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公开(公告)号:US5296515A
公开(公告)日:1994-03-22
申请号:US893165
申请日:1992-06-03
IPC分类号: C08F8/50
CPC分类号: C08F8/50
摘要: A method is provided for hydrovisbreaking hydrocarbon polymers, particularly those derived from scrap articles, in which a mixture of at least one hydrocarbon polymer and a solvent is contacted with hydrogen under conditions sufficient to hydrovisbreak the polymer. The solvent comprises a combined weight percentage of C.sub.n H.sub.2n-8 and C.sub.n H.sub.2n-10 hydrocarbons of at least about 10 weight percent, where n is an integer of at least 8 in C.sub.n H.sub.2n-8 and n is an integer of at least 10 in C.sub.n H.sub.2n-10. The hydrovisbroken polymer can be fed to a catalytic cracker for cracking to cracked products.
摘要翻译: 提供了一种用于加氢裂解烃聚合物,特别是衍生自废料的那些烃聚合物的方法,其中至少一种烃聚合物和溶剂的混合物在足以使聚合物破裂的条件下与氢气接触。 溶剂包括CnH2n-8和CnH2n-10烃的至少约10重量%的组合重量百分数,其中n是C n H 2n-8中的至少8的整数,n是C n H 2n-10中的至少10的整数 。 加氢分解聚合物可以进料到催化裂化器中以开裂裂化产物。
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公开(公告)号:US08460937B2
公开(公告)日:2013-06-11
申请号:US13431964
申请日:2012-03-27
CPC分类号: B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要: A method of screening catalysts for liquid-phase selective hydrogenation by preparing a test catalyst by adding a promoter to a reference catalyst; preparing a liquid reactant stream comprising C2H2 dissolved in n-methyl-2-pyrrolidone; testing the test and reference catalysts by contacting the reactant stream and gas mixture comprising hydrogen and carbon monoxide in continuous flow with the test catalyst and reference catalyst, respectively, at selective hydrogenation reaction conditions to produce a product stream, condensing substantially all of the n-methyl-2-pyrrolidone from the product stream; measuring the concentrations of products comprising C2H2, C2H4, and C2H6 in the product stream at steady state; determining performance parameters for the test catalyst and the reference catalyst comprising the respective C2H2 conversion Sc and C2H4 selectivity relative to C2H6 Ss; and comparing the test catalyst performance parameters to those for the reference catalyst.
摘要翻译: 一种筛选用于液相选择性氢化的催化剂的方法,通过向参考催化剂中加入助催化剂制备试验催化剂; 制备包含溶解在正甲基-2-吡咯烷酮中的C2H2的液体反应物流; 通过在选择性氢化反应条件下分别使包含氢气和一氧化碳的反应物流和连续流动的气体混合物与测试催化剂和参考催化剂分别接触来测试测试和参考催化剂,以产生产物流,基本上将所有的n- 甲基-2-吡咯烷酮; 在稳定状态下测量产物流中包含C2H2,C2H4和C2H6的产物的浓度; 确定测试催化剂和参考催化剂的性能参数,其包含相对于C 2 H 6 S的相应的C 2 H 2转化率Sc和C 2 H 4选择性; 并将试验催化剂性能参数与参考催化剂的参数进行比较。
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公开(公告)号:US08247340B2
公开(公告)日:2012-08-21
申请号:US13045346
申请日:2011-03-10
CPC分类号: B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要: A composition and method for preparation of a catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a Group VIII metal and a Group IB, Group IIB, Group IIIA, and/or Group VIIB promoter on a particulate support.
