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公开(公告)号：US06946553B2
公开(公告)日：2005-09-20
申请号：US10367701
申请日：2003-02-19
IPC分类号： B01J29/035 , B01J29/90 , B01J38/66 , C07D201/04
CPC分类号： B01J29/90 , B01J29/035 , B01J38/66
摘要： Improved processes for producing an ε-caprolactam using a solid catalyst and for producing a catalyst which can be used in the production of ε-caprolactam are provided. In the present invention, a solid catalyst such as a zeolite is treated with an aqueous solution containing an ammonia and at least one compound selected from the group consisting of quaternary ammonium compounds and lower alkylamines. In accordance with the present invention, a zeolite having a high catalyst activity and a long lifetime is produced, and a solid catalyst which has been used in the production of ε-caprolactam can be re-activated. In the present invention, by using the thus obtained zeolite and/or the thus activated solid catalyst, an ε-caprolactam is produced in a high yield over the long period of time.
摘要翻译： 提供了使用固体催化剂生产ε-己内酰胺和用于生产可用于生产ε-己内酰胺的催化剂的改进方法。 在本发明中，使用含有氨和至少一种选自季铵化合物和低级烷基胺的化合物的水溶液处理沸石等固体催化剂。 根据本发明，产生具有高催化剂活性和长寿命的沸石，并且可以重新活化用于生产ε-己内酰胺的固体催化剂。 在本发明中，通过使用由此获得的沸石和/或由此活化的固体催化剂，可以长时间以高产率生产ε-己内酰胺。
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2.发明授权Process for producing pentacyl-type crystalline zeolites and a process for producing &egr;-caprolactam using the same 有权制备戊酰基型结晶沸石的方法和使用该方法制备ε-己内酰胺的方法公开(公告)号：US06303099B1
公开(公告)日：2001-10-16
申请号：US09605473
申请日：2000-06-28
申请人： Hiroshi Ichihashi , Keisuke Sugita , Makoto Yako
发明人： Hiroshi Ichihashi , Keisuke Sugita , Makoto Yako
IPC分类号： C01B3936
CPC分类号： C01B39/40 , B01J29/40 , C07D201/04 , Y02P20/52 , Y10S423/22 , Y10S423/29 , Y10S423/34
摘要： A process for producing a pentacyl-type crystalline zeolite is provided which comprises the steps of (i) preparing a mixture of a silicon compound, water and tetrapropyl ammonium hydroxide, (ii) conducting a hydrothermal reaction of the mixture to obtain a reaction mixture containing zeolite crystals, (iii) separating zeolite crystals from the reaction mixture to collect a remaining solution, (iv) calcinating the resulting zeolite crystals, (v) treating the calcinated zeolite crystals with a solution such as ammonia water and (vi) recycling the solution collected in step (iii) to step (i), wherein in the mixture prepared in step (i) a molar ratio of hydroxide ion to silicon is from about 0.1 to about 0.4 and a molar ratio of potassium to silicon is about 0.1 or less. With this process, a zeolite catalyst having good performance can be produced with good reproducibility.
摘要翻译： 提供了一种制备五酰基型结晶沸石的方法，其包括以下步骤：（i）制备硅化合物，水和四丙基氢氧化铵的混合物，（ii）进行混合物的水热反应，得到含有 沸石晶体，（iii）从反应混合物中分离沸石晶体以收集剩余溶液，（iv）煅烧所得沸石晶体，（v）用溶液如氨水处理煅烧的沸石晶体，和（vi）回收溶液 在步骤（iii）至步骤（i）中收集，其中在步骤（i）中制备的混合物中，氢氧根离子与硅的摩尔比为约0.1至约0.4，并且钾与硅的摩尔比为约0.1或更小 。 通过该方法，可以以良好的再现性制造具有良好性能的沸石催化剂。
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公开(公告)号：US06531595B2
公开(公告)日：2003-03-11
申请号：US09963603
申请日：2001-09-27
IPC分类号： C07D20104
CPC分类号： C07D201/04
摘要： A method is provided for producing &egr;-caprolactam from cyclohexanone oxime by using a zeolite or non-zeolitic material as a catalyst under gas phase reaction conditions. The method comprises a reaction step converting cyclohexanone oxime into &egr;-caprolactam in the presence of the zeolite or non-zeolitic material; and a regeneration step of treating the zeolite or non-zeolitic material with a non-oxidizing gas at a temperature of from about 100°C. to about 600° C.
