公开(公告)号：US06239303B1

公开(公告)日：2001-05-29

申请号：US09688387

申请日：2000-10-17

申请人： Kenji Funatsu ,  Tohru Kubota ,  Mikio Endo

发明人： Kenji Funatsu ,  Tohru Kubota ,  Mikio Endo

IPC分类号： C07F708

CPC分类号： C07F7/188

摘要： A hydroxyl group-containing compound is silylated by reacting it with an organohydrosilane compound in the presence of a ruthenium complex catalyst having carbonyl groups as ligands. Silylation takes place in a short time while the amount of the catalyst is minimized.

摘要翻译： 在含有羰基作为配体的钌络合物催化剂的存在下，使含羟基化合物与有机氢硅烷化合物反应进行甲硅烷基化。 在短时间内发生硅烷化，同时使催化剂的量最小化。

公开(公告)号：US06426427B1

公开(公告)日：2002-07-30

申请号：US09935659

申请日：2001-08-24

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

IPC分类号： C07F708

CPC分类号： C07F7/14

摘要： A bissilylnorbornane compound is prepared by reacting 2,5-norbornadiene with a hydrogenchlorosilane in the presence of a mixture of a palladium compound and a phosphite or a palladium complex having a phosphate ligand as a catalyst. The bissilylnorbornane compound can be produced in high yields while suppressing formation of by-product nortricyclene.

摘要翻译： 通过在钯化合物和亚磷酸盐或具有磷酸盐配体作为催化剂的钯络合物的混合物存在下使2,5-降冰片二烯与氢氯硅烷反应来制备二苯基降冰片烷化合物。 双降冰片烷基化合物可以以高产率生产，同时抑制副产物诺里克林的形成。

公开(公告)号：US06359161B2

公开(公告)日：2002-03-19

申请号：US09852638

申请日：2001-05-11

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

IPC分类号： C07F708

CPC分类号： C07F7/14

摘要： A halopropyldimethylchlorosilane is prepared by reacting dimethylchlorosilane with an allyl halide in the presence of an iridium catalyst. The reaction is effected in the presence of an internal olefin compound, typically 1,5-cyclooctadiene. The internal olefin compound suppresses deactivation of the iridium catalyst during reaction. Using a smaller amount of the iridium catalyst, the process produces the halopropyldimethylchlorosilane in high yields.

摘要翻译： 卤代丙基二甲基氯硅烷通过使二氯甲硅烷与烯丙基卤化物在铱催化剂存在下反应来制备。 反应在内部烯烃化合物（通常为1,5-环辛二烯）的存在下进行。 内部烯烃化合物抑制反应期间铱催化剂的失活。 使用较少量的铱催化剂，该方法以高产率生产卤代丙基二甲基氯硅烷。

公开(公告)号：US06245925B1

公开(公告)日：2001-06-12

申请号：US09627074

申请日：2000-07-27

申请人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

发明人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

IPC分类号： C07F708

CPC分类号： C07F7/14

摘要： By reacting 4-vinyl-1-cyclohexene with a hydrogenchlorosilane compound in the presence of a platinum catalyst to give a reaction solution containing a monosilyl compound, removing the residual 4-vinyl-1-cyclohexene and isomers thereof from the reaction solution, and reacting the monosilyl compound again with the hydrogenchlorosilane compound, an organic silicon compound in which the two double bonds in 4-vinyl-1-cyclohexene have been hydrosilylated is produced in high yields.

摘要翻译： 通过在铂催化剂存在下使4-乙烯基-1-环己烯与氢氯硅烷化合物反应，得到含有单甲硅烷基化合物的反应溶液，从反应溶液中除去残留的4-乙烯基-1-环己烯及其异构体， 再次与高氯代硅烷化合物（其中4-乙烯基-1-环己烯中的两个双键已经被氢化硅烷化）的有机硅化合物再次产生单甲硅烷基化合物。

公开(公告)号：US5455360A

公开(公告)日：1995-10-03

申请号：US107886

申请日：1993-08-18

申请人： Norihisa Mino ,  Kazufumi Ogawa ,  Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota ,  Katsuya Takemura

发明人： Norihisa Mino ,  Kazufumi Ogawa ,  Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota ,  Katsuya Takemura

IPC分类号： C08G77/26 ,  B05D1/18 ,  C07F7/12 ,  C07F7/18 ,  C08G77/28 ,  C08J5/18 ,  C09K3/16 ,  H01B1/12 ,  C07F7/10 ,  C07D207/323

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y10/00 ,  B82Y40/00 ,  C07F7/12 ,  C07F7/182 ,  C07F7/1836 ,  C07F7/1868