摘要翻译: 一种用于制备用于相对于烷烃对烯烃具有高选择性的炔烃至烯烃的液相选择性氢化的催化剂的组合物和方法,具有高炔烃转化率和持续催化活性的组合物和方法,其包含VIII族金属和IB族,IIB族, IIIA和/或VIIB族促进剂。
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公开(公告)号:US20120190117A1
公开(公告)日:2012-07-26
申请号:US13431964
申请日:2012-03-27
CPC分类号: B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要: A method of screening catalysts for liquid-phase selective hydrogenation by preparing a test catalyst by adding a promoter to a reference catalyst; preparing a liquid reactant stream comprising C2H2 dissolved in n-methyl-2-pyrrolidone; testing the test and reference catalysts by contacting the reactant stream and gas mixture comprising hydrogen and carbon monoxide in continuous flow with the test catalyst and reference catalyst, respectively, at selective hydrogenation reaction conditions to produce a product stream, condensing substantially all of the n-methyl-2-pyrrolidone from the product stream; measuring the concentrations of products comprising C2H2, C2H4, and C2H6 in the product stream at steady state; determining performance parameters for the test catalyst and the reference catalyst comprising the respective C2H2 conversion Sc and C2H4 selectivity relative to C2H6 Ss; and comparing the test catalyst performance parameters to those for the reference catalyst.
摘要翻译: 一种筛选用于液相选择性氢化的催化剂的方法,通过向参考催化剂中加入助催化剂制备试验催化剂; 制备包含溶解在正甲基-2-吡咯烷酮中的C2H2的液体反应物流; 通过在选择性氢化反应条件下分别使包含氢气和一氧化碳的反应物流和连续流动的气体混合物与测试催化剂和参考催化剂分别接触来测试测试和参考催化剂,以产生产物流,基本上将所有的n- 甲基-2-吡咯烷酮; 在稳定状态下测量产物流中包含C2H2,C2H4和C2H6的产物的浓度; 确定测试催化剂和参考催化剂的性能参数,其包含相对于C 2 H 6 S的相应的C 2 H 2转化率Sc和C 2 H 4选择性; 并将试验催化剂性能参数与参考催化剂的参数进行比较。
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公开(公告)号:US07955576B2
公开(公告)日:2011-06-07
申请号:US12335713
申请日:2008-12-16
IPC分类号: B01D47/00
CPC分类号: B01J20/08 , B01D53/8665 , B01D2251/102 , B01D2255/20723 , B01D2255/9202 , B01D2257/60 , B01D2257/602 , B01D2258/0291 , B01J20/02 , B01J20/103 , B01J20/106 , B01J20/12 , B01J20/18 , B01J20/3078 , B01J20/3234 , B01J20/3236 , B01J35/006
摘要: A composition, containing vanadium and a support, wherein at least a portion of the vanadium has crystallite sizes of less than about 100 Å as determined by an analytical method such as X-Ray Diffraction, is disclosed. A method of preparing such composition is also disclosed. The composition is employed in a process to remove a heavy metal from a gaseous feed stream which can optionally include a separate mercury adsorption stage.
摘要翻译: 含有钒和载体的组合物,其中至少一部分钒具有通过诸如X射线衍射之类的分析方法测定的小于约的微晶尺寸。 还公开了制备这种组合物的方法。 该组合物用于从气态进料流中除去重金属的方法,其可任选地包括单独的汞吸附阶段。
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公开(公告)号:US07919431B2
公开(公告)日:2011-04-05
申请号:US10727919
申请日:2003-12-04
CPC分类号: B01J23/50 , B01J23/44 , B01J23/48 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/002 , B01J37/0036 , B01J37/009 , B01J37/0205 , B01J37/18 , C10G45/34 , C10G45/40 , C10G2400/20
摘要: A composition and method for preparation of a catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a Group VIII metal and a Group IB, Group IIB, Group IIIA, and/or Group VIIB promoter on a particulate support.
摘要翻译: 一种用于制备用于相对于烷烃对烯烃具有高选择性的炔烃至烯烃的液相选择性氢化的催化剂的组合物和方法,具有高炔烃转化率和持续催化活性的组合物和方法,其包含VIII族金属和IB族,IIB族, IIIA和/或VIIB族促进剂。
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公开(公告)号:US20100196263A1
公开(公告)日:2010-08-05
申请号:US12689127
申请日:2010-01-18
CPC分类号: C01B39/026 , B01J29/084
摘要: Compositions and methods for preparing mesoporous materials from low Si/Al ratio zeolites. Such compositions can be prepared by acid wash and/or isomorphic substitution pretreatment of low Si/Al ratio zeolites prior to introduction of mesoporosity.
