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1.发明申请REUSABLE HOMOGENEOUS COBALT PYRIDINE DIIMINE CATALYSTS FOR DEHYDROGENATIVE SILYLATION AND TANDEM DEHYDROGENATIVE-SILYLATION-HYDROGENATION 有权用于去离子硅烷化和均聚脱氢硅烷化加氢反应的均匀的均匀的钴盐酸二丁酯催化剂公开(公告)号：US20140243486A1
公开(公告)日：2014-08-28
申请号：US14270710
申请日：2014-05-06
申请人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G.P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
发明人： Aroop Kumar Roy , Crisita Carmen Hojilla Atienza , Paul J. Chirik , Kenrick M. Lewis , Keith J. Weller , Susan Nye , Johannes G.P. Delis , Julie L. Boyer , Tianning Diao , Eric Pohl
CPC分类号： C07F7/1876 , B01J31/1815 , B01J2231/323 , B01J2531/0241 , B01J2531/0244 , B01J2531/845 , C07F7/0829 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F15/065 , C08G77/12 , C08G77/20 , C08G77/38 , C08L83/04 , C08L83/14
摘要： Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient, reusable, and selective dehydrogenative silylation, crosslinking, and tandem dehydrogenative silylation-hydrogenation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的钴配合物及其作为有效，可重复使用和选择性脱氢甲硅烷基化，交联和串联脱氢甲硅烷基化氢化催化剂的用途。
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2.发明申请SELECTIVE 1,2-HYDROSILYLATION OF TERMINALLY UNSATURATED 1,3-DIENES USING IRON CATALYSTS 有权使用铁催化剂的终端不饱和1,3-二氧化物的选择性1,2-脱氢公开(公告)号：US20140330024A1
公开(公告)日：2014-11-06
申请号：US14270661
申请日：2014-05-06
申请人： Crisita Carmen Hojilla Atienza , Aroop Kumar Roy , Paul J. Chirik , Keith J. Weller , Johannes G.P. Delis , Tianning Diao
发明人： Crisita Carmen Hojilla Atienza , Aroop Kumar Roy , Paul J. Chirik , Keith J. Weller , Johannes G.P. Delis , Tianning Diao
IPC分类号： C07F7/08
CPC分类号： C07F7/0812 , B01J31/1815 , B01J2231/323 , B01J2531/0216 , B01J2531/0244 , B01J2531/842 , C07F7/0803
摘要： The present invention is directed to a selective and efficient process for the hydrosilylation of compounds containing terminally unsaturated 1,3-dienes using iron-based hydrosilylation catalysts. The resulting 1,2-addition products are useful as precursors for various silicone materials or silane- or silyl/silicone-functionalized polyolefins.
摘要翻译： 本发明涉及使用铁基氢化硅烷化催化剂对含有末端不饱和1,3-二烯的化合物进行氢化硅烷化的选择性和有效的方法。 所得1,2-加成产物可用作各种有机硅材料或硅烷或甲硅烷基/硅氧烷官能化聚烯烃的前体。
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3.发明申请SATURATED AND UNSATURATED SILAHYDROCARBONS VIA IRON AND COBALT PYRIDINE DIIMINE CATALYZED OLEFIN SILYLATION 有权饱和和不饱和硅烷通过铁和钴吡啶二胺催化烯烃硅酸盐公开(公告)号：US20140330036A1
公开(公告)日：2014-11-06
申请号：US14243044
申请日：2014-04-02
申请人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G.P. Delis , Aroop Kumar Roy
发明人： Kenrick Martin Lewis , Crisita Carmen Hojilla Atienza , Julie L. Boyer , Paul J. Chirik , Johannes G.P. Delis , Aroop Kumar Roy
IPC分类号： C07F7/08
CPC分类号： C07F7/0829 , C07F7/0805 , C07F7/0896 , C07F15/02 , C07F15/025 , C07F15/06 , C07F15/065
摘要： The present invention relates to processes for the synthesis of saturated and unsaturated silahydrocarbons using iron-containing or cobalt-containing catalysts. The processes of the invention can produce tetraalkylsilanes, phenyltrialkylsilanes, substituted phenyltrialkylsilanes and their mixtures, which are useful as lubricants and hydraulic fluids, as well as alkyl alkenylsilanes, phenyl alkenylsilanes and substituted phenyl alkenylsilanes and their mixtures, which are useful in the synthesis of saturated silahydrocarbons and other organofunctional silanes.
