公开(公告)号：US20120148939A1

公开(公告)日：2012-06-14

申请号：US13288190

申请日：2011-11-03

申请人： Kazuya Yamamoto ,  Koji Yamada ,  Susumu Yamaguchi ,  Hirohisa Tanaka ,  Masaharu Asano ,  Tetsuya Yamaki ,  Hiroshi Koshikawa ,  Yasunari Maekawa ,  Warapon Sinananwanich

发明人： Kazuya Yamamoto ,  Koji Yamada ,  Susumu Yamaguchi ,  Hirohisa Tanaka ,  Masaharu Asano ,  Tetsuya Yamaki ,  Hiroshi Koshikawa ,  Yasunari Maekawa ,  Warapon Sinananwanich

IPC分类号： H01M8/10

CPC分类号： H01M8/1041 ,  H01M8/0289 ,  H01M8/103 ,  H01M8/1039

摘要： An anion exchange membrane includes a quaternary ammonium salt group in which two methyl groups, and one alkyl group having 3 to 8 carbon atoms are bonded to a nitrogen atom.

摘要翻译： 阴离子交换膜包括其中两个甲基和一个具有3-8个碳原子的烷基与氮原子键合的季铵盐基团。

公开(公告)号：US08283088B2

公开(公告)日：2012-10-09

申请号：US12311570

申请日：2007-09-05

申请人： Masaru Yoshida ,  Masaharu Asano ,  Jinhua Chen ,  Yasunari Maekawa ,  Toshimitsu Tachibana ,  Yozo Nagai ,  Soji Nishiyama

发明人： Masaru Yoshida ,  Masaharu Asano ,  Jinhua Chen ,  Yasunari Maekawa ,  Toshimitsu Tachibana ,  Yozo Nagai ,  Soji Nishiyama

IPC分类号： H01M8/10

CPC分类号： C08F255/00 ,  C08F8/00 ,  C08F8/12 ,  C08F8/36 ,  C08F259/08 ,  C08J5/2293 ,  C08J7/18 ,  C08J2323/06 ,  C08J2327/18 ,  H01B1/122 ,  H01M8/1027 ,  H01M8/1037 ,  H01M8/1039 ,  H01M8/1044 ,  H01M8/106 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02P70/56 ,  C08F230/08

摘要： An object is to provide an electrolyte membrane that maintains excellent cell characteristics for a long time under high temperature and low water retention, as this is the most important point in fuel cells.A process for producing a polymer electrolyte membrane for fuel cells is provided, which process comprises in sequence: forming graft molecular chains by graft-polymerization of a vinyl silane coupling agent on a polymer film substrate that has phenyl groups capable of holding sulfonic acid groups; introducing sulfonic acid groups into phenyl groups contained in the graft molecular chains; and hydrolyzing and condensing alkoxy groups contained in the graft molecular chains so that a silane crosslinked structure is introduced between the graft molecular chains. A polymer electrolyte membrane produced by the process is also provided.

摘要翻译： 目的是提供一种电解质膜，其在高温和低保水性下长时间保持优异的电池特性，因为这是燃料电池中最重要的一点。 本发明提供一种燃料电池用高分子电解质膜的制造方法，该方法依次包括：在具有能够保持磺酸基的苯基的聚合物膜基材上接枝聚合乙烯基硅烷偶联剂而形成接枝分子链; 将磺酸基团引入到接枝分子链中所含的苯基中; 并且使包含在接枝分子链中的烷氧基水解和缩合，使得在接枝分子链之间引入硅烷交联结构。 还提供了通过该方法制备的聚合物电解质膜。

公开(公告)号：US20100040927A1

公开(公告)日：2010-02-18

申请号：US12311570

申请日：2007-09-05

申请人： Masaru Yoshida ,  Masaharu Asano ,  Jinhua Chen ,  Yasunari Maekawa ,  Toshimitsu Tachibana ,  Yozo Nagai ,  Soji Nishiyama

发明人： Masaru Yoshida ,  Masaharu Asano ,  Jinhua Chen ,  Yasunari Maekawa ,  Toshimitsu Tachibana ,  Yozo Nagai ,  Soji Nishiyama

IPC分类号： H01M8/10 ,  C08J9/00

CPC分类号： C08F255/00 ,  C08F8/00 ,  C08F8/12 ,  C08F8/36 ,  C08F259/08 ,  C08J5/2293 ,  C08J7/18 ,  C08J2323/06 ,  C08J2327/18 ,  H01B1/122 ,  H01M8/1027 ,  H01M8/1037 ,  H01M8/1039 ,  H01M8/1044 ,  H01M8/106 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02P70/56 ,  C08F230/08

摘要： An object is to provide an electrolyte membrane that maintains excellent cell characteristics for a long time under high temperature and low water retention, as this is the most important point in fuel cells.A process for producing a polymer electrolyte membrane for fuel cells is provided, which process comprises in sequence: forming graft molecular chains by graft-polymerization of a vinyl silane coupling agent on a polymer film substrate that has phenyl groups capable of holding sulfonic acid groups; introducing sulfonic acid groups into phenyl groups contained in the graft molecular chains; and hydrolyzing and condensing alkoxy groups contained in the graft molecular chains so that a silane crosslinked structure is introduced between the graft molecular chains. A polymer electrolyte membrane produced by the process is also provided.

