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1.发明申请SATURATED AND UNSATURATED SILAHYDROCARBONS VIA IRON AND COBALT PYRIDINE DIIMINE CATALYZED OLEFIN SILYLATION 有权饱和和不饱和硅烷通过铁和钴吡啶二胺催化烯烃硅酸盐公开(公告)号：US20140330036A1
公开(公告)日：2014-11-06
申请号：US14243044
申请日：2014-04-02
申请人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G.P. Delis , Aroop Kumar Roy
发明人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G.P. Delis , Aroop Kumar Roy
IPC分类号： C07F7/08
CPC分类号： C07F7/0829 , C07F7/0805 , C07F7/0896 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065
摘要： The present invention relates to processes for the synthesis of saturated and unsaturated silahydrocarbons using iron-containing or cobalt-containing catalysts. The processes of the invention can produce tetraalkylsilanes, phenyltrialkylsilanes, substituted phenyltrialkylsilanes and their mixtures, which are useful as lubricants and hydraulic fluids, as well as alkyl alkenylsilanes, phenyl alkenylsilanes and substituted phenyl alkenylsilanes and their mixtures, which are useful in the synthesis of saturated silahydrocarbons and other organofunctional silanes.
摘要翻译： 本发明涉及使用含铁或含钴催化剂合成饱和和不饱和硅烷烃的方法。 本发明的方法可以生产四烷基硅烷，苯基三烷基硅烷，取代的苯基三烷基硅烷及其混合物，其可用作润滑剂和液压流体，以及烷基烯基硅烷，苯基烯基硅烷和取代的苯基烯基硅烷及其混合物，其可用于合成饱和 硅烷烃等有机官能硅烷。
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2.发明申请REUSABLE HOMOGENEOUS COBALT PYRIDINE DIIMINE CATALYSTS FOR DEHYDROGENATIVE SILYLATION AND TANDEM DEHYDROGENATIVE-SILYLATION-HYDROGENATION 有权用于去离子硅烷化和均聚脱氢硅烷化加氢反应的均匀的均匀的钴盐酸二丁酯催化剂公开(公告)号：US20140243486A1
公开(公告)日：2014-08-28
申请号：US14270710
申请日：2014-05-06
申请人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G.P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
发明人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G.P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
CPC分类号： C07F7/1876 , B01J31/1815 , B01J2231/323 , B01J2531/0241 , B01J2531/0244 , B01J2531/845 , C07F7/0829 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F15/065 , C08G77/12 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/14
摘要： Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient, reusable, and selective dehydrogenative silylation, crosslinking, and tandem dehydrogenative silylation-hydrogenation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的钴配合物及其作为有效，可重复使用和选择性脱氢甲硅烷基化，交联和串联脱氢甲硅烷基化氢化催化剂的用途。
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3.发明授权Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation 有权饱和和不饱和硅烃通过铁和钴吡啶二亚胺催化烯烃甲硅烷基化公开(公告)号：US09371339B2
公开(公告)日：2016-06-21
申请号：US14243044
申请日：2014-04-02
申请人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G. P. Delis , Aroop Kumar Roy
发明人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G. P. Delis , Aroop Kumar Roy
CPC分类号： C07F7/0829 , C07F7/0805 , C07F7/0896 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065
摘要： The present invention relates to processes for the synthesis of saturated and unsaturated silahydrocarbons using iron-containing or cobalt-containing catalysts. The processes of the invention can produce tetraalkylsilanes, phenyltrialkylsilanes, substituted phenyltrialkylsilanes and their mixtures, which are useful as lubricants and hydraulic fluids, as well as alkyl alkenylsilanes, phenyl alkenylsilanes and substituted phenyl alkenylsilanes and their mixtures, which are useful in the synthesis of saturated silahydrocarbons and other organofunctional silanes.
摘要翻译： 本发明涉及使用含铁或含钴催化剂合成饱和和不饱和硅烷烃的方法。 本发明的方法可以生产四烷基硅烷，苯基三烷基硅烷，取代的苯基三烷基硅烷及其混合物，其可用作润滑剂和液压流体，以及烷基烯基硅烷，苯基烯基硅烷和取代的苯基烯基硅烷及其混合物，其可用于合成饱和 硅烷烃等有机官能硅烷。
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4.发明申请SELECTIVE 1,2-HYDROSILYLATION OF TERMINALLY UNSATURATED 1,3-DIENES USING IRON CATALYSTS 有权使用铁催化剂的终端不饱和1,3-二氧化物的选择性1,2-脱氢公开(公告)号：US20140330024A1
公开(公告)日：2014-11-06
申请号：US14270661
申请日：2014-05-06
申请人： Crisita Carmen Hojilla Atienza , Aroop Kumar Roy , Paul J. Chirik , Keith J. Weller , Johannes G.P. Delis , Tianning Diao
发明人： Crisita Carmen Hojilla Atienza , Aroop Kumar Roy , Paul J. Chirik , Keith J. Weller , Johannes G.P. Delis , Tianning Diao
IPC分类号： C07F7/08
CPC分类号： C07F7/0812 , B01J31/1815 , B01J2231/323 , B01J2531/0216 , B01J2531/0244 , B01J2531/842 , C07F7/0803
摘要： The present invention is directed to a selective and efficient process for the hydrosilylation of compounds containing terminally unsaturated 1,3-dienes using iron-based hydrosilylation catalysts. The resulting 1,2-addition products are useful as precursors for various silicone materials or silane- or silyl/silicone-functionalized polyolefins.
摘要翻译： 本发明涉及使用铁基氢化硅烷化催化剂对含有末端不饱和1,3-二烯的化合物进行氢化硅烷化的选择性和有效的方法。 所得1,2-加成产物可用作各种有机硅材料或硅烷或甲硅烷基/硅氧烷官能化聚烯烃的前体。
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5.发明授权Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation 有权用于脱氢甲硅烷基化和串联脱氢甲硅烷基化氢化的可重复使用的均匀的钴吡啶二亚胺催化剂公开(公告)号：US09447125B2
公开(公告)日：2016-09-20
申请号：US14270710
申请日：2014-05-06
申请人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G. P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
发明人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G. P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
IPC分类号： C08G77/06 , C07F7/18 , C07F7/08 , C08G77/38 , B01J31/18 , C07F15/06 , C08L83/04 , C08L83/14 , C08G77/04 , C08G77/12 , C08G77/20
CPC分类号： C07F7/1876 , B01J31/1815 , B01J2231/323 , B01J2531/0241 , B01J2531/0244 , B01J2531/845 , C07F7/0829 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F15/065 , C08G77/12 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/14
摘要： Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient, reusable, and selective dehydrogenative silylation, crosslinking, and tandem dehydrogenative silylation-hydrogenation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的钴配合物及其作为有效，可重复使用和选择性脱氢甲硅烷基化，交联和串联脱氢甲硅烷基化氢化催化剂的用途。
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