摘要翻译： 提供了一种通过在气相反应条件下使用沸石或非沸石材料作为催化剂从环己酮肟生产ε-己内酰胺的方法。 该方法包括在沸石或非沸石材料存在下将环己酮肟转化成ε-己内酰胺的反应步骤; 以及在约100℃的温度下用非氧化性气体处理沸石或非沸石材料的再生步骤。 至约600℃
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公开(公告)号：US4575572A
公开(公告)日：1986-03-11
申请号：US753861
申请日：1985-07-11
IPC分类号： B01J27/053 , B01J27/055 , C07C5/11
CPC分类号： B01J27/055 , B01J27/053 , C07C5/11 , C07C2523/50 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/89 , C07C2527/053
摘要： A method for producing cycloolefins useful as an intermediate material for lysine, caprolactam, adipic acid, medicines, agricultural chemicals, dyes and the like, which comprises partial hydrogenation of aromatic hydrocarbons with hydrogen gas in the presence of a catalyst composed of barium sulfate which is a carrier as well as ruthenium and at least one metal selected from the group consisting of iron, cobalt, silver and copper supported on said barium sulfate, and water.
摘要翻译： 一种制备用作赖氨酸，己内酰胺，己二酸，药物，农药，染料等的中间体的环烯烃的方法，其包括在由硫酸钡组成的催化剂存在下用氢气部分氢化芳烃 载体以及钌和至少一种选自负载在所述硫酸钡上的铁，钴，银和铜组成的组中的金属和水。
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公开(公告)号：US3970702A
公开(公告)日：1976-07-20
申请号：US529100
申请日：1974-12-03
申请人： Tatsuo Shiraishi , Susumu Kishiwada , Shinkichi Shimizu , Shigern Honmaru , Hiroshi Ichihashi , Yoshihiko Nagaoka
发明人： Tatsuo Shiraishi , Susumu Kishiwada , Shinkichi Shimizu , Shigern Honmaru , Hiroshi Ichihashi , Yoshihiko Nagaoka
CPC分类号： C07C45/35
摘要： A catalytic process for the preparation of acrolein by the vapor phase oxidation of propylene which comprises contacting propylene and oxygen with a catalyst composition comprising a catalyst system of the formula:Mo.sub.a Bi.sub.b Fe.sub.c X.sub.d Ni.sub.e Tl.sub.f P.sub.g O.sub.hwherein X is one or more of Mg, Mn and Co and a, b, c, d, e, f, g and h represent, respectively, the number of atoms wherein a is 12, b is 0.1 to 5, c is 0.1 to 5, d is 0 to 12, e is 0.1 to 12, f is 1 or less but not 0, g is 0 to 5 and h depends on the number of the other atoms and is usually from 36 to 89. Acrolein is produced with the use of said catalyst in a high selectivity and an excellent yield per each pass even at a large space velocity.
摘要翻译： 用于通过丙烯气相氧化制备丙烯醛的催化方法，其包括使丙烯和氧与催化剂组合物接触，所述催化剂组合物包含下式的催化剂体系：
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6.发明授权Process for producing epsilon-caprolactam and activating solid catalysts therefor 失效生产EPSILON-CAPROLACTAM和活化其固体催化剂的方法
公开(公告)号：US5212302A
公开(公告)日：1993-05-18
申请号：US811627
申请日：1991-12-23
IPC分类号： B01J29/035 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/90 , B01J38/12 , B01J38/66 , C07D201/04
CPC分类号： B01J29/90 , B01J29/035 , B01J29/86 , B01J29/87 , B01J29/88 , B01J38/12 , B01J38/66 , C07D201/04 , Y02P20/52 , Y02P20/584
摘要： In the production of .epsilon.-caprolactam from cyclohexanon oxime in gaseous phase in the presence of solid catalysts, the catalysts, no matter whether they may have worked, are brought into contact with either aqueous solution of ammonium salts and at least one basic material or ammonia water.
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公开(公告)号：US4003978A
公开(公告)日：1977-01-18
申请号：US515888
申请日：1974-10-18
摘要： A method for treating ammonia-containing gases for removing ammonia therefrom, which comprises contacting the ammonia-containing gases with a metal oxide catalyst having the following formula:Cr.sub.x A.sub.y O.sub.zwherein Cr is chromium; A is at least one element selected from the group consisting of tin, antimony, vanadium, cobalt, silver, zinc, nickel, titanium, molybdenum, tungsten, sulfur, phosphorus, boron, germanium and zirconium; x is a numeral of 4 to 12; y is a numeral of 0.2 to 8 and z is a numeral of 6.2 to 42, in a vapor phase at a temperature of from 200.degree. to 500.degree. C in the presence of molecular oxygen, and thereby the ammonia is oxidized to harmless nitrogen gas.