摘要翻译： 目的是提供一种电解质膜，其在高温和低保水性下长时间保持优异的电池特性，因为这是燃料电池中最重要的一点。 本发明提供一种燃料电池用高分子电解质膜的制造方法，该方法依次包括：在具有能够保持磺酸基的苯基的聚合物膜基材上接枝聚合乙烯基硅烷偶联剂而形成接枝分子链; 将磺酸基团引入到接枝分子链中所含的苯基中; 并且使包含在接枝分子链中的烷氧基水解和缩合，使得在接枝分子链之间引入硅烷交联结构。 还提供了通过该方法制备的聚合物电解质膜。

公开(公告)号：US08372558B2

公开(公告)日：2013-02-12

申请号：US12230103

申请日：2008-08-22

申请人： Jinhua Chen ,  Yasunari Maekawa ,  Masaharu Asano ,  Masaru Yoshida

发明人： Jinhua Chen ,  Yasunari Maekawa ,  Masaharu Asano ,  Masaru Yoshida

IPC分类号： H01M8/10

CPC分类号： H01M8/1025 ,  C08F8/12 ,  C08F2810/20 ,  C08J3/28 ,  C08J2351/08 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1067 ,  H01M8/1072 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02P70/56 ,  C08F285/00

摘要： A vinyl monomer is graft polymerized on an aromatic hydrocarbon-based polymer film substrate to introduce graft chains into the substrate and thereafter a functional monomer represented by the following formula and having sulfonic acid groups or functional groups capable of conversion to sulfonic acid groups is graft polymerized to introduce the sulfonic acid groups or the functional groups capable of conversion to sulfonic acid groups: where R is an aromatic ring or an aliphatic chain; X is (1) —OH, (2) —OLi, —ONa or —OK, (3) —F or —Cl, or (4) —OCnH2n+1 where n is an integer of 1 to 7. Since the graft chains obtained by graft polymerization of the vinyl monomer can also be utilized as scaffold polymers, the graft polymerizability of the functional monomer to the aromatic hydrocarbon-based polymer film substrate is sufficiently improved to enable the preparation of a polymer electrolyte membrane that excels not only in proton conductivity and mechanical strength but also in dimensional stability.

摘要翻译： 乙烯基单体在芳烃类聚合物膜基材上接枝聚合以将接枝链引入基材中，然后将由下式表示的具有磺酸基或能够转化为磺酸基的官能团的官能单体接枝聚合 引入磺酸基团或能够转化为磺酸基团的官能团：其中R是芳环或脂族链; X是（1）-OH，（2）-OLi，-ONa或-OK，（3）-F或-Cl或（4）-OCnH 2 + 1，其中n是1至7的整数。 通过乙烯基单体的接枝聚合获得的链也可以用作支架聚合物，功能性单体对芳族烃类聚合物膜基材的接枝聚合性得到充分改善，能够制备高分子电解质膜， 质子传导性和机械强度，而且尺寸稳定性。

公开(公告)号：US20100190875A1

公开(公告)日：2010-07-29

申请号：US12662160

申请日：2010-04-01

申请人： Jinhua Chen ,  Yasunari Maekawa ,  Masaharu Asano ,  Masaru Yoshida

发明人： Jinhua Chen ,  Yasunari Maekawa ,  Masaharu Asano ,  Masaru Yoshida

IPC分类号： B01J41/12

CPC分类号： H01M8/1018 ,  H01M8/0289 ,  H01M8/04197 ,  H01M8/1011 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1088 ,  Y02E60/523 ,  Y02P70/56

摘要： An aromatic polymer film substrate, or a grafted aromatic polymer film substrate having a monomer introduced therein as graft chains is irradiated with ionizing radiation to impart a crosslinked structure. The aromatic polymer film substrate or the grafted aromatic polymer film substrate, provided with the crosslinked structure, is directly sulfonated to obtain a crosslinked aromatic polymer electrolyte membrane. The crosslinked aromatic polymer electrolyte membrane has low water uptake, high proton conductivity, low methanol permeability, high chemical stability, and excellent mechanical characteristics.

