公开(公告)号：US20120056166A1

公开(公告)日：2012-03-08

申请号：US13138976

申请日：2010-05-11

申请人： Ken-ichi Nakayama ,  Junji Kido ,  Yong-Jin Pu ,  Yohei Hashimoto ,  Naomi Oguma ,  Naoki Hirata

发明人： Ken-ichi Nakayama ,  Junji Kido ,  Yong-Jin Pu ,  Yohei Hashimoto ,  Naomi Oguma ,  Naoki Hirata

IPC分类号： H01L51/54 ,  C07D409/14

CPC分类号： C07D209/48 ,  C07D409/14 ,  C07D495/04 ,  C07D495/14 ,  H01L51/0053 ,  H01L51/0068 ,  H01L51/0074

摘要： An organic semiconductor material is represented by the following formula (F):wherein A represents a cyclic conjugated skeleton structure formed of one or more aromatic rings, and R1 and R2 each independently represent a substituted or unsubstituted alkyl group. The organic semiconductor material has high electron mobility and high on/off ratio, and can form an organic semiconductor thin film by a solution process making use of its solution.

摘要翻译： 有机半导体材料由下式（F）表示：其中A表示由一个或多个芳环形成的环状共轭骨架结构，R 1和R 2各自独立地表示取代或未取代的烷基。 有机半导体材料具有高电子迁移率和高开/关比，并且可以通过使用其溶液的溶液法形成有机半导体薄膜。

公开(公告)号：US08895963B2

公开(公告)日：2014-11-25

申请号：US13138976

申请日：2010-05-11

申请人： Ken-ichi Nakayama ,  Junji Kido ,  Yong-Jin Pu ,  Yohei Hashimoto ,  Naomi Oguma ,  Naoki Hirata

发明人： Ken-ichi Nakayama ,  Junji Kido ,  Yong-Jin Pu ,  Yohei Hashimoto ,  Naomi Oguma ,  Naoki Hirata

IPC分类号： H01L51/54 ,  C07D409/14 ,  H01L51/00 ,  C07D495/04 ,  C07D495/14 ,  C07D209/48

CPC分类号： C07D209/48 ,  C07D409/14 ,  C07D495/04 ,  C07D495/14 ,  H01L51/0053 ,  H01L51/0068 ,  H01L51/0074

摘要： An organic semiconductor material is represented by the following formula (F):wherein A represents a cyclic conjugated skeleton structure formed of one or more aromatic rings, and R1 and R2 each independently represent a substituted or unsubstituted alkyl group. The organic semiconductor material has high electron mobility and high on/off ratio, and can form an organic semiconductor thin film by a solution process making use of its solution.

摘要翻译： 有机半导体材料由下式（F）表示：其中A表示由一个或多个芳环形成的环状共轭骨架结构，R 1和R 2各自独立地表示取代或未取代的烷基。 有机半导体材料具有高电子迁移率和高开/关比，并且可以通过使用其溶液的溶液法形成有机半导体薄膜。

公开(公告)号：US08927972B2

公开(公告)日：2015-01-06

申请号：US13392409

申请日：2010-09-03

申请人： Ken-ichi Nakayama ,  Junji Kido ,  Yong-Jin Pu ,  Fumito Suzuki ,  Naomi Oguma ,  Naoki Hirata

发明人： Ken-ichi Nakayama ,  Junji Kido ,  Yong-Jin Pu ,  Fumito Suzuki ,  Naomi Oguma ,  Naoki Hirata

IPC分类号： H01L29/08 ,  H01L51/00 ,  H01L51/52 ,  B82Y10/00 ,  H01L51/05

CPC分类号： H01L51/5296 ,  B82Y10/00 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0067 ,  H01L51/0081 ,  H01L51/0504

摘要： A current-amplifying transistor device is provided, between an emitter electrode and a collector electrode, with two organic semiconductor layers and a sheet-shaped base electrode. One of the organic semiconductor layers is arranged between the emitter electrode and the base collector electrode, and has a diode structure of a p-type organic semiconductor layer and an n-type p-type organic semiconductor layer. A current-amplifying, light-emitting transistor device including the current-amplifying transistor device and an organic EL device portion formed in the current-amplifying transistor device is also disclosed.

