公开(公告)号：US08513368B2

公开(公告)日：2013-08-20

申请号：US13260237

申请日：2010-03-30

申请人： Kenji Michiue ,  Sei-ichi Ishii ,  Makoto Mitani ,  Takeshi Karino

发明人： Kenji Michiue ,  Sei-ichi Ishii ,  Makoto Mitani ,  Takeshi Karino

IPC分类号： C08F236/04 ,  C08F236/06 ,  C08F4/6592

CPC分类号： C08F210/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F36/04 ,  C08F2420/02 ,  C08F4/6592 ,  C08F236/06 ,  C08F2500/03 ,  C08F2500/20 ,  C08F4/65904 ,  C08F4/65927 ,  C08F4/64113

摘要： An object of the invention is to provide copolymers which have a double bond in a side chain and are substantially free of unsaturated bonds in the main chain, copolymers which have a cyclic structure and are substantially free of unsaturated bonds in the main chain, and processes for economically synthesizing these copolymers.

摘要翻译： 本发明的目的是提供在侧链中具有双键并且在主链中基本上不含不饱和键的共聚物，具有环状结构且在主链中基本上不含不饱和键的共聚物，和 用于经济地合成这些共聚物。

公开(公告)号：US20120059135A1

公开(公告)日：2012-03-08

申请号：US13260237

申请日：2010-03-30

申请人： Kenji Michiue ,  Sei-ichi Ishii ,  Makoto Mitani ,  Takeshi Karino

发明人： Kenji Michiue ,  Sei-ichi Ishii ,  Makoto Mitani ,  Takeshi Karino

IPC分类号： C08F4/76 ,  C08F236/06

CPC分类号： C08F210/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F36/04 ,  C08F2420/02 ,  C08F4/6592 ,  C08F236/06 ,  C08F2500/03 ,  C08F2500/20 ,  C08F4/65904 ,  C08F4/65927 ,  C08F4/64113

摘要： An object of the invention is to provide copolymers which have a double bond in a side chain and are substantially free of unsaturated bonds in the main chain, copolymers which have a cyclic structure and are substantially free of unsaturated bonds in the main chain, and processes for economically synthesizing these copolymers.A copolymer of the invention is obtained by copolymerizing at least ethylene and a conjugated diene. In the copolymer, structural units derived from the conjugated diene represent 1 to 90 mol %. Structural units resulting from 1,2-addition of the conjugated diene and having a side-chain double bond represent 0 to 90 mol %, structural units resulting from 1,4-addition of the conjugated diene represent 0 to 3 mol %, structural units resulting from 1,3-addition of the conjugated diene represent 0 to 3 mol %, and the total of structural units resulting from 1,2-addition of the conjugated diene and having a 1,2-cyclopropane skeleton and structural units resulting from 1,2-addition of the conjugated diene and having a 1,2-cyclopentane skeleton represent 4 to 100 mol %.

摘要翻译： 本发明的目的是提供在侧链中具有双键并且在主链中基本上不含不饱和键的共聚物，具有环状结构且在主链中基本上不含不饱和键的共聚物，和 用于经济地合成这些共聚物。 至少乙烯和共轭二烯共聚得到本发明的共聚物。 在共聚物中，衍生自共轭二烯的结构单元表示1〜90摩尔％。 由共轭二烯的1,2-加成而具有侧链双键的结构单元表示0〜90摩尔％，由共轭二烯的1,4-加成得到的结构单元为0〜3摩尔％，结构单元 由共轭二烯的1,3-加成得到的共轭二烯的含量为0〜3摩尔％，1,2-共轭二烯的1,2-加成结构单元和1,2-环丙烷骨架的结构单元总和由1 共轭二烯的2-加成1,2-环戊烷骨架为4〜100摩尔％。

公开(公告)号：US20100267908A1

公开(公告)日：2010-10-21

申请号：US12659722

申请日：2010-03-18

申请人： Kenji Michiue ,  Mitsuhiko Onda ,  Shigekazu Matsui ,  Sadahiko Matsuura ,  Koji Endo ,  Makoto Mitani ,  Terunori Fujita