摘要翻译： 将具有引入其中的单体作为接枝链的芳族聚合物膜基材或其接枝的芳族聚合物膜基材用电离辐射照射以赋予交联结构。 具有交联结构的芳香族聚合物膜基材或接枝芳香族聚合物膜基材直接磺化，得到交联的芳族聚合物电解质膜。 交联芳香族聚合物电解质膜吸水率低，质子传导率高，甲醇渗透性低，化学稳定性高，机械特性优良。

公开(公告)号：US20120321993A1

公开(公告)日：2012-12-20

申请号：US13580328

申请日：2011-11-16

申请人： Hideyuki Emori ,  Hirose Suzuki ,  Masaharu Asano ,  Yasunari Maekawa

发明人： Hideyuki Emori ,  Hirose Suzuki ,  Masaharu Asano ,  Yasunari Maekawa

IPC分类号： B29C39/00 ,  H01M8/10 ,  C25B9/00

CPC分类号： C08J5/2237 ,  C08F259/06 ,  C08J2327/16 ,  C08J2351/00 ,  H01B1/122 ,  H01M8/1023 ,  H01M8/1039 ,  Y02P70/56 ,  C08F212/04 ,  C08F220/06

摘要： The process for producing a proton conductive polymer electrolyte membrane of the present invention includes the steps of: irradiating resin fine particles with radiation; graft-polymerizing a vinyl monomer having a sulfonic acid group precursor and a vinyl monomer having a carbonyl group equivalent with the resin fine particles in a solid-liquid two-phase system to obtain a finely particulate graft polymer; preparing a casting solution of a polymer having a phosphoric acid group or a phosphonic acid group and the graft polymer, and forming a cast membrane from this solution; drying the cast membrane to obtain a film; converting the sulfonic acid group precursor into a sulfonic acid group; and forming a crosslinked structure between the carbonyl group equivalents. In the solid-liquid two-phase system, a liquid phase includes the vinyl monomers and a solvent for the monomers, and a solid phase includes the resin fine particles. By this process, a proton conductive polymer electrolyte membrane having high oxidation resistance, and a process capable of producing this membrane industrially are provided.

摘要翻译： 本发明的质子传导性聚合物电解质膜的制造方法包括以下步骤：用辐射照射树脂微粒; 将具有磺酸基前体的乙烯基单体和具有与树脂细颗粒的羰基当量的乙烯基单体接枝聚合在固 - 液两相体系中以获得细微的接枝聚合物; 制备具有磷酸基或膦酸基的聚合物和接枝聚合物的浇铸溶液，并从该溶液中形成流延膜; 干燥流延膜以获得膜; 将磺酸基前体转化成磺酸基团; 并在羰基当量之间形成交联结构。 在固液两相体系中，液相包括乙烯基单体和单体的溶剂，固相包括树脂微粒。 通过该方法，提供了具有高抗氧化性的质子传导性聚合物电解质膜以及能够在工业上制造该膜的方法。

公开(公告)号：US07993793B2

公开(公告)日：2011-08-09

申请号：US11727177

申请日：2007-03-23

申请人： Masaru Yoshida ,  Masaharu Asano ,  Jinhua Chen ,  Yasunari Maekawa ,  Toshimitsu Tachibana ,  Yozo Nagai ,  Soji Nishiyama

发明人： Masaru Yoshida ,  Masaharu Asano ,  Jinhua Chen ,  Yasunari Maekawa ,  Toshimitsu Tachibana ,  Yozo Nagai ,  Soji Nishiyama

IPC分类号： H01M8/10

CPC分类号： C08J7/18 ,  C08J5/2287 ,  C08J2327/18 ,  H01M8/106 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02P70/56

摘要： By performing photograft polymerization of functional monomers such that grafted chains will be introduced from the surface of a polymer base film into its interior without deteriorating its inherent characteristics and also by creating a multiplex crosslinked structure between the grafted chains and the base film under such conditions as to cause preferential radiation-induced crosslinking reaction, there is produced a polymer electrolyte membrane having high enough oxidation resistance and proton conductivity to be suitable for use in fuel cells.

