/038 ,  C08F22/16 ,  G03F7/039 ,  G03C1/492

CPC分类号： G03F7/039 ,  Y10S430/111 ,  Y10S522/904 ,  Y10S522/905

摘要： An image forming layer comprising a polymer which has a component showing UV absorption at 320 nm or higher and a component containing the carboxylic acid (carboxylate) group represented by the following general formula I:--(Y).sub.1 --X--(CH.sub.2).sub.k --COOT (I)wherein X represents sulfur, oxygen, single bond, C.dbd.W or N--U where W represents oxygen or sulfur and U represents an optionally substituted aryl, alkyl group or hydrogen, Y represents an optionally substituted alkylene, arylene, aralkylene group or divalent heterocyclic ring, and T represents a hydrogen, alkali metal, alkaline earth metal or HN(R.sup.1)(R.sup.2)(R.sup.3) where R.sup.1, R.sup.2 and R.sup.3, which may be identical or different, independently represent a hydrogen atom, optionally substituted alkyl or aryl group and R.sup.1, R.sup.2 and R.sup.3 may join together to form a ring structure, k represents 0 or 1 and 1 is 0 or 1, provided that X represents C.dbd.W when k is 0. The image forming layer shows an extremely high sensitivity and excellent scratch resistance of the image areas upon development.

摘要翻译： 包含具有在320nm以上的UV吸收的成分的聚合物和含有下述通式I所示的羧酸（羧酸酯基）的成分的成像层： - （Y）1-X-（CH 2）k -COOT（I）其中X表示硫，氧，单键，C = W或NU，其中W表示氧或硫，U表示任选取代的芳基，烷基或氢，Y表示任选取代的亚烷基，亚芳基，亚芳基 或二价杂环，T表示氢，碱金属，碱土金属或HN（R1）（R2）（R3），其中R1，R2和R3可以相同或不同，独立地表示氢原子，任选取代 烷基或芳基，并且R 1，R 2和R 3可以连接在一起形成环结构，k表示0或1且1为0或1，条件是当k为0时X表示C = W。图像形成层显示出极高的 图像区域的高灵敏度和优异的耐刮擦性 发展。

公开(公告)号：US06596455B2

公开(公告)日：2003-07-22

申请号：US09837163

申请日：2001-04-19

申请人： Hiromitsu Yanaka ,  Kazuo Maemoto

发明人： Hiromitsu Yanaka ,  Kazuo Maemoto

IPC分类号： G03F7038

CPC分类号： B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/22 ,  B41C2210/24

摘要： A lithographic printing plate precursor having a heat-sensitive layer on a water-receptive substrate, wherein the heat-sensitive layer comprises microcapsules containing a compound having a thermally reactive functional group, and the heat-sensitive layer or a layer adjacent to the heat-sensitive layer contains a compound capable of acting as a co-reactant in thermal reaction of the compound having a thermally reactive functional group in a state contained in other microcapsules.

摘要翻译： 1.一种平版印刷版原版，其在受水基材上具有热敏层，其中，所述热敏层包含含有具有热反应性官能团的化合物的微胶囊，以及所述热敏层或与所述热敏层相邻的层， 敏感层含有能够在具有热反应性官能团的化合物在其它微胶囊中所含的状态的热反应中作为共反应物的化合物。

公开(公告)号：US06340554B1

公开(公告)日：2002-01-22

申请号：US09596051

申请日：2000-06-16

申请人： Koichi Kawamura ,  Kazuo Maemoto ,  Sumiaki Yamasaki ,  Tadahiro Sorori ,  Hiroshi Tashiro ,  Kiyotaka Fukino

发明人： Koichi Kawamura ,  Kazuo Maemoto ,  Sumiaki Yamasaki ,  Tadahiro Sorori ,  Hiroshi Tashiro ,  Kiyotaka Fukino

IPC分类号： G03F7004

CPC分类号： B41M5/368 ,  B41C1/1041

摘要： An object of the present invention is to provide excellent in terms of durability wherein development with water, or direct production of the plate from digital data through infrared laser recording in particular such that a special process is not necessary, is possible, by forming on a support a photosensitive layer containing a reaction product of a compound having in a molecule thereof a functional group X and a functional group Y and a compound represented by a formula (1) stated below, or alternatively, containing a polymerization product of a compound having the functional group X and a compound represented by the formula (1) stated below. Further by incorporating water-insoluble particles in this photosensitive layer, many voids are formed in the photosensitive layer, further improving sensitivity and discrimination. The functional group X is a group selected from among a sulfonic acid ester group, a disulfone group, a sulfonimide group, and an alkoxyalkyl ester group and the functional group Y is a group selected from among —OH, —NH2, —COOH, —NH—CO—R3, and —Si(OR4)3 [wherein R3 and R4 each represents an alkyl group or an aryl group]. (R1)n—X—(OR2)4−n  (1) (1) is (R1)n—X—(OR2)4−n wherein R1 and R2 each represents an alkyl group or an aryl group; X represents Si, Al, Ti, or Zr; and n represents an integer from 0 to 2.

摘要翻译： 本发明的目的在于提供优异的耐久性，其特征在于，利用水的显影，或通过红外激光记录从数字数据直接制造板，使得不需要特殊的处理，可以通过在 支持含有分子中具有官能团X和官能团Y的化合物和由下式（1）表示的化合物的反应产物的感光层，或者包含具有下式的化合物的聚合产物： 官能团X和下述式（1）表示的化合物。 此外，通过在该感光层中引入水不溶性颗粒，在感光层中形成许多空隙，进一步提高了敏感性和鉴别性。 官能团X是选自磺酸酯基，二砜基，磺酰亚胺基和烷氧基烷基酯基的基团，官能团Y是选自-OH，-NH 2，-COOH， - NH-CO-R3和-Si（OR4）3 [其中R3和R4各自表示烷基或芳基]（1）为（R1）nX-（OR2）4-n，其中R1和R2各自表示 烷基或芳基; X表示Si，Al，Ti或Zr; n表示0〜2的整数。