发明人： Kenji Michiue ,  Mitsuhiko Onda ,  Shigekazu Matsui ,  Sadahiko Matsuura ,  Koji Endo ,  Makoto Mitani ,  Terunori Fujita

IPC分类号： C07F7/28 ,  B01J31/16 ,  C08F210/00 ,  C08F4/44 ,  C08F210/14

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/02 ,  C08F210/16 ,  C08F2420/02 ,  C08F4/6592 ,  C08F2500/10 ,  C08F236/06 ,  C08F232/00 ,  C08F2500/25 ,  C08F210/10 ,  C08F210/06

摘要： [Task] To provide a catalyst for olefin polymerization having an excellent olefin polymerization performance and capable of producing a polyolefin with excellent properties.[Construction] A catalyst for olefin polymerization comprising (A) a transition metal compound represented by the following general formula (1); and (B) at least one compound selected from the group consisting of (B-1) organometallic compound, (B-2) organoaluminum oxy compound and (B-3) compounds capable of reacting with the transition metal compound (A) to form an ion pair: (M is a transition metal atom selected from Groups 4 to 6 of the periodic table; the two of R1 to R4, which are adjacent to each other, are combined to form a ring with the carbon atoms to which the two are bonded; groups of not forming a ring, R5 to R8, and X are each an atom or a group selected from a hydrogen atom, a halogen atom, a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing group, and a nitrogen-containing group; Q is —O—, —S—, —NRa—, or —PRb— (Ra and Rb are each a hydrogen atom or a hydrocarbon group); Y is a neutral ligand having an electron-donating group; m is a number satisfying the valence of M; and n is an integer of 0 to 3.).

摘要翻译： [任务]提供具有优异的烯烃聚合性能并能够生产具有优异性能的聚烯烃的烯烃聚合催化剂。 [构造]烯烃聚合用催化剂，其包含（A）由以下通式（1）表示的过渡金属化合物; 和（B）选自（B-1）有机金属化合物，（B-2）有机铝氧化合物和能够与过渡金属化合物（A）反应形成的（B-3）化合物的至少一种化合物，以形成 离子对：（M是选自元素周期表第4至6族的过渡金属原子;相互相邻的R 1至R 4中的两个被结合形成具有碳原子的环， 键合;不形成环的基团，R 5〜R 8和X各自为选自氢原子，卤素原子，烃基，卤代烃基，含氧基和 含氮基团; Q是-O - ， - S - ， - NR a - 或-PR b-（R a和R b各自是氢原子或烃基）; Y是具有给电子基团的中性配体; m为满足M的化合价的数; n为0〜3的整数。

公开(公告)号：US07601423B2

公开(公告)日：2009-10-13

申请号：US11791104

申请日：2005-11-18

申请人： Yasushi Nakayama ,  Naoto Matsukawa ,  Junji Saito ,  Hideki Bando ,  Yoshiho Sonobe ,  Kenji Michiue ,  Makoto Mitani ,  Terunori Fujita

发明人： Yasushi Nakayama ,  Naoto Matsukawa ,  Junji Saito ,  Hideki Bando ,  Yoshiho Sonobe ,  Kenji Michiue ,  Makoto Mitani ,  Terunori Fujita

IPC分类号： C08F4/10 ,  C08F4/16 ,  C08F4/12

CPC分类号： C08F10/02 ,  C08F10/00 ,  C08F110/02 ,  Y10T428/2982 ,  Y10T428/31938 ,  C08F4/6555 ,  C08F2500/17 ,  C08F2500/24 ,  C08F4/64048 ,  C08F4/64044

摘要： Ethylene-based copolymer microparticles and functional group-containing ethylene-based copolymer microparticles that have particle diameter smaller than that of conventional polyethylene fine-particles, no inter-particle agglomeration, very narrow particle size distribution, and high sphericity are provided, in which requirements (A) to (E): (A) The intrinsic viscosity [η] measured in decalin at 135° C. is in the range of 0.1 to 50 dl/g, (B) at least 95 wt % or more of particles pass through a mesh screen with an opening of 37 μm, (C) the median diameter (d50) measured by laser diffraction scattering is 3 μm≦d50≦25 μm, (D) the circularity coefficient is 0.85 or more, and (E) the variation coefficient of particle diameter (Cv) is 20% or less. Non-agglomerated spherical magnesium-containing microparticles used as magnesium-containing carrier component for olefin-polymerization catalysts that can manufacture the above microparticles are also provided.