摘要翻译： 一种用于处理含氨气体以从其中除去氨的方法，其包括使含氨气体与具有下式的金属氧化物催化剂接触：
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8.发明授权Process for producing .epsilon.-caprolactam and activating solid catalysts therefor 失效制备ε-己内酰胺和活化固体催化剂的方法
公开(公告)号：US5403801A
公开(公告)日：1995-04-04
申请号：US10791
申请日：1993-01-29
IPC分类号： B01J29/035 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/90 , B01J38/12 , B01J38/66 , C07D201/04 , B01J37/00 , B01J29/28
CPC分类号： B01J29/90 , B01J29/035 , B01J29/86 , B01J29/87 , B01J29/88 , B01J38/12 , B01J38/66 , C07D201/04 , Y02P20/52 , Y02P20/584
摘要： In the production of .epsilon.-caprolactam from cyclohexanon oxime in gaseous phase in the presence of solid catalysts, the catalysts, no matter whether they may have worked, are brought into contact with either aqueous solution of ammonium salts and at least one basic material or ammonia water.
摘要翻译： 在固体催化剂存在下，在气相中从环己酮肟制备ε-己内酰胺时，催化剂无论是否可能已经起作用，都与铵盐水溶液和至少一种碱性物质或氨 水。
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公开(公告)号：US5071802A
公开(公告)日：1991-12-10
申请号：US489952
申请日：1990-03-07
申请人： Shinkichi Shimizu , Takayasu Niwa , Nobuyuki Abe , Masanori Doba , Akira Iguchi , Hiroshi Ichihashi , Masaru Kitamura
发明人： Shinkichi Shimizu , Takayasu Niwa , Nobuyuki Abe , Masanori Doba , Akira Iguchi , Hiroshi Ichihashi , Masaru Kitamura
IPC分类号： B01J23/90 , B01J29/90 , B01J38/52 , C07D201/04 , C07D213/10
CPC分类号： C07D213/10 , B01J23/90 , B01J29/90 , B01J38/52 , C07D201/04 , Y02P20/584
摘要： Carbonaceous materials deposited on solid catalysts and produced, for example, in Beckmann rearrangement in a gaseous phase are burned off by effecting the treatment in the presence of alcohols such as methanol or ethanol together with molecular oxygen-containing gas in order to regenerate the catalyst activity.
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公开(公告)号：US4565801A
公开(公告)日：1986-01-21
申请号：US371223
申请日：1982-04-23
IPC分类号： C07C57/05 , B01J27/00 , B01J27/19 , B01J27/199 , C01B25/16 , C01B25/24 , C07C51/00 , C07C51/25 , C07C67/00 , B01J27/14
CPC分类号： C07C51/252 , B01J23/002 , B01J27/19 , B01J27/199 , C01B25/16 , B01J2523/00
摘要： A heteropoly-acid of the formula:H.sub.3+x (PMo.sub.12-x V.sub.x O.sub.40).nH.sub.2 Owherein x and n are numbers satisfying respectively the equations: 0.ltoreq.x.ltoreq.3 and n.ltoreq.6, and comprising phosphorus as the central atom and molybdenum or molybdenum and vanadium as the coordinating atoms, or its reduction-form product, which is in a cubic crystal structure having diffraction lines at lattice spacings (d) of at least 8.4, 6.8, 5.9, 4.8, 4.2 and 3.4 in the X-ray powder diffraction. The heteropoly-acid is useful as a catalyst, especially as a catalyst in the production of methacrylic acid by the gas-phase catalytic oxidation of methacrolein.
摘要翻译： 具有下式的杂多酸：H3 + x（PMo12-xVxO40）·nH2O其中x和n分别满足等式：0≤x≤3和n≤6，并且包含磷作为 中心原子和钼或钼和钒作为配位原子，或其还原形式的产物，其在晶格间距（d）处具有至少8.4,6.8,5.9,4.8,4.2和3.4的衍射线的立方晶体结构 在X射线粉末衍射中。 杂多酸可用作催化剂，特别是通过甲基丙烯醛的气相催化氧化生产甲基丙烯酸时的催化剂。
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