-
1.发明授权Method for production of organic-inorganic complex, organic-inorganic complex, and polymeric composite material 有权有机 - 无机复合物，有机 - 无机复合物和聚合物复合材料的生产方法公开(公告)号：US07888416B2
公开(公告)日：2011-02-15
申请号：US12090415
申请日：2006-10-13
申请人： Kenji Tamura , Hirohisa Yamada , Hikaru Uno
发明人： Kenji Tamura , Hirohisa Yamada , Hikaru Uno
摘要： Disclosed are: a method for production of an organic-inorganic complex by intercalation of a positively charged organic compound between layers of a non-swellable layered silicate which is believed to be difficult to achieve under convenient conditions; the organic-inorganic complex; and a layered silicate/polymer nanocomposite using the organic-inorganic complex. The method comprises: step (I) wherein a hydrous layered silicate having a hydroxyl group in its crystalline structure is heat-treated at a temperature not higher than 1,200° C. and lower than the phase transition temperature of the silicate to dehydrate the silicate; and step (II) wherein the dehydrated layered silicate is contacted with an aqueous solution of a positively charged organic compound.
摘要翻译： 本发明公开了一种在易溶的条件下难以实现的非溶胀性层状硅酸盐层之间插入带正电荷的有机化合物的有机 - 无机络合物的制造方法。 有机 - 无机复合物; 和使用有机 - 无机络合物的层状硅酸盐/聚合物纳米复合材料。 该方法包括：步骤（I），其中将具有其结晶结构中的羟基的含水层状硅酸盐在不高于1200℃的温度下进行热处理，并且低于硅酸酯的相变温度使硅酸酯脱水; 和脱水层状硅酸盐与带正电荷的有机化合物的水溶液接触的工序（II）。
-
2.发明申请METHOD FOR PRODUCTION OF ORGANIC-INORGANIC COMPLEX, ORGANIC-INORGANIC COMPLEX, AND POLYMERIC COMPOSITE MATERIAL 有权有机无机复合材料，有机无机复合材料和聚合复合材料的生产方法公开(公告)号：US20090227715A1
公开(公告)日：2009-09-10
申请号：US12090415
申请日：2006-10-13
申请人： Kenji Tamura , Hirohisa Yamada , Hikaru Uno
发明人： Kenji Tamura , Hirohisa Yamada , Hikaru Uno
摘要： Disclosed are: a method for production of an organic-inorganic complex by intercalation of a positively charged organic compound between layers of a non-swellable layered silicate which is believed to be difficult to achieve under convenient conditions; the organic-inorganic complex; and a layered silicate/polymer nanocomposite using the organic-inorganic complex. The method comprises: step (I) wherein a hydrous layered silicate having a hydroxyl group in its crystalline structure is heat-treated at a temperature not higher than 1,200° C. and lower than the phase transition temperature of the silicate to dehydrate the silicate; and step (II) wherein the dehydrated layered silicate is contacted with an aqueous solution of a positively charged organic compound.
摘要翻译： 本发明公开了一种在易溶的条件下难以实现的非溶胀性层状硅酸盐层之间插入带正电荷的有机化合物的有机 - 无机络合物的制造方法。 有机 - 无机复合物; 和使用有机 - 无机络合物的层状硅酸盐/聚合物纳米复合材料。 该方法包括：步骤（I），其中将具有其结晶结构中的羟基的含水层状硅酸盐在不高于1200℃的温度下进行热处理，并且低于硅酸酯的相变温度以使硅酸酯脱水; 和脱水层状硅酸盐与带正电荷的有机化合物的水溶液接触的工序（II）。
-
公开(公告)号：US20090233107A1
公开(公告)日：2009-09-17
申请号：US12066743
申请日：2006-09-13
申请人： Hirohisa Yamada , Kenji Tamura , Shingo Yokoyama
发明人： Hirohisa Yamada , Kenji Tamura , Shingo Yokoyama
摘要： A new mixed layer silicate useful for industrial materials is provided.The mixed layer silicate is obtained by a specific synthesis method. The mixed layer silicate includes non-swelling 2:1 type layered silicate layers having a layer charge of 0 or non-swelling 2:1 type layered silicate layers having a layer charge of 0.6 to 1 and including potassium ions between layers and swelling 2:1 type layered silicate layers having a layer charge of 0.2 to 0.6 and including exchangeable cations between layers. The mixed layer silicate has a structure in which individual layers are laminated in a regular order in a lamination direction (regularly mixed layer structure). Furthermore, an organic-inorganic composite material is prepared through intercalation of a positive charge organic compound into the swelling 2:1 type layered silicate layers in the resulting mixed layer silicate, and the resulting organic-inorganic composite material is swollen and peeled in a polymer, so that a polymer composite material in which silicate sheet sets, each set including a few silicate sheets, are homogeneously dispersed in the polymer can be obtained.