摘要翻译： 提供粒径小于常规聚乙烯微粒的乙烯基共聚物微粒和含官能团的乙烯类共聚物微粒，不存在颗粒间团聚，非常窄的粒度分布和高球形度，其中要求 （A）〜（E）：（A）在135℃下在十氢化萘中测定的特性粘度η为0.1〜50dl / g，（B）至少95重量％以上的粒子通过 通过37μm的开口的筛网，（C）通过激光衍射散射测量的中值粒径（d50）为3μm（d50）=25μm，（D）圆形度系数为0.85以上，（E ），粒径变化系数（Cv）为20％以下。 还提供了用于制造上述微粒的用于烯烃聚合催化剂的含镁载体组分的非团聚球状含镁微粒。

公开(公告)号：US20080044655A1

公开(公告)日：2008-02-21

申请号：US11791104

申请日：2005-11-18

申请人： Yasushi Nakayama ,  Naoto Matsukawa ,  Junji Saito ,  Hideki Bando ,  Yoshiho Sonobe ,  Kenji Michiue ,  Makoto Mitani ,  Terunori Fujita

发明人： Yasushi Nakayama ,  Naoto Matsukawa ,  Junji Saito ,  Hideki Bando ,  Yoshiho Sonobe ,  Kenji Michiue ,  Makoto Mitani ,  Terunori Fujita

IPC分类号： C08F10/02

CPC分类号： C08F10/02 ,  C08F10/00 ,  C08F110/02 ,  Y10T428/2982 ,  Y10T428/31938 ,  C08F4/6555 ,  C08F2500/17 ,  C08F2500/24 ,  C08F4/64048 ,  C08F4/64044

摘要： Ethylene-based copolymer microparticles and functional group-containing ethylene-based copolymer microparticles that have particle diameter smaller than that of conventional polyethylene fine-particles, no inter-particle agglomeration, very narrow particle size distribution, and high sphericity are provided, in which requirements (A) to (E): (A) The intrinsic viscosity [η] measured in decalin at 135° C. is in the range of 0.1 to 50 dl/g, (B) at least 95 wt % or more of particles pass through a mesh screen with an opening of 37 μm, (C) the median diameter (d50) measured by laser diffraction scattering is 3 μm≦d50≦25 μm, (D) the circularity coefficient is 0.85 or more, and (E) the variation coefficient of particle diameter (Cv) is 20% or less. Non-agglomerated spherical magnesium-containing microparticles used as magnesium-containing carrier component for olefin-polymerization catalysts that can manufacture the above microparticles are also provided.

摘要翻译： 提供了粒径小于常规聚乙烯微粒的乙烯基共聚物微粒和含官能团的乙烯类共聚物微粒，不存在颗粒间聚集，非常窄的粒度分布和高球形度，其中要求 （A）〜（E）：（A）在135℃下在十氢化萘中测定的特性粘度η为0.1〜50dl / g，（B）至少95重量％以上的粒子通过 通过具有37μm的开口的网筛，（C）通过激光衍射散射测量的中值直径（d <50>）为3μm<= D <50 <= 25 （D）圆度系数为0.85以上，（E）粒径变化系数（Cv）为20％以下。 还提供了用于制造上述微粒的用于烯烃聚合催化剂的含镁载体组分的非团聚球状含镁微粒。

公开(公告)号：US20070260026A1

公开(公告)日：2007-11-08

申请号：US11661184

申请日：2005-08-25

申请人： Kenji Michiue ,  Mitsuhiko Onda ,  Shigekazu Matsui ,  Sadahiko Matsuura ,  Koji Endo ,  Makoto Mitani ,  Terunori Fujita