摘要翻译： 在发射电极和集电极之间设置有两个有机半导体层和片状基极的电流放大晶体管器件。 有机半导体层之一配置在发射电极和集电极之间，具有p型有机半导体层和n型p型有机半导体层的二极管结构。 还公开了一种电流放大型发光晶体管器件，其包括形成在电流放大晶体管器件中的电流放大晶体管器件和有机EL器件部分。

公开(公告)号：US20120146011A1

公开(公告)日：2012-06-14

申请号：US13392409

申请日：2010-09-03

申请人： Ken-ichi Nakayama ,  Junji Kido ,  Yong-Jin Pu ,  Fumito Suzuki ,  Naomi Oguma ,  Naoki Hirata

发明人： Ken-ichi Nakayama ,  Junji Kido ,  Yong-Jin Pu ,  Fumito Suzuki ,  Naomi Oguma ,  Naoki Hirata

IPC分类号： H01L51/30

CPC分类号： H01L51/5296 ,  B82Y10/00 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0067 ,  H01L51/0081 ,  H01L51/0504

摘要： A current-amplifying transistor device is provided, between an emitter electrode and a collector electrode, with two organic semiconductor layers and a sheet-shaped base electrode. One of the organic semiconductor layers is arranged between the emitter electrode and the base collector electrode, and has a diode structure of a p-type organic semiconductor layer and an n-type p-type organic semiconductor layer. A current-amplifying, light-emitting transistor device including the current-amplifying transistor device and an organic EL device portion formed in the current-amplifying transistor device is also disclosed.

摘要翻译： 在发射电极和集电极之间设置有两个有机半导体层和片状基极的电流放大晶体管器件。 有机半导体层之一配置在发射电极和集电极之间，具有p型有机半导体层和n型p型有机半导体层的二极管结构。 还公开了一种电流放大型发光晶体管器件，其包括形成在电流放大晶体管器件中的电流放大晶体管器件和有机EL器件部分。

公开(公告)号：US09608217B2

公开(公告)日：2017-03-28

申请号：US14396023

申请日：2012-04-27

申请人： Ken-ichi Nakayama ,  Junji Kido ,  Ryotaro Akiba ,  Naomi Oguma ,  Naoki Hirata

发明人： Ken-ichi Nakayama ,  Junji Kido ,  Ryotaro Akiba ,  Naomi Oguma ,  Naoki Hirata

IPC分类号： H01L51/00 ,  H01L51/05 ,  H01L51/10

CPC分类号： H01L51/0504 ,  H01L51/0036 ,  H01L51/105 ,  H01L2251/301 ,  H01L2251/308

摘要： The present invention provides a transistor element having a laminated structure, the laminated structure comprising a sheet-like base electrode being arranged between an emitter electrode and a collector electrode; at least one p-type organic semiconductor layer being provided on each of the surface and the back sides of the base electrode; and a current transmission promotion layer being formed, on each of the surface and back sides of the base electrode, between the base electrode and the p-type organic semiconductor layer or layers provided on each of the surface and back sides of the base electrode. According to the present invention, it becomes possible to provide a transistor element (MBOT) that is, in particular, stably supplied through a simple production process, has a structure capable of being mass-produced, and has a large current modulation effect and an excellent ON/OFF ratio at a low voltage in the emitter electrode and the collector electrode.

公开(公告)号：US20130153884A1

公开(公告)日：2013-06-20

申请号：US13819636

申请日：2011-08-17

申请人： Musubu Ichikawa ,  Hyeon-Gu Jeon ,  Naomi Oguma ,  Naoki Hirata ,  Hisao Kono

发明人： Musubu Ichikawa ,  Hyeon-Gu Jeon ,  Naomi Oguma ,  Naoki Hirata ,  Hisao Kono

IPC分类号： C09K19/34 ,  H01L51/00

CPC分类号： C09K19/3483 ,  C07D471/04 ,  C09B5/62 ,  C09K19/3488 ,  H01L51/0053 ,  H01L51/0076 ,  H01L51/0558 ,  H01L51/0562 ,  Y10T428/2982

摘要： Provided are a fine-particulate organic semiconductor material, a thin organic semiconductor film and an organic transistor. The fine-particulate organic semiconductor material is in a form of fine particles and is usable as an organic semiconductor material. The fine particles are fine thermotropic liquid crystal particles that undergo a phase transition into a liquid crystal state when heated to a temperature of from 50° C. to 350° C. The fine-particulate organic semiconductor material can easily and uniformly form the thin organic semiconductor film over a large area by a film printing process or a dispersion coating process. The thin organic semiconductor film has high electron mobility and high ON/OFF value.