摘要翻译： 提供了一种用于工业材料的新型混合层状硅酸盐。 通过特定的合成方法获得混合层状硅酸盐。 混合层硅酸盐包括具有层电荷为0的非膨胀2:1层状硅酸盐层或层积电荷为0.6〜1的不溶胀2:1层状硅酸盐层，并且在层之间包含钾离子和溶胀2： 1层层状硅酸盐层，其层电荷为0.2至0.6，并且包括层之间的可交换阳离子。 混合层状硅酸盐具有以层叠方向（规则的混合层结构）的顺序层叠各层的结构。 此外，通过在所得混合层硅酸盐中将阳离子有机化合物插入溶胀的2:1层状硅酸盐层中制备有机 - 无机复合材料，所得有机 - 无机复合材料在聚合物中溶胀并剥离 可以得到均匀分散在聚合物中的含有硅酸盐系列的硅酸盐系列组合物的聚合物复合材料。
-
公开(公告)号：US09284490B2
公开(公告)日：2016-03-15
申请号：US13881556
申请日：2011-10-13
申请人： Kenji Tamura , Kazuya Morimoto , Hirohisa Yamada
发明人： Kenji Tamura , Kazuya Morimoto , Hirohisa Yamada
CPC分类号： C09K21/06 , C01B13/14 , C01B13/145 , C01F5/14 , C01F7/021 , C01F11/02 , C01G49/02 , C01P2002/08 , C01P2002/22 , C01P2002/72 , C01P2002/82
摘要： The invention has for its objects to provide an organic/inorganic hybrid that has high flame retardancy, flexibility, moldability and affinities for organic compounds, and is capable of including therein an organic compound having a large number of carbon atoms.The organic/inorganic hybrid comprises a layered hydroxide mineral 40 with sheet-like inorganic compound unit layers 11a, 11b, 11c and 11d and an organic compound 13 included between the inorganic compound unit layers 11a, 11b, 11c and 11d. The above objects are achievable by using as the hydroxide mineral 40 at least one hydroxide mineral selected from the group consisting of Mg(OH)2, Ca(OH)2, Al(OH)3, AlO(OH), Fe(OH)3 and FeO(OH), and as the organic compound 13 a saccharide having 4 to 40 carbon atoms.