摘要翻译： 本发明涉及使用含铁或含钴催化剂合成饱和和不饱和硅烷烃的方法。 本发明的方法可以生产四烷基硅烷，苯基三烷基硅烷，取代的苯基三烷基硅烷及其混合物，其可用作润滑剂和液压流体，以及烷基烯基硅烷，苯基烯基硅烷和取代的苯基烯基硅烷及其混合物，其可用于合成饱和 硅烷烃等有机官能硅烷。
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4.发明申请COBALT CATALYSTS AND THEIR USE FOR HYDROSILYLATION AND DEHYDROGENATIVE SILYLATION 有权钴催化剂及其用于氢化和脱氢硅烷的使用公开(公告)号：US20150137033A1
公开(公告)日：2015-05-21
申请号：US14547641
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G.P. Delis , Renyuan Yu
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Keith J. Weller , Johannes G.P. Delis , Renyuan Yu
CPC分类号： B01J31/2295 , B01J2231/14 , B01J2231/323 , B01J2231/766 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08G81/02
摘要： Disclosed herein are cobalt complexes containing pyridine di-imine ligands and chelating alkenyl-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有吡啶二亚胺配体和螯合烯基 - 修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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5.发明申请COBALT CATALYSTS AND THEIR USE FOR HYDROSILYLATION AND DEHYDROGENATIVE SILYLATION 有权钴催化剂及其用于氢化和脱氢硅烷的使用公开(公告)号：US20150141647A1
公开(公告)日：2015-05-21
申请号：US14547661
申请日：2014-11-19
申请人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Johannes G.P. Delis , Keith J. Weller
发明人： Tianning Diao , Paul J. Chirik , Aroop Kumar Roy , Kenrick Lewis , Susan Nye , Johannes G.P. Delis , Keith J. Weller
CPC分类号： B01J31/2295 , B01J2231/323 , B01J2531/845 , C07F7/0838 , C07F7/0879 , C07F7/1804 , C07F7/1876 , C07F15/06 , C07F15/065 , C08J3/24 , C08J2383/04
摘要： Disclosed herein are cobalt complexes containing terpyridine ligands and chelating alkene-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.
摘要翻译： 本文公开了含有三联吡啶配体和螯合烯烃修饰的甲硅烷基配体的钴络合物，以及它们作为氢化硅烷化和/或脱氢甲硅烷基化和交联催化剂的用途。 钴配合物还表现出足够的空气稳定性用于处理和操作。
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6.发明申请SELECTIVE NON-PRECIOUS METAL-CATALYZED MONO-HYDROSILYLATION OF POLYUNSATURATED COMPOUNDS 有权选择性非金属金属催化的聚氧化复合化合物的单羟基化公开(公告)号：US20120130105A1
公开(公告)日：2012-05-24
申请号：US13302506
申请日：2011-11-22
申请人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G.P. Delis , Susan A. Nye , Paul J. Chirik
发明人： Kenrick M. Lewis , Aaron M. Tondreau , Richard W. Cruse , Keith J. Weller , Johannes G.P. Delis , Susan A. Nye , Paul J. Chirik
CPC分类号： C07F15/025 , B01J31/1805
摘要： Disclosed herein is the selective synthesis of mono-hydrosilylated derivatives of polyunsaturated compounds, such as trivinylcyclohexane using non-precious metal based pyridinediimine and terpyridine complex as selective hydrosilylation catalysts.