摘要翻译： 提供了一种细颗粒状有机半导体材料，有机半导体薄膜和有机晶体管。 细颗粒状有机半导体材料为微粒状，可用作有机半导体材料。 细颗粒是当加热到50℃至350℃的温度时，经历相变为液晶状态的细微的热致液晶颗粒。微粒有机半导体材料可以容易且均匀地形成薄的有机 通过膜印刷方法或分散涂布方法在大面积上形成半导体膜。 薄的有机半导体膜具有高的电子迁移率和高的ON / OFF值。

公开(公告)号：US09133193B2

公开(公告)日：2015-09-15

申请号：US13502262

申请日：2010-10-29

申请人： Musubu Ichikawa ,  Naoki Hirata ,  Hisao Kono ,  Naomi Oguma

发明人： Musubu Ichikawa ,  Naoki Hirata ,  Hisao Kono ,  Naomi Oguma

IPC分类号： H01L51/30 ,  C07D471/06 ,  H01L51/00 ,  H01L51/05

CPC分类号： C07D471/06 ,  C09B5/62 ,  H01L51/0053 ,  H01L51/0545

摘要： Provided are an organic semiconductor material, organic semiconductor thin film and organic thin-film transistor, which contain a perylene tetracarboxylic diimide derivative represented by the following formula (1): In the formula (1), R1 means a linear or branched alkyl group having from 1 to 20 carbon atoms, R2 means a linear or branched alkyl group having from 2 to 6 carbon atoms, R3 means a linear or branched alkyl group having from 2 to 6 carbon atoms, X1 and X2 each mean a heteroatom selected from an oxygen atom, sulfur atom or selenium atom, Y means a halogen atom or cyano group, m stands for a number of from 0 to 4, and n stands for a number of from 0 to 2. Further, the alkyl groups represented by R1 and R2 may each be substituted with one or more fluorine atoms.

摘要翻译： 提供一种有机半导体材料，有机半导体薄膜和有机薄膜晶体管，其含有下式（1）表示的苝四羧酸二酰亚胺衍生物：式（1）中，R 1表示具有 1至20个碳原子，R 2表示具有2至6个碳原子的直链或支链烷基，R 3表示具有2至6个碳原子的直链或支链烷基，X 1和X 2均表示选自氧的杂原子 原子，硫原子或硒原子，Y表示卤素原子或氰基，m表示0〜4的数，n表示0〜2的数。此外，由R1和R2表示的烷基 可各自被一个或多个氟原子取代。

公开(公告)号：US09518224B2

公开(公告)日：2016-12-13

申请号：US13819636

申请日：2011-08-17

申请人： Musubu Ichikawa ,  Hyeon-Gu Jeon ,  Naomi Oguma ,  Naoki Hirata ,  Hisao Kono

发明人： Musubu Ichikawa ,  Hyeon-Gu Jeon ,  Naomi Oguma ,  Naoki Hirata ,  Hisao Kono

IPC分类号： H01L51/00 ,  C09K19/34 ,  C07D471/04 ,  C09B5/62 ,  H01L51/05

CPC分类号： C09K19/3483 ,  C07D471/04 ,  C09B5/62 ,  C09K19/3488 ,  H01L51/0053 ,  H01L51/0076 ,  H01L51/0558 ,  H01L51/0562 ,  Y10T428/2982

摘要： Provided are a fine-particulate organic semiconductor material, a thin organic semiconductor film and an organic transistor. The fine-particulate organic semiconductor material is in a form of fine particles and is usable as an organic semiconductor material. The fine particles are fine thermotropic liquid crystal particles that undergo a phase transition into a liquid crystal state when heated to a temperature of from 50° C. to 350° C. The fine-particulate organic semiconductor material can easily and uniformly form the thin organic semiconductor film over a large area by a film printing process or a dispersion coating process. The thin organic semiconductor film has high electron mobility and high ON/OFF value.

