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公开(公告)号：US3974256A
公开(公告)日：1976-08-10
申请号：US467716
申请日：1974-05-07
CPC分类号： B01D53/52 , B01D53/04 , C10K1/20 , B01D2253/10 , B01D2253/104 , B01D2253/108 , B01D2253/112 , B01D2257/304 , B01D2257/308 , B01D2259/4009 , B01D2259/402
摘要： Hydrogen sulfide and its precursors can be selectively sorbed from gas streams containing same by contacting the gas stream at elevated temperatures with a regenerable sorbent comprising a supported or unsupported lanthanum or rare earth metal component. Subsequent to sorption, the sorbent may be desorbed and regenerated by treatment with steam (desorption) and an oxidizing gas (regeneration). The sorbent capacity may be increased by the use of alkali or alkaline earth metal components as promoters.
摘要翻译： 硫化氢及其前体可以选择性地从含有它们的气流中吸收，所述气流通过在升高的温度下与含有负载或未负载的镧或稀土金属组分的可再生吸附剂接触。 在吸附之后，吸附剂可以通过用蒸汽（解吸）和氧化气体（再生）处理来解吸和再生。 吸附剂容量可以通过使用碱金属或碱土金属组分作为助催化剂而增加。
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2.发明授权
公开(公告)号：US4412911A
公开(公告)日：1983-11-01
申请号：US351967
申请日：1982-02-24
摘要： A partially deactivated alkaline earth metal perovskite-containing catalyst is reactivated by contact with a reducing gas at reducing conditions. The reactivated catalyst is useful in hydrocarbon treating processes such as catalytic cracking and fluid coking.
摘要翻译： 通过在还原条件下与还原气体接触，使部分失活的含碱土金属钙钛矿催化剂再活化。 再活化的催化剂可用于烃处理过程如催化裂化和流化焦化。
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公开(公告)号：US4002720A
公开(公告)日：1977-01-11
申请号：US536164
申请日：1974-12-24
CPC分类号： B01D53/52 , B01D53/04 , C10K1/20 , B01D2253/10 , B01D2253/104 , B01D2253/108 , B01D2253/112 , B01D2257/304 , B01D2257/308 , B01D2259/4009 , B01D2259/402
摘要： Hydrogen sulfide and its precursors can be selectively sorbed from gas streams containing the same by contacting the gas stream at elevated temperatures with a regenerable sorbent comprising a steam-treated support composited with a rare earth metal component. Presteaming the support lowers the amount of rare earth metal component needed to achieve a given activity level for hydrogen sulfide removal. Subsequent to sorption, the sorbent composite may be desorbed and regenerated by treatment with steam (desorption) and an oxidizing gas (regeneration). The sorbent capacity may be increased by the use of alkali or alkaline earth metal components as promoters. A preferred sorbent comprises lanthanum composited with presteamed alumina.
摘要翻译： 硫化氢及其前体可以通过使高温气流与含有与稀土金属组分合成的经蒸汽处理的载体的可再生吸附剂接触而从含有它们的气流中选择性吸收。 预硫化载体降低了实现硫化氢去除的给定活性水平所需的稀土金属组分的量。 在吸附之后，吸附剂复合物可以通过用蒸汽（解吸）和氧化气体（再生）处理来解吸和再生。 吸附剂容量可以通过使用碱金属或碱土金属组分作为助催化剂而增加。 优选的吸附剂包括与预制氧化铝复合的镧。
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公开(公告)号：US5296515A
公开(公告)日：1994-03-22
申请号：US893165
申请日：1992-06-03
IPC分类号： C08F8/50
CPC分类号： C08F8/50
摘要： A method is provided for hydrovisbreaking hydrocarbon polymers, particularly those derived from scrap articles, in which a mixture of at least one hydrocarbon polymer and a solvent is contacted with hydrogen under conditions sufficient to hydrovisbreak the polymer. The solvent comprises a combined weight percentage of C.sub.n H.sub.2n-8 and C.sub.n H.sub.2n-10 hydrocarbons of at least about 10 weight percent, where n is an integer of at least 8 in C.sub.n H.sub.2n-8 and n is an integer of at least 10 in C.sub.n H.sub.2n-10. The hydrovisbroken polymer can be fed to a catalytic cracker for cracking to cracked products.