摘要翻译： 本文公开了多不饱和化合物的单氢化硅烷化衍生物的选择性合成，例如使用非贵金属的吡啶二亚胺和三联吡啶络合物作为选择性氢化硅烷化催化剂的三乙烯基环己烷。
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7.发明申请IN-SITU ACTIVATION OF METAL COMPLEXES CONTAINING TERDENTATE NITROGEN LIGANDS USED AS HYDROSILYLATION CATALYSTS 有权含有作为氢化催化剂的硫酸氮配体的金属络合物的原位活化公开(公告)号：US20120130106A1
公开(公告)日：2012-05-24
申请号：US13302236
申请日：2011-11-22
申请人： Paul J. Chirik , Aaron M. Tondreau , Johannes G.P. Delis , Kenrick M. Lewis , Keith J. Weller , Susan A. Nye
发明人： Paul J. Chirik , Aaron M. Tondreau , Johannes G.P. Delis , Kenrick M. Lewis , Keith J. Weller , Susan A. Nye
IPC分类号： C07F7/08
CPC分类号： C07F7/0879 , C07F7/0838
摘要： Disclosed herein is a process for the hydrosilylation of a composition containing a silyl hydride and a compound containing at least one unsaturated group, the process comprising contacting a non-previous metal based complex as a catalyst precursor with an activator being a reducing agent shortly before, simultaneously or after contacting the complex with the composition, to cause the silyl hydride to react with the compound containing at least one unsaturated group to produce a hydrosilylation product.
摘要翻译： 本文公开了含有甲硅烷基氢化物和含有至少一个不饱和基团的化合物的组合物的氢化硅烷化方法，该方法包括使非先前的作为催化剂前体的金属络合物与不久之前的还原剂的活化剂接触， 同时或使复合物与组合物接触后，使甲硅烷基氢化物与含有至少一个不饱和基团的化合物反应产生氢化硅烷化产物。
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8.发明申请NON-PRECIOUS METAL-CONTAINING 2,8-BIS(IMINO)QUINOLINE COMPLEXES AND THEIR USE AS HYDROSILYLATION CATALYSTS 有权非金属含金属2,8位（IMINO）喹啉配合物及其作为氢化催化剂的用途公开(公告)号：US20120130021A1
公开(公告)日：2012-05-24
申请号：US13302448
申请日：2011-11-22
申请人： Aaron M. Tondreau , Paul J. Chirik , Johannes G.P. Delis , Keith J. Weller , Kenrick M. Lewis , Susan A. Nye
发明人： Aaron M. Tondreau , Paul J. Chirik , Johannes G.P. Delis , Keith J. Weller , Kenrick M. Lewis , Susan A. Nye
CPC分类号： C07F15/025 , C07F7/0829 , C07F7/0879
摘要： Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.
摘要翻译： 本文公开了含有2,8-双（亚氨基）喹啉配体的锰，铁，钴或镍络合物及其作为氢化硅烷化反应的催化剂或催化剂前体的用途。
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公开(公告)号：US20110009573A1
公开(公告)日：2011-01-13
申请号：US12832627
申请日：2010-07-08
申请人： Johannes G.P. Delis , Susan A. Nye , Kenrick M. Lewis , Keith J. Weller , Paul J. Chirik , Aaron M. Tondreau , Sarah Kathleen Russell
发明人： Johannes G.P. Delis , Susan A. Nye , Kenrick M. Lewis , Keith J. Weller , Paul J. Chirik , Aaron M. Tondreau , Sarah Kathleen Russell
CPC分类号： C07F7/1876 , C07B2200/11 , C07F15/02
摘要： Disclosed herein are manganese, iron, cobalt, or nickel complexes containing terdentate pyridine diimine ligands and their use as efficient and selective hydrosilylation catalysts.
摘要翻译： 本文公开了含有三齿吡啶二亚胺配体的锰，铁，钴或镍配合物及其作为有效和选择性氢化硅烷化催化剂的用途。
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公开(公告)号：US20110009565A1
公开(公告)日：2011-01-13
申请号：US12832533
申请日：2010-07-08
CPC分类号： C07F7/0829 , B01J31/1815 , B01J2231/323 , B01J2531/0238 , B01J2531/72 , B01J2531/842 , B01J2531/847 , C07F7/0879 , C07F7/16 , C07F15/02 , C07F15/04 , C07F15/06
摘要： Disclosed herein are metal-terpyridine complexes and their use in hydrosilylation reactions.
摘要翻译： 本文公开了金属 - 三联吡啶络合物及其在氢化硅烷化反应中的用途。
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