摘要翻译： 本发明的目的是提供对有机化合物具有高阻燃性，柔性，成型性和亲和力的有机/无机混合物，并且能够在其中包含具有大量碳原子的有机化合物。 有机/无机杂化物包括具有片状无机化合物单元层11a，11b，11c和11d的层状氢氧化物矿物40和包含在无机化合物单元层11a，11b，11c和11d之间的有机化合物13。 通过使用氢氧化物矿物40，可以使用选自Mg（OH）2，Ca（OH）2，Al（OH）3，AlO（OH），Fe（OH） 3和FeO（OH），作为有机化合物13，具有碳原子数4〜40的糖类。
-
5.发明授权Organic-inorganic composite and polymeric composite material, and method producing them 有权有机 - 无机复合材料和聚合物复合材料及其制备方法公开(公告)号：US08420040B2
公开(公告)日：2013-04-16
申请号：US11661311
申请日：2005-08-25
申请人： Kenji Tamura , Hirohisa Yamada , Shingo Yokoyama , Tsutomu Sato
发明人： Kenji Tamura , Hirohisa Yamada , Shingo Yokoyama , Tsutomu Sato
CPC分类号： C09C1/42 , B82Y30/00 , C01B33/44 , C01P2002/72 , C01P2004/04 , C01P2004/61 , C08J5/005 , C08J2377/00 , C09C1/405 , Y10T428/251
摘要： An organic-inorganic composite is useful as a sheeted filler having a high aspect ratio. A positively charged organic compound is intercalated into a non-swelling layered silicate that is composed of mica and has K ions between the layers, and has primary particles of 2 μm to 500 μm as an average particle size. The layered silicate is represented as the formula: (KaM0.1-b)(XcYd)(Si4-eAle)O10(OHfF2-f), wherein 0.6≦a≦1.0, 0≦b≦0.1, 1.0≦c≦3, 0≦d≦2, 2≦c+d≦3, 0≦e≦4, 0≦f≦2; M is a cation other than K which is between layers and at least one of Li, Na, Rb, Cs, NH4, Be, Mg, Ca, Sr, Ba, Mn, Fe, Ni, Cu, Zn and Al; X and Y are metals enclosed in an octahedral formed in a 2:1 typed sheet; X is at least one of Mg, Fe, Mn, Ni, Zn and Li; and Y is at least one of Al, Fe, Mn and Cr.
摘要翻译： 有机 - 无机复合材料可用作具有高纵横比的片状填料。 带正电的有机化合物插入由云母组成并且在层之间具有K离子的非溶胀层状硅酸盐中，并且具有作为平均粒径的2μm至500μm的初级粒子。 层状硅酸盐表示为：（KaM0.1-b）（XcYd）（Si4-eAle）O10（OHfF2-f），其中0.6＆nlE; a＆nlE; 1.0,0和nlE; b＆nlE; 0.1,1.0＆nlE; c＆nlE; 3，0＆nlE; d＆nlE; 2，2＆nlE; c + d＆nlE; 3,0和nlE; e＆nlE; 4,0＆nlE; f＆nlE; 2; M是层间和Li，Na，Rb，Cs，NH4，Be，Mg，Ca，Sr，Ba，Mn，Fe，Ni，Cu，Zn和Al中的至少一种之间的K之外的阳离子; X和Y是以2：1型片形成的八面体封闭的金属; X是Mg，Fe，Mn，Ni，Zn和Li中的至少一种; Y是Al，Fe，Mn和Cr中的至少一种。
-
公开(公告)号：US20100127416A1
公开(公告)日：2010-05-27
申请号：US12603932
申请日：2009-10-22
申请人： Kazumi MINAGAWA , Hirohisa Yamada , Kenji Tamura
发明人： Kazumi MINAGAWA , Hirohisa Yamada , Kenji Tamura
CPC分类号： C01B13/145 , B01J4/002 , B01J19/0013 , B01J19/1887 , B01J21/16 , B01J29/06 , B01J2204/002 , B01J2219/0009 , B01J2219/00128 , B01J2219/00198 , B01J2219/00202 , B01J2219/00231 , B01J2219/00234 , B82Y40/00 , C01B33/26 , C01B33/40
摘要： The apparatus for manufacturing solid particles at a nano level includes a chamber for isolation from an external space, a monoaxial rotary disk disposed in the chamber, a receiving surface at one end of the rotary disk, a material supply mechanism for supplying the material to the receiving surface, a rotary mechanism for applying a centrifugal force to the rotary disk so that the raw material supplied to the receiving surface is produced into a thin film and atomized and scattered from the outer peripheral edge, and a control mechanism for the temperature in the chamber that controls the temperature at least at the outer peripheral edge of the receiving surface and on the side nearer to the center of rotation to a temperature lower than a volatilization temperature of a volatile solvent and the temperature at the outer side therefrom to the volatilization temperature of the volatile solvent or higher.