摘要翻译： 通过进行功能性单体的光移植聚合，使得接枝链从聚合物基膜的表面引入其内部而不损害其固有特性，并且还可以在接枝链和基膜之间在如下条件下形成多重交联结构： 引起优先辐射诱导的交联反应，产生具有足够高的抗氧化性和质子传导性的聚合物电解质膜，以适用于燃料电池。

公开(公告)号：US20070224480A1

公开(公告)日：2007-09-27

申请号：US11727177

申请日：2007-03-23

申请人： Masaru Yoshida ,  Masaharu Asano ,  Jinhun Chen ,  Yasunari Maekawa ,  Toshimitsu Tachibana ,  Yozo Nagai ,  Soji Nishiyama

发明人： Masaru Yoshida ,  Masaharu Asano ,  Jinhun Chen ,  Yasunari Maekawa ,  Toshimitsu Tachibana ,  Yozo Nagai ,  Soji Nishiyama

IPC分类号： H01M8/10 ,  C08J5/22

CPC分类号： C08J7/18 ,  C08J5/2287 ,  C08J2327/18 ,  H01M8/106 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02P70/56

摘要： By performing photograft polymerization of functional monomers such that grafted chains will be introduced from the surface of a polymer base film into its interior without deteriorating its inherent characteristics and also by creating a multiplex crosslinked structure between the grafted chains and the base film under such conditions as to cause preferential radiation-induced crosslinking reaction, there is produced a polymer electrolyte membrane having high enough oxidation resistance and proton conductivity to be suitable for use in fuel cells.

摘要翻译： 通过进行功能性单体的光移植聚合，使得接枝链从聚合物基膜的表面引入其内部而不损害其固有特性，并且还可以在接枝链和基膜之间在如下条件下形成多重交联结构： 引起优先辐射诱导的交联反应，产生具有足够高的抗氧化性和质子传导性的聚合物电解质膜，以适用于燃料电池。

公开(公告)号：US20130115543A1

公开(公告)日：2013-05-09

申请号：US13468745

申请日：2012-05-10

申请人： Kazuaki Kudo ,  Toshio Takayama ,  June Park ,  Masaharu Asano ,  Yasunari Maekawa

发明人： Kazuaki Kudo ,  Toshio Takayama ,  June Park ,  Masaharu Asano ,  Yasunari Maekawa

IPC分类号： H01M8/10

CPC分类号： H01M8/10 ,  H01M8/103 ,  H01M8/1067 ,  H01M8/1072 ,  Y02P70/56

摘要： The present invention relates to a thermostable polymer electrolyte membrane which comprises a main chain comprising an alicyclic polybenzimidazole and a graft chain added to the main chain by radiation-induced graft polymerization, wherein at least a part of the graft chain has sulfonic acid groups. The thermostable polymer electrolyte membrane of the invention is used for many apparatuses such as polymer electrolyte fuel cells or water electrolysis devices, in which the electrolyte membrane exhibits high proton conductivity, low fuel permeability, high oxidation resistance and superior mechanical property under operation conditions at high temperature. The present invention also provides a simple and low-cost process for producing the same.

摘要翻译： 本发明涉及一种耐热聚合物电解质膜，其包括通过辐射诱导的接枝聚合添加到主链中的脂环族聚苯并咪唑和接枝链的主链，其中至少一部分接枝链具有磺酸基。 本发明的耐热聚合物电解质膜用于诸如聚合物电解质燃料电池或水电解装置的许多装置，其中电解质膜在高的操作条件下表现出高质子传导性，低燃料渗透性，高抗氧化性和优异的机械性能 温度。 本发明还提供了一种简单且低成本的制造方法。

公开(公告)号：US20080312350A1

公开(公告)日：2008-12-18

申请号：US12068036

申请日：2008-01-31

申请人： Jinhua Chen ,  Yasunari Maekawa ,  Masaharu Asano ,  Masaru Yoshida

发明人： Jinhua Chen ,  Yasunari Maekawa ,  Masaharu Asano ,  Masaru Yoshida

IPC分类号： C08J5/22

CPC分类号： H01M8/1018 ,  H01M8/0289 ,  H01M8/04197 ,  H01M8/1011 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1088 ,  Y02E60/523 ,  Y02P70/56

摘要： An aromatic polymer film substrate, or a grafted aromatic polymer film substrate having a monomer introduced therein as graft chains is irradiated with ionizing radiation to impart a crosslinked structure. The aromatic polymer film substrate or the grafted aromatic polymer film substrate, provided with the crosslinked structure, is directly sulfonated to obtain a crosslinked aromatic polymer electrolyte membrane. The crosslinked aromatic polymer electrolyte membrane has low water uptake, high proton conductivity, low methanol permeability, high chemical stability, and excellent mechanical characteristics. A method for producing the crosslinked aromatic polymer electrolyte membrane is also provided.

摘要翻译： 将具有引入其中的单体作为接枝链的芳族聚合物膜基材或其接枝的芳族聚合物膜基材用电离辐射照射以赋予交联结构。 具有交联结构的芳香族聚合物膜基材或接枝芳香族聚合物膜基材直接磺化，得到交联的芳族聚合物电解质膜。 交联芳香族聚合物电解质膜吸水率低，质子传导率高，甲醇渗透性低，化学稳定性高，机械特性优良。 还提供了制备交联芳族聚合物电解质膜的方法。