摘要： Disclosed are a conductive pyrrole derivative monomolecular film covalently bonded to a substrate surface and method of manufacturing the same, and a monomer used for forming the conductive pyrrole derivative monomolecular film and method of manufacturing the same. The invention relates to a monomolecular ultrathin film comprising 1-pyrrolyl groups and silicon groups. The monomer used for forming the film is provided by reacting .omega.-(1-pyrrolyl)-1-alkene compound to a monosilane derivative compound, in which three out of four hydrogen atoms of monosilane are replaced with halogen or alkoxy groups, in the presence of a transition metal catalyst. A substrate is dipped and held in a nonaqueous solution of the above-noted monomer, thus chemically bonding a monomolecular film to a substrate surface. Furthermore, a polypyrrole derivative ultrathin film is formed by the electrolytic or catalytic polymerization of the monomolecular film.

摘要翻译： 公开了共价键合到基材表面的导电吡咯衍生物单分子膜及其制备方法，以及用于形成导电吡咯衍生物单分子膜的单体及其制造方法。 本发明涉及包含1-吡咯基和硅基团的单分子超薄膜。 用于形成膜的单体是通过使ω-（1-吡咯基）-1-烯烃化合物与甲硅烷衍生物化合物反应而得到的，其中甲硅烷的四个氢原子中的三个被卤素或烷氧基取代， 的过渡金属催化剂。 将基材浸渍并保持在上述单体的非水溶液中，从而将单分子膜化学键合到基材表面。 此外，通过单分子膜的电解或催化聚合形成聚吡咯衍生物超薄膜。

公开(公告)号：US5116973A

公开(公告)日：1992-05-26

申请号：US564093

申请日：1990-08-08

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

IPC分类号： C03C17/30 ,  C07B61/00 ,  C07F7/18 ,  C09D5/00

CPC分类号： C07F7/182

摘要： A silane compound having the following formula, wherein R.sup.1 and R.sup.2 are each monovalent hydrocarbon radicals having 1 to 4 carbon atoms and n is an integer of 0, 1 or 2: ##STR1## which is manufactured by reacting 1-allyl-.epsilon.-caprolactam of the following formula: ##STR2## with a hydrogen silane of the following formula:HSiR.sup.1.sub.n (OR.sup.2).sub.3-nin the presence of a platinum-containing catalyst. The silane compound is useful as a surface treatment agent for imparting a moisture-repelling property to the surface of various materials.

公开(公告)号：US5000881A

公开(公告)日：1991-03-19

申请号：US366003

申请日：1989-06-14

申请人： Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota

发明人： Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08F30/08

CPC分类号： C07F7/184 ,  C07F7/0818 ,  C07F7/182 ,  C07F7/1836 ,  C08F30/08

摘要： A novel organosilane compound having polymerizability is disclosed which is a vinyl .omega.-triorganosilyl n-undecanoate of the formula CH.sub.2 .dbd.CH--O--CO--(--CH.sub.2 --).sub.10 --SiR.sub.3, in which R is an alkyl group having 1 to 4 carbon atoms, alkoxy group having 1 to 4 carbon atoms or trialkyl siloxy group of which the alkyl group has 1 to 4 carbon atoms. This compound can be prepared by the hydrosilylation reaction between a triorganosilane of the formula HSiR.sub.3 and vinyl 10-undecenoate of the formulaCH.sub.2 .dbd.CH--O--CO--(--CH.sub.2 --).sub.8 --CH.dbd.CH.sub.2in the presence of a platinum catalyst. The compound is polymerizable to give not only a homopolymer of the compound alone but also a copolymer with other comonomers such as vinyl chloride, chloro trifluoroethylene, methyl methacrylate and the like.

摘要翻译： 公开了一种具有聚合性的新颖的有机硅烷化合物，它是式CH 2 = CH-O-CO - （ - CH 2））10-SiR 3的乙烯基ω-三有机甲硅烷基正十一酸酯，其中R是具有1-4个碳原子的烷基 原子，具有1至4个碳原子的烷氧基或其烷基具有1至4个碳原子的三烷基甲硅烷氧基。 在铂催化剂存在下，该化合物可以通过式HSiR 3的三有机硅烷与式CH 2 = CH-O-CO - （ - CH 2）8 -CH = CH 2的10-十一碳烯酸乙烯酯的氢化硅烷化反应来制备。 该化合物是可聚合的，不仅可以单独使用化合物的均聚物，而且可以与其它共聚单体如氯乙烯，氯三氟乙烯，甲基丙烯酸甲酯等共聚。