发明人： Kenji Michiue ,  Mitsuhiko Onda ,  Shigekazu Matsui ,  Sadahiko Matsuura ,  Koji Endo ,  Makoto Mitani ,  Terunori Fujita

IPC分类号： C08F4/645 ,  C07F17/00 ,  C07F7/00 ,  C07F7/28 ,  C08F10/00

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/02 ,  C08F210/16 ,  C08F2420/02 ,  C08F4/6592 ,  C08F2500/10 ,  C08F236/06 ,  C08F232/00 ,  C08F2500/25 ,  C08F210/10 ,  C08F210/06

摘要： [Task] To provide a catalyst for olefin polymerization having an excellent olefin polymerization performance and capable of producing a polyolefin with excellent properties. [Construction] A catalyst for olefin polymerization comprising (A) a transition metal compound represented by the following general formula (1); and (B) at least one compound selected from the group consisting of (B-1) organometallic compound, (B-2) organoaluminum oxy compound and (B-3) compounds capable of reacting with the transition metal compound (A) to form an ion pair: (M is a transition metal atom selected from Groups 4 to 6 of the periodic table; the two of R1 to R4, which are adjacent to each other, are combined to form a ring with the carbon atoms to which the two are bonded; groups of not forming a ring, R5 to R8, and X are each an atom or a group selected from a hydrogen atom, a halogen atom, a hydrocarbon group, a halogenated hydrocarbon group, an oxygen-containing group, and a nitrogen-containing group; Q is —O—, —S—, —NRa—, or —PRb— (Ra and Rb are each a hydrogen atom or a hydrocarbon group); Y is a neutral ligand having an electron-donating group; m is a number satisfying the valence of M; and n is an integer of 0 to 3.).

摘要翻译： [任务]提供具有优异的烯烃聚合性能并能够生产具有优异性能的聚烯烃的烯烃聚合催化剂。 [构造]烯烃聚合用催化剂，其包含（A）由以下通式（1）表示的过渡金属化合物; 和（B）选自（B-1）有机金属化合物，（B-2）有机铝氧化合物和能够与过渡金属化合物（A）反应形成的（B-3）化合物的至少一种化合物，以形成 离子对：（M是选自元素周期表第4至6族的过渡金属原子; R 1至R 4中的两个与每个 其它组合形成与两个键合的碳原子的环;不形成环的基团，R 5至R 8，以及X各自为 选自氢原子，卤原子，烃基，卤代烃基，含氧基和含氮基的原子或基团; Q是-O - ， - S - ， - - （R a）a和b b各自为氢原子或烃基 ）; Y是具有给电子基团的中性配体; m是满足M的化合价的数; n是0-3的整数。

公开(公告)号：US08349451B2

公开(公告)日：2013-01-08

申请号：US11887928

申请日：2006-04-07

申请人： Yasushi Nakayama ,  Naoto Matsukawa ,  Junji Saito ,  Susumu Murata ,  Makoto Mitani ,  Terunori Fujita

发明人： Yasushi Nakayama ,  Naoto Matsukawa ,  Junji Saito ,  Susumu Murata ,  Makoto Mitani ,  Terunori Fujita

IPC分类号： B32B15/02

CPC分类号： B01J13/14 ,  B01J13/02 ,  Y10T428/2982 ,  Y10T428/2985 ,  Y10T428/2987 ,  Y10T428/2989

摘要： To provide capsular fine particles comprising an olefinic polymer which have a uniform particle size distribution and a uniform particle size, and which are spherical and free from the coagulation between particles. Capsular fine particles comprising the olefinic polymer, of which the ratio (L/M) of the outer diameter (L) to the inner diameter (M) is 1.1 to 6.0, and the average diameter is 0.6 to 40 μm.