摘要翻译： 用于制造纳米级固体颗粒的装置包括用于与外部空间隔离的室，设置在室中的单轴旋转盘，在旋转盘的一端的接收表面，用于将材料供应到 接收表面，用于向旋转盘施加离心力的旋转机构，使得供应到接收表面的原料被制成薄膜并从外周边缘雾化和散射;以及控制机构， 室至少在接收表面的外周边缘处和在更接近旋转中心的一侧将温度控制在低于挥发性溶剂的挥发温度的温度以及其外侧的温度至挥发温度 的挥发性溶剂或更高。
-
公开(公告)号：US08080188B2
公开(公告)日：2011-12-20
申请号：US12603932
申请日：2009-10-22
申请人： Kazumi Minagawa , Hirohisa Yamada , Kenji Tamura
发明人： Kazumi Minagawa , Hirohisa Yamada , Kenji Tamura
IPC分类号： B29B9/00
CPC分类号： C01B13/145 , B01J4/002 , B01J19/0013 , B01J19/1887 , B01J21/16 , B01J29/06 , B01J2204/002 , B01J2219/0009 , B01J2219/00128 , B01J2219/00198 , B01J2219/00202 , B01J2219/00231 , B01J2219/00234 , B82Y40/00 , C01B33/26 , C01B33/40
摘要： The apparatus for manufacturing solid particles at a nano level includes a chamber for isolation from an external space, a monoaxial rotary disk disposed in the chamber, a receiving surface at one end of the rotary disk, a material supply mechanism for supplying the material to the receiving surface, a rotary mechanism for applying a centrifugal force to the rotary disk so that the raw material supplied to the receiving surface is produced into a thin film and atomized and scattered from the outer peripheral edge, and a control mechanism for the temperature in the chamber that controls the temperature at least at the outer peripheral edge of the receiving surface and on the side nearer to the center of rotation to a temperature lower than a volatilization temperature of a volatile solvent and the temperature at the outer side therefrom to the volatilization temperature of the volatile solvent or higher.
摘要翻译： 用于制造纳米级固体颗粒的装置包括用于与外部空间隔离的室，设置在室中的单轴旋转盘，在旋转盘的一端的接收表面，用于将材料供应到 接收表面，用于向旋转盘施加离心力的旋转机构，使得供应到接收表面的原料被制成薄膜并从外周边缘雾化和散射;以及控制机构， 室至少在接收表面的外周边缘处和在更接近旋转中心的一侧将温度控制在低于挥发性溶剂的挥发温度的温度以及其外侧的温度至挥发温度 的挥发性溶剂或更高。
-
8.发明申请Adsorbent for radioelement-containing waste and method for fixing radioelement 失效用于含放射性废物的废物的吸附剂和固定放射性元素的方法公开(公告)号：US20090305885A1
公开(公告)日：2009-12-10
申请号：US11628787
申请日：2005-06-07
申请人： Hirohisa Yamada , Kenji Tamura , Junzo Tanaka , Toshiyuki Ikoma , Yasushi Suetsugu , Yusuke Moriyoshi , Yujiro Watanabe
发明人： Hirohisa Yamada , Kenji Tamura , Junzo Tanaka , Toshiyuki Ikoma , Yasushi Suetsugu , Yusuke Moriyoshi , Yujiro Watanabe
CPC分类号： B01J20/06 , B01J20/0222 , B01J20/0225 , B01J20/0251 , B01J20/0259 , B01J20/041 , B01J20/08 , B01J20/28004 , B01J20/28019 , B01J20/30 , C02F1/281 , C02F1/288 , C02F2101/006 , G21F9/02 , G21F9/12 , G21F9/30
摘要： An adsorbent for radioelement-containing waste composed of the following spherical layered double hydroxide (A) or spherical metal hydroxide (B) is provided. (A) is a nonstoichiometric compound represented by general formula (a) or (b): [M2+1-xM3+x(OH)2]x+[An−x/n.mH2O]x− . . . (a), [Al2Li(OH)6]x+[An−x/n.mH2O]x− . . . (b) wherein 0.1≦x≦0.4, 0