摘要翻译： 提供了一种用于加氢裂解烃聚合物，特别是衍生自废料的那些烃聚合物的方法，其中至少一种烃聚合物和溶剂的混合物在足以使聚合物破裂的条件下与氢气接触。 溶剂包括CnH2n-8和CnH2n-10烃的至少约10重量％的组合重量百分数，其中n是C n H 2n-8中的至少8的整数，n是C n H 2n-10中的至少10的整数 。 加氢分解聚合物可以进料到催化裂化器中以开裂裂化产物。
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5.发明授权Hydrocarbon treating processes using perovskite-containing catalytic compositions 失效使用含钙钛矿的催化组合物的烃处理方法
公开(公告)号：US4522706A
公开(公告)日：1985-06-11
申请号：US564843
申请日：1983-12-23
CPC分类号： C10B55/02 , B01J23/005 , C10G11/04 , Y10S502/525
摘要： Hydrocarbon treating processes such as catalytic cracking and fluid coking are provided in which a perovskite-containing catalytic composition is used as catalyst. The perovskite-containing catalytic composition is produced by interrupting the reaction of perovskite precursors after formation of at least 60 wt. % perovskite and before formation of more than 99 wt. % perovskite from the precursors.
摘要翻译： 提供了使用含有钙钛矿的催化剂组合物作为催化剂的烃处理方法如催化裂化和流体焦化。 含钙钛矿的催化剂组合物是通过在形成至少60wt。％之后中断钙钛矿前体的反应来制备的。 ％钙钛矿，形成99重量％以上。 ％前体钙钛矿。
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6.发明授权
公开(公告)号：US4446011A
公开(公告)日：1984-05-01
申请号：US411366
申请日：1982-08-25
摘要： A catalyst regeneration process is provided in which the rate of removal of carbon from the coked catalyst is increased at a relatively low temperature when the catalyst comprises a perovskite. Hydrocarbon treating processes utilizing the regenerated perovskite-containing catalysts are also provided. The regenerated catalyst is particularly suited for use in catalytic cracking of hydrocarbon residua.
摘要翻译： 提供了一种催化剂再生方法，其中当催化剂包含钙钛矿时，来自焦化催化剂的碳的去除速率在相对较低的温度下增加。 还提供了利用再生的含钙钛矿催化剂的烃处理方法。 再生催化剂特别适用于烃残渣的催化裂化。
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公开(公告)号：US4179409A
公开(公告)日：1979-12-18
申请号：US850038
申请日：1977-11-09
CPC分类号： B01J29/061 , B01J23/002 , B01J2523/00 , Y10S502/525
摘要： A perovskite is added to a conventional hydrocarbon cracking catalyst comprising a zeolite and an inorganic oxide gel matrix. The perovskite is present in said catalyst in an amount up to about 10 weight percent based on the total catalyst.
摘要翻译： 将钙钛矿加入到包含沸石和无机氧化物凝胶基质的常规烃裂解催化剂中。 基于总催化剂，钙钛矿存在于所述催化剂中，其量高达约10重量％。
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8.发明申请Transition metal mediated oxidation of hetero atoms in organic molecules coordinated to transition metals 失效过渡金属介导的有机分子中杂原子的氧化与过渡金属配位公开(公告)号：US20090274755A1
公开(公告)日：2009-11-05
申请号：US12459757
申请日：2009-07-07
IPC分类号： A61K9/48 , C07D401/02 , A61K9/00 , A61K31/4439
CPC分类号： C07D401/12 , A61K9/5078 , A61K31/4439
摘要： The present invention is directed to a process for the catalytic oxidation of the thioether 5-methoxy-2-((4-methoxy-3,5-dimethyl-2-pyridinyl)methyl)methylthio)-1H-benzimidazole to its sulfoxide: 5-methoxy-2-((4-methoxy-3,5-dimethyl-2-pyridinyl) methyl)methylsulfinyl)-1H-benzimidazole comprising: reacting the thioether with: 1) a transition metal catalyst; and, 2) an oxygen source; wherein the thioether is oxidized to a sulfoxide and wherein one of either the R and S enantiomers is formed to an enantiomeric excess.