摘要翻译： 提供包含具有均匀粒度分布和均匀粒度的烯属聚合物的囊状细颗粒，并且其是球形的并且没有颗粒之间的凝结。 包含其外径（L）与内径（M）的比（L / M）为1.1〜6.0，平均直径为0.6〜40μm的烯烃系聚合物的囊状微粒。

公开(公告)号：US07858723B2

公开(公告)日：2010-12-28

申请号：US11883316

申请日：2006-01-31

申请人： Yasuo Satoh ,  Hideki Bando ,  Yoshiho Sonobe ,  Masao Suzuki ,  Daisuke Tanifuji ,  Chiaki Tomata ,  Makoto Mitani

发明人： Yasuo Satoh ,  Hideki Bando ,  Yoshiho Sonobe ,  Masao Suzuki ,  Daisuke Tanifuji ,  Chiaki Tomata ,  Makoto Mitani

IPC分类号： C08F10/02 ,  C08F10/04 ,  C08F10/14

CPC分类号： C08F10/02 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  C08F4/65916 ,  C08F4/6492 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/11 ,  C08F2500/04

摘要： Ethylene-based resin, which exhibits a satisfactorily high melt tension and can provide a molded object excellent in mechanical strength, the ethylene-based resin characterized in simultaneously satisfying the requirements [1] to [5] described below: [1] melt flow rate (MFR) under a loading of 2.16 kg at 190° C. is in the range of 0.1 to 100 g/10 minutes; [2] density (d) is in the range of 875 to 970 kg/m3; [3] ratio [MT/η*(g/P)] of melt tension [MT(g)] at 190° C. to shearing viscosity [η*(P)] at 200° C. at an angular velocity of 1.0 rad/sec. is in the range of 1.50×10−4 to 9.00×10−4; [4] sum [(A+B)(/1000C)] of the number of methyl branches [A(/1000C)] and the number of ethyl branches [B(/1000C)] per 1000 carbon atoms measured by 13C-NMR is 1.8 or less; and [5] zero shear viscosity [η0(P)] at 200° C. and weight-average molecular weight (Mw) measured by GPC-viscosity detector method (GPC-VISCO) satisfy the following relational expression (Eq-1): 0.01×10−13×Mw3.4≦η0≦4.5×10−13×Mw3.4  (Eq-1).

摘要翻译： 乙烯系树脂具有令人满意的高熔融张力，可提供机械强度优异的成型体，同时满足下述[1]〜[5]所述的乙烯类树脂：[1]熔体流动速率 （MFR）为2.16kg，190℃时为0.1〜100g / 10分钟; [2]密度（d）在875至970kg / m3的范围内; 在190℃下熔体张力[MT（g）]与剪切粘度[eegr * *（P）]的比值[MT / eegr * *（g / P）]以角速度 为1.0弧度/秒。 在1.50×10-4到9.00×10-4的范围内; [13]通过13 C-NMR测定的每1000个碳原子的甲基支链数[A（/ 1000C）]和乙基支链数[B（/ 1000C）]的[（A + B）（/ 1000C） 为1.8以下; 和[5]在200℃下的零剪切粘度[＆eegr.0（P）]和通过GPC-粘度检测器法（GPC-VISCO）测量的重均分子量（Mw）满足以下关系式（Eq-1 ）：0.01×10-13×Mw3.4＆nlE;＆eegr; 0＆nlE; 4.5×10-13×Mw3.4（Eq-1）。

公开(公告)号：US20090098381A1

公开(公告)日：2009-04-16

申请号：US11887928

申请日：2006-04-07

申请人： Yasushi Nakayama ,  Naoto Matsukawa ,  Junji Saito ,  Susumu Murata ,  Makoto Mitani ,  Terunori Fujita

发明人： Yasushi Nakayama ,  Naoto Matsukawa ,  Junji Saito ,  Susumu Murata ,  Makoto Mitani ,  Terunori Fujita

IPC分类号： B32B15/02

CPC分类号： B01J13/14 ,  B01J13/02 ,  Y10T428/2982 ,  Y10T428/2985 ,  Y10T428/2987 ,  Y10T428/2989

摘要： To provide capsular fine particles comprising an olefinic polymer which have a uniform particle size distribution and a uniform particle size, and which are spherical and free from the coagulation between particles. Capsular fine particles comprising the olefinic polymer, of which the ratio (L/M) of the outer diameter (L) to the inner diameter (M) is 1.1 to 6.0, and the average diameter is 0.6 to 40 μm.

