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1.发明申请METHOD FOR PRODUCING STRUCTURE WHEREIN AROMATIC POLYMER IS BONDED TO BASE, STRUCTURE HAVING AROMATIC POLYMER CHAIN BONDED TO CONDUCTIVE BASE, AND ELECTRONIC DEVICE COMPRISING THE STRUCTURE 审中-公开用于生产结构的方法，其中芳族聚合物结合到基底，具有结合到导电基底的芳族聚合物链的结构，以及包含结构的电子装置公开(公告)号：US20100069603A1
公开(公告)日：2010-03-18
申请号：US12525132
申请日：2008-02-01
IPC分类号： C08G75/04
CPC分类号： C08G61/02 , C08G61/10 , C08G61/12 , C08G61/122 , C08G61/126 , C08G2261/411 , C08G2261/5222 , C08G2261/77 , C08G2261/91
摘要： Disclosed is a method for efficiently producing a structure wherein an aromatic polymer is bonded to a base. Also disclosed is such a structure wherein the base is electrically conductive. Specifically disclosed is a method for producing a structure, which comprises a step for polycondensing an aromatic compound represented by the formula (I) below in the presence of a polymerization catalyst and a base having a group represented by the formula (II) below. MYnAr—X (I) (In the formula (I), Ar represents a divalent group composed of an aromatic ring; X represents a halogen atom or the like; Y represents an oxygen atom, a sulfur atom, an imino group or the like; n represents 0 or 1; and M represents a hydrogen atom, —B(OQ1)2 (wherein Q1 represents a hydrogen atom, a hydrocarbon group or the like) or the like.) —Ara—(Xa)p (II) (In the formula (II), Ara represents a group having a valence of (p+1) and composed of an aromatic ring; Xa represents a halogen atom or a monovalent group expressed as —SO3Qa (wherein Qa represents a substituted or unsubstituted hydrocarbon group); p represents an integer not less than 1, and when p is an integer not less than 2, the plurality of Xa's may be the same as or different from each other.)
摘要翻译： 公开了一种有效地制备其中芳族聚合物与碱结合的结构的方法。 还公开了这样的结构，其中基底是导电的。 具体公开的是一种结构的制造方法，该方法包括在聚合催化剂和具有下述通式（II）所示基团的基团的存在下使由下式（I）表示的芳族化合物缩聚的步骤。 （I）（式（I）中，Ar表示由芳香环构成的二价基团，X表示卤素原子等，Y表示氧原子，硫原子，亚氨基 基团等; n表示0或1; M表示氢原子，-B（OQ1）2（其中Q1表示氢原子，烃基等）等。）-Ara-（Xa） p（II）（式（II）中，Ara表示具有（p + 1）价并且由芳香环构成的基团; Xa表示卤素原子或表示为-SO 3 Q a的一价基团（其中Qa表示 取代或未取代的烃基）; p表示1以上的整数，当p为2以上的整数时，多个X a可以相同也可以不同。
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公开(公告)号：US08349997B2
公开(公告)日：2013-01-08
申请号：US12526747
申请日：2008-02-14
IPC分类号： C08G75/00
CPC分类号： C08G61/126 , C08G61/02 , C08G61/12 , C08G61/124 , C08G2261/126 , C08G2261/312 , C08G2261/3142 , C08G2261/3162 , C08G2261/3221 , C08G2261/3223 , C08G2261/411 , C08G2261/417 , C09K11/06 , C09K2211/14 , H01L51/0039 , H01L51/0043
摘要： Disclosed is a method for producing a block copolymer which comprises two or more blocks composed of aromatic units having different basic structures from each other and has a high molecular weight, a narrow chain length distribution and a narrow molecular weight distribution. Also disclosed is a block copolymer produced by the method. The method for producing a block copolymer comprises the step of sequentially reacting two or more aromatic compounds which are selected from aromatic compounds represented by a specific general formula and are different in the group Ar, in the presence of a nickel complex containing a phosphine compound represented by a specific general formula or a palladium complex containing a phosphine compound represented by a specific general formula to thereby form blocks comprising the aromatic compounds sequentially, wherein the two or more aromatic compounds are reacted in descending order of parameter of aromatic ring charge.
摘要翻译： 公开了一种嵌段共聚物的制造方法，其包含两个以上由具有不同碱性结构的芳香族单元构成的嵌段，具有高分子量，窄链长分布和窄分子量分布。 还公开了通过该方法制备的嵌段共聚物。 嵌段共聚物的制造方法包括在含有表示的膦化合物的镍配合物的存在下，使两种以上选自由特定通式表示的芳香族化合物与Ar组不同的芳香族化合物反应的工序 通过具体通式或含有由特定通式表示的膦化合物的钯络合物，从而依次形成包含芳香族化合物的嵌段，其中两个或更多个芳香族化合物以芳环电荷参数的降序进行反应。
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公开(公告)号：US07999058B2
公开(公告)日：2011-08-16
申请号：US12278879
申请日：2007-02-13
CPC分类号： C08G61/10
摘要： A method for producing an aromatic polymer includes polycondensing an aromatic compound represented by formula (I) in the presence of a nickel complex containing a phosphine compound represented by formula (II), wherein, Ar denotes an aromatic ring containing organic group, which aromatic ring may contain an oxygen atom and/or a nitrogen atom; R denotes a monovalent group containing a hydrocarbon group; k is an integer of 1 or more; X denotes an halogen atom, a nitro group or a group represented by —SO3Q, wherein Q denotes a monovalent hydrocarbon group; Y denotes O, S, an imino group, an ethenylene group, or an ethynylene group; n denotes 0 or 1; and M denotes H, —B(OQ1)2, —Si(Q2)3, —Sn(Q3)3 or —Z1(Z2)m, wherein Q1 denotes H or a monovalent hydrocarbon group; Q2 and Q3 denote a monovalent hydrocarbon group; Z1 denotes a metal atom or a metal ion; Z2 denotes a counter ion; and m is an integer of 0 or higher; wherein, R1 denotes a monovalent hydrocarbon group, and R2 denotes a divalent hydrocarbon group.
摘要翻译： 一种芳族聚合物的制造方法，其特征在于，在含有式（II）表示的膦化合物的镍络合物的存在下，使由式（I）表示的芳香族化合物缩聚，其中，Ar表示含有有机基团的芳香环，该芳香环 可以含有氧原子和/或氮原子; R表示含有烃基的一价基团; k为1以上的整数， X表示卤原子，硝基或-SO 3 Q表示的基团，其中Q表示一价烃基; Y表示O，S，亚氨基，亚乙烯基或