摘要翻译： 本发明涉及一种将硫醚5-甲氧基-2 - （（4-甲氧基-3,5-二甲基-2-吡啶基）甲基）甲硫基）-1H-苯并咪唑催化氧化成其亚砜的方法：5 - （（4-甲氧基-3,5-二甲基-2-吡啶基）甲基）甲基亚磺酰基）-1H-苯并咪唑包括：使硫醚与以下物质反应：1）过渡金属催化剂; 和2）氧源; 其中所述硫醚被氧化成亚砜，并且其中R和S对映异构体之一形成为对映体过量。
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公开(公告)号：US4219447A
公开(公告)日：1980-08-26
申请号：US970936
申请日：1978-12-19
申请人： Kenneth S. Wheelock
发明人： Kenneth S. Wheelock
摘要： A novel catalyst precursor which comprises a Group IV-B transition metal oxide deposited on the surface of an inorganic metal oxide support, preferably alumina; especially where the Group IV-B transition metal oxide is deposited on the support surface as discrete areas separated by areas of support surface which contain little, if any, of said Group IV-B transition metal oxide; and a catalyst composition comprised of a cluster of a Group IV-B transition metal oxide and a Group VIII metal preferably a Group VIII noble metal, deposited on an inorganic metal oxide support, particularly an alumina support, especially where the clusters are deposited on the surface of the support, as discrete clusters separated by areas of support surface which contain little, if any, of said Group VI-B transition metal oxide, or clusters of said Group IV-B and Group VIII metals.
摘要翻译： 一种新型催化剂前体，其包含沉积在无机金属氧化物载体表面上的优选氧化铝的IV-B族过渡金属氧化物; 特别是在IV-B族过渡金属氧化物沉积在支撑表面上的离散区域中分离的区域，该区域由少量（如果有的话）含有所述IV-B族过渡金属氧化物的支撑表面区域分开; 以及沉积在无机金属氧化物载体上的Ⅳ-B族过渡金属氧化物和Ⅷ族金属，优选Ⅷ族贵金属的簇的催化剂组合物，特别是其上沉积在 支撑体的表面，作为离散的簇，其被包含少量（如果有的话）的所述VI-B族过渡金属氧化物或所述IV-B族和第VIII族金属的簇的支撑表面区域分开。
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10.发明授权
公开(公告)号：US4171289A
公开(公告)日：1979-10-16
申请号：US856930
申请日：1977-12-02
申请人： Kenneth S. Wheelock
发明人： Kenneth S. Wheelock
CPC分类号： B01J23/40 , B01D53/944 , B01J37/0201
摘要： The disclosure herein relates to (a) a process for the preparation of catalysts which are highly active for oxidizing the carbon monoxide (CO) and hydrocarbon (HC) present in automobile exhaust gases, with minimum oxidation of the sulfur dioxide, by controlling the acidity of the support, or carrier, within certain critical ranges while a Group VIII noble metal component, or components, is composited with said support in forming the catalyst; (b) a process embodying the use of the so-formed catalysts in the treatment of automotive exhaust gases; and, (c) the catalyst compositions so-formed from supports the surface acidity of which is controlled. In the formation of the catalysts the total surface acidity of the support on which the metal, or metals, component is deposited is maintained between about 0.01 to about 0.10 micromoles pyridine/m.sup.2, and the surface area of the metal, or metals, component ranges up to about 50 m.sup.2 /g, preferably from about 1 m.sup.2 /g to about 35 m.sup.2 /g, and more preferably from about 1 m.sup.2 /g to about 20 m.sup.2 /g.
摘要翻译： 本文的公开内容涉及（a）制备催化剂的方法，所述催化剂通过控制酸度来最小程度地氧化二氧化硫，所述催化剂对于氧化汽车废气中存在的一氧化碳（CO）和烃（HC）是高度活性的 的载体或载体在某些临界范围内，而第VIII族贵金属组分或组分与形成催化剂的所述载体复合; （b）在汽车尾气处理中使用如此形成的催化剂的方法; 和（c）由其表面酸度被控制的载体所形成的催化剂组合物。 在催化剂的形成中，金属或金属组分沉积在其上的载体的总表面酸度保持在约0.01至约0.10微摩尔吡啶/ m 2之间，并且金属或金属的组分范围 高达约50m 2 / g，优选约1m 2 / g至约35m 2 / g，更优选约1m 2 / g至约20m 2 / g。
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