摘要翻译： 提供了由以下球形层状双氢氧化物（A）或球状金属氢氧化物（B）组成的含放射性元素的废物的吸附剂。 （A）是由通式（a）或（b）表示的非化学计量的化合物：[M2 + 1-xM3 + x（OH）2] x + [An-x / n.mH2O] x-。 。 。 （a），[Al 2 Li（OH）6] x + [An-x / n.mH 2 O] x - 。 。 。 （b）其中0.1 <= x <= 0.4,0
-
公开(公告)号：US20130221295A1
公开(公告)日：2013-08-29
申请号：US13881556
申请日：2011-10-13
申请人： Kenji Tamura , Kazuya Morimoto , Hirohisa Yamada
发明人： Kenji Tamura , Kazuya Morimoto , Hirohisa Yamada
IPC分类号： C09K21/06
CPC分类号： C09K21/06 , C01B13/14 , C01B13/145 , C01F5/14 , C01F7/021 , C01F11/02 , C01G49/02 , C01P2002/08 , C01P2002/22 , C01P2002/72 , C01P2002/82
摘要： The invention has for its objects to provide an organic/inorganic hybrid that has high flame retardancy, flexibility, moldability and affinities for organic compounds, and is capable of including therein an organic compound having a large number of carbon atoms.The organic/inorganic hybrid comprises a layered hydroxide mineral 40 with sheet-like inorganic compound unit layers 11a, 11b, 11c and 11d and an organic compound 13 included between the inorganic compound unit layers 11a, 11b, 11c and 11d. The above objects are achievable by using as the hydroxide mineral 40 at least one hydroxide mineral selected from the group consisting of Mg(OH)2, Ca(OH)2, Al(OH)3, AlO(OH), Fe(OH)3 and FeO(OH), and as the organic compound 13 a saccharide having 4 to 40 carbon atoms.
摘要翻译： 本发明的目的是提供对有机化合物具有高阻燃性，柔性，成型性和亲和力的有机/无机混合物，并且能够在其中包含具有大量碳原子的有机化合物。 有机/无机杂化物包括具有片状无机化合物单元层11a，11b，11c和11d的层状氢氧化物矿物40和包含在无机化合物单元层11a，11b，11c和11d之间的有机化合物13。 通过使用氢氧化物矿物40，可以使用选自Mg（OH）2，Ca（OH）2，Al（OH）3，AlO（OH），Fe（OH） 3和FeO（OH），作为有机化合物13，具有碳原子数4〜40的糖类。
-
10.发明授权Adsorbent for radioelement-containing waste and method for fixing radioelement 失效用于含放射性废物的废物的吸附剂和固定放射性元素的方法公开(公告)号：US08207391B2
公开(公告)日：2012-06-26
申请号：US11628787
申请日：2005-06-07
申请人： Hirohisa Yamada , Kenji Tamura , Junzo Tanaka , Toshiyuki Ikoma , Yasushi Suetsugu , Yusuke Moriyoshi , Yujiro Watanabe
发明人： Hirohisa Yamada , Kenji Tamura , Junzo Tanaka , Toshiyuki Ikoma , Yasushi Suetsugu , Yusuke Moriyoshi , Yujiro Watanabe
CPC分类号： B01J20/06 , B01J20/0222 , B01J20/0225 , B01J20/0251 , B01J20/0259 , B01J20/041 , B01J20/08 , B01J20/28004 , B01J20/28019 , B01J20/30 , C02F1/281 , C02F1/288 , C02F2101/006 , G21F9/02 , G21F9/12 , G21F9/30
摘要： An adsorbent for radioelement-containing waste composed of the following spherical layered double hydroxide (A) or spherical metal hydroxide (B) is provided. (A) is a nonstoichiometric compound represented by general formula (a) or (b): [M2+1-xM3+x(OH)2]x+[An−x/n·mH2O]x− . . . (a), [Al2Li(OH)6]x+[An−x/n·mH2O]x− . . . (b) wherein 0.1≦x≦0.4, 0
摘要翻译： 提供了由以下球形层状双氢氧化物（A）或球状金属氢氧化物（B）组成的含放射性元素的废物的吸附剂。 （A）是由通式（a）或（b）表示的非化学计量的化合物：[M2 + 1-xM3 + x（OH）2] x + [An-x / n·mH2O] x-。 。 。 （a），[Al 2 Li（OH）6] x + [An-x / n·mH 2 O] x - 。 。 。 （b）其中0.1＆nlE; x＆nlE; 0.4,0
-
-
-
-
-
-
-
-
-
搜索结果
94 条记录 (耗时 0.024 秒)