公开(公告)号：US4957607A

公开(公告)日：1990-09-18

申请号：US380350

申请日：1989-07-17

申请人： Mikio Endo ,  Minoru Takamizawa ,  Toshinobu Ishihara ,  Tohru Kubota ,  Toshio Shinohara

发明人： Mikio Endo ,  Minoru Takamizawa ,  Toshinobu Ishihara ,  Tohru Kubota ,  Toshio Shinohara

IPC分类号： C07F7/12 ,  C07B61/00 ,  C07F7/08 ,  C07F7/14 ,  C07F7/18

CPC分类号： C07F7/0801 ,  C07F7/14 ,  C07F7/1876

摘要： Cycloalkyl silane compounds such as cyclohexyl methyl dichlorosilane can be efficiently prepared by the photochemically induced hydrosilylation reaction. For example, an equimolar mixture of cyclohexene and methyl dichlorosilane with admixture of a catalytic amount of a platinum catalyst, which is an alcohol complex of chloroplatinic acid, is irradiated at a temperature of 70.degree. C. with ultraviolet light so that the hydrosilylation reaction takes place and proceeds almost to completeness without deactivation of the platinum catalyst to give the desired product in a yield of 90% or even higher. Unexpectedly, the efficiency of the reaction can be greatly increased when the platinum catalyst is prepared by heating a solution of chloroplatinic acid in 2-ethylhexyl alcohol at 50.degree. to 80.degree. C. for at least 4 hours.

公开(公告)号：US6087520A

公开(公告)日：2000-07-11

申请号：US233452

申请日：1999-01-20

申请人： Tohru Kubota ,  Mikio Endo

发明人： Tohru Kubota ,  Mikio Endo

IPC分类号： B01J27/13 ,  C07B61/00 ,  C07F7/08 ,  C07F7/10 ,  C07F7/04

CPC分类号： C07F7/0874

摘要： By subjecting to hydrosilylation a hydrogendimethylalkoxysilane compound and an N-silylated allylamine compound in the presence of a platinum catalyst, adding an alcohol to the reaction product to effect desilylation reaction, and hydrolyzing the resulting 3-aminopropyldimethylalkoxysilane compound, 1,3-bis(3-aminopropyl)tetramethyldisiloxane is prepared. The end product free of isomers and of quality can be prepared through simple steps, at a low cost and in high yields.

摘要翻译： 通过在铂催化剂存在下进行氢化硅烷化氢化二甲基烷氧基硅烷化合物和N-甲硅烷基化烯丙胺化合物，向反应产物中加入醇进行脱甲硅烷基化反应，并水解得到的3-氨基丙基二甲基烷氧基硅烷化合物1,3-双（3 氨基丙基）四甲基二硅氧烷。 不含异构体和质量的最终产品可以通过简单的步骤以低成本和高产率制备。

公开(公告)号：US5440063A

公开(公告)日：1995-08-08

申请号：US335415

申请日：1994-11-03

申请人： Masaki Takeuchi ,  Akira Yamamoto ,  Mikio Endo ,  Tohru Kubota ,  Yasufumi Kubota

发明人： Masaki Takeuchi ,  Akira Yamamoto ,  Mikio Endo ,  Tohru Kubota ,  Yasufumi Kubota

IPC分类号： C07B61/00 ,  C07F7/12 ,  C07F7/08

CPC分类号： C07F7/126 ,  C07F7/123

摘要： Dimethylchlorosilane and a triorganochlorosilane of the formula: R.sup.1 R.sup.2 R.sup.3 SiCl wherein R.sup.1, R.sup.2, and R.sup.3 are independently selected from monovalent hydrocarbon groups are concurrently prepared by reacting dimethyldichlorosilane with a SiH bond-containing silane compound of the formula: R.sup.1 R.sup.2 R.sup.3 SiH in the presence of a Lewis acid catalyst. The method is especially effective for concomitant preparation of dimethylchlorosilane and trimethylchlorosilane or t-butyldimethylchlorosilane in an inexpensive, simple, safe manner and in high yields.

摘要翻译： 二甲基氯硅烷和式R 1 R 2 R 3 SiCl其中R 1，R 2和R 3独立地选自一价烃基的三有机氯硅烷同时通过在路易斯酸催化剂存在下使二甲基二氯硅烷与下式的R 1 R 2 R 3 SiH的含SiH键的硅烷化合物反应制备： 。 该方法对于以廉价，简单，安全的方式并以高产率同时制备二甲基氯硅烷和三甲基氯硅烷或叔丁基二甲基氯硅烷是特别有效的。