摘要翻译: 低Si / Al比沸石制备介孔材料的组合物和方法。 这种组合物可以在引入中孔隙之前通过酸洗和/或同构取代预处理低Si / Al比沸石来制备。
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公开(公告)号:US07585487B2
公开(公告)日:2009-09-08
申请号:US10735557
申请日:2003-12-12
IPC分类号: C01G31/02
CPC分类号: B01J20/08 , B01D53/8665 , B01D2251/102 , B01D2255/20723 , B01D2255/9202 , B01D2257/60 , B01D2257/602 , B01D2258/0291 , B01J20/02 , B01J20/103 , B01J20/106 , B01J20/12 , B01J20/18 , B01J20/3078 , B01J20/3234 , B01J20/3236 , B01J35/006
摘要: A composition, containing vanadium and a support, wherein at least a portion of the vanadium has crystallite sizes of less than about 100 Å as determined by an analytical method such as X-Ray Diffraction, is disclosed. A method of preparing such composition is also disclosed. The composition is employed in a process to remove a heavy metal from a gaseous feed stream which can optionally include a separate mercury adsorption stage.
摘要翻译: 含有钒和载体的组合物,其中至少一部分钒具有通过诸如X射线衍射之类的分析方法测定的小于约的微晶尺寸。 还公开了制备这种组合物的方法。 该组合物用于从气态进料流中除去重金属的方法,其可任选地包括单独的汞吸附阶段。
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9.
公开(公告)号:US20090110631A1
公开(公告)日:2009-04-30
申请号:US12009894
申请日:2008-01-23
IPC分类号: C01B39/02
CPC分类号: C01B39/026 , B01D11/0203 , B01D11/0288
摘要: The invention provides methods of recovering a pore-forming agent from an inorganic material that defines a plurality of mesopores having a controlled cross sectional area to form a mesostructure having long-range crystallinity and also to methods of making one or more mesostructures that features removal, recovery, and/or reuse of the pore-forming agent. Suitable pore-forming agents include, for example, surfactants.
摘要翻译: 本发明提供从限定具有受控横截面积的多个介孔的无机材料回收成孔剂的方法,以形成具有远程结晶度的介观结构,以及制备一种或多种特征为除去的介孔结构的方法, 回收和/或再利用。 合适的成孔剂包括例如表面活性剂。
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公开(公告)号:US20080300437A1
公开(公告)日:2008-12-04
申请号:US12114088
申请日:2008-05-02
IPC分类号: C07C5/05 , B01J23/08 , B01J23/44 , B01J23/48 , B01J23/06 , B01J23/70 , B01J23/80 , B01J23/825 , B01J27/10 , B01J27/25 , B01J23/34
CPC分类号: B01J37/08 , B01J21/04 , B01J23/44 , B01J23/50 , B01J23/52 , B01J23/60 , B01J23/62 , B01J23/6562 , B01J23/66 , B01J35/008 , B01J35/08 , B01J37/18 , C07C7/167 , C07C2523/56 , C07C2523/60 , C07C2523/62 , C07C2523/64
摘要: A process and catalyst for the liquid phase selective hydrogenation of alkynes to alkenes with high selectivity to alkenes relative to alkanes, high alkyne conversion, and sustained catalytic activity comprising a reactant comprising an alkyne and a non-hydrocarbon solvent/absorbent, contacting the reactant stream with a hydrogen-containing stream in the presence of a supported, promoted, Group VIII catalyst, removing the solvent/absorbent, and recovering the alkene product.
摘要翻译: 一种用于相对于烷烃对烯烃具有高选择性的烯烃至烯烃的液相选择性氢化的方法和催化剂,高炔转化率和持续的催化活性,其包含含有炔烃和非烃溶剂/吸收剂的反应物,使反应物流 在含有载体的促进的VIII族催化剂的存在下,将含氢的物流除去溶剂/吸收剂,并回收烯烃产物。
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