摘要翻译： 提供包含具有均匀粒度分布和均匀粒度的烯属聚合物的囊状细颗粒，并且其是球形的并且没有颗粒之间的凝结。 包含其外径（L）与内径（M）的比（L / M）为1.1〜6.0，平均直径为0.6〜40μm的烯属聚合物的囊状微粒。

公开(公告)号：US07452946B2

公开(公告)日：2008-11-18

申请号：US10553726

申请日：2004-05-19

申请人： Sadahiko Matsuura ,  Naoto Matsukawa ,  Makoto Mitani ,  Junji Saito ,  Terunori Fujita ,  Yasushi Tohi ,  Koji Endo ,  Kenji Iwamasa ,  Keiko Takahashi

发明人： Sadahiko Matsuura ,  Naoto Matsukawa ,  Makoto Mitani ,  Junji Saito ,  Terunori Fujita ,  Yasushi Tohi ,  Koji Endo ,  Kenji Iwamasa ,  Keiko Takahashi

IPC分类号： C08F4/6592 ,  C08F4/642 ,  C08F4/645 ,  C08F210/16

CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F4/65904 ,  C08F4/64048 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/11 ,  C08F2500/20 ,  C08F2500/14 ,  C08F2500/04

摘要： An ethylene-based polymer which is a copolymer obtained from ethylene and a C3 to C10α-olefin and satisfies the following requirements (i), (ii), (iii) and (iv) simultaneously provides a blow-molded product and an extrusion-molded product excellent in moldability, mechanical strength and outward appearance. (i) melt flow rate [MFR2 (g/10 min)] under a loading of 2.16 kg at 190° C. is in the range of 0.01 to 10, (ii) melt tension [MT (g)] and the above melt flow rate [MFR2 (g/10 min)] satisfy the following relationship: MT≧3.2×MFR2−0.55, (iii) an activation energy [Ea] of fluidization is less than 30 (KJ/mol), and (iv) swell ratio is 1.36 or more. The ethylene-based polymer of the invention is preferably produced by copolymerizing ethylene with a C3 to C10 α-olefin, in the presence of a solid catalyst carrying, on (C) a solid carrier, a mixed transition metal compound consisting of (A1) a group 4 transition metal compound containing a specific salicyl aldimine ligand and (A2) a group 4 transition metal compound containing a specific cyclopentadienyl ligand and (B) at least one compound selected from (b-1) an organometallic compound, (b-2) an organoaluminum oxy compound, and (b-3) a compound reacting with the transition metal compound to form an ion pair.

摘要翻译： 乙烯基聚合物是由乙烯和C 3〜C 10α-烯烃得到的共聚物，其满足以下要求（i），（ii），（iii）和（iv）同时提供吹塑成型品， 成型性，机械强度和外观优异的成型品。 （i）在190℃下2.16kg负荷下的熔体流动速率[MFR 2]（g / 10min）]在0.01至10的范围内，（ii）熔体张力[MT （g）]和上述熔体流动速率[MFR 2（g / 10min）]满足以下关系：MT> = 3.2×MFR 2 <-0.005 （iii）流化的活化能[Ea]小于30（KJ / mol），（iv）溶胀比为1.36以上。 本发明的乙烯类聚合物优选通过在（C）固体载体，由（A1）组成的混合过渡金属化合物的固体催化剂存在下，使乙烯与C 3至C 10α-烯烃共聚而制备， 含有特定水杨醛亚胺配体的第4族过渡金属化合物和（A2）含有特定环戊二烯基配体的第4族过渡金属化合物和（B）至少一种选自（b-1）有机金属化合物，（b-2） ）有机铝氧化合物，和（b-3）与过渡金属化合物反应形成离子对的化合物。