摘要翻译： 提供了一种细颗粒状有机半导体材料，有机半导体薄膜和有机晶体管。 细颗粒状有机半导体材料为微粒状，可用作有机半导体材料。 细颗粒是当加热至50℃至350℃的温度时，经历相变为液晶状态的细微的热致液晶颗粒。微粒有机半导体材料可以容易且均匀地形成薄的有机 通过膜印刷方法或分散涂布方法在大面积上形成半导体膜。 薄的有机半导体膜具有高的电子迁移率和高的ON / OFF值。

公开(公告)号：US20120199824A1

公开(公告)日：2012-08-09

申请号：US13502262

申请日：2010-10-29

申请人： Musubu Ichikawa ,  Naoki Hirata ,  Hisao Kono ,  Naomi Oguma

发明人： Musubu Ichikawa ,  Naoki Hirata ,  Hisao Kono ,  Naomi Oguma

IPC分类号： H01L51/30 ,  C07D471/06

CPC分类号： C07D471/06 ,  C09B5/62 ,  H01L51/0053 ,  H01L51/0545

摘要： Provided are an organic semiconductor material, organic semiconductor thin film and organic thin-film transistor, which contain a perylene tetracarboxylic diimide derivative represented by the following formula (1): In the formula (1), R1 means a linear or branched alkyl group having from 1 to 20 carbon atoms, R2 means a linear or branched alkyl group having from 2 to 6 carbon atoms, R3 means a linear or branched alkyl group having from 2 to 6 carbon atoms, X1 and X2 each mean a heteroatom selected from an oxygen atom, sulfur atom or selenium atom, Y means a halogen atom or cyano group, m stands for a number of from 0 to 4, and n stands for a number of from 0 to 2. Further, the alkyl groups represented by R1 and R2 may each be substituted with one or more fluorine atoms.

摘要翻译： 提供一种有机半导体材料，有机半导体薄膜和有机薄膜晶体管，其含有下式（1）表示的苝四羧酸二酰亚胺衍生物：式（1）中，R 1表示具有 1至20个碳原子，R 2表示具有2至6个碳原子的直链或支链烷基，R 3表示具有2至6个碳原子的直链或支链烷基，X 1和X 2均表示选自氧的杂原子 原子，硫原子或硒原子，Y表示卤素原子或氰基，m表示0〜4的数，n表示0〜2的数。此外，由R1和R2表示的烷基 可各自被一个或多个氟原子取代。

公开(公告)号：US06797436B2

公开(公告)日：2004-09-28

申请号：US09988139

申请日：2001-11-19

申请人： Minoru Takizawa ,  Yoshifumi Sugito ,  Naomi Oguma ,  Seiji Doi ,  Sachio Yoshikawa ,  Michiei Nakamura

发明人： Minoru Takizawa ,  Yoshifumi Sugito ,  Naomi Oguma ,  Seiji Doi ,  Sachio Yoshikawa ,  Michiei Nakamura

IPC分类号： H01M1040

CPC分类号： H01M10/0565 ,  C08F8/00 ,  H01M2/1653 ,  H01M2/1666 ,  H01M6/22 ,  H01M10/052 ,  H01M2300/0014 ,  H01M2300/0025 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y10T442/2139 ,  Y10T442/2861 ,  Y10T442/2918 ,  C08F297/00

摘要： A solidifying material for a cell electrolyte solution is a block copolymer, which comprises, as segments A, a polymer non-compatible with the cell electrolyte solution and, as segments B, a polymer compatible with the cell electrolyte solution. The solidifying material absorbs and solidifies the cell electrolyte solution. A smallest unit of the block copolymer is A-B-A. To each of the segments B, at least one group selected from the group consisting of a carboxyl group, an ester group, a hydroxyl group, a sulfonic group, an amino group, a cyclic carbonate group and a polyoxyalkylene group is bonded via a —S— bond or a —C— bond.

摘要翻译： 用于电池电解质溶液的固化材料是嵌段共聚物，其包含作为区段A的与电池电解质溶液不相容的聚合物，并且作为区段B包含与电池电解质溶液相容的聚合物。 凝固材料吸收并固化细胞电解质溶液。 嵌段共聚物的最小单元是A-B-A。 对于各段B，通过α-烯烃键合至少一个选自羧基，酯基，羟基，磺酸基，氨基，环状碳酸酯基和聚氧化烯基的基团， S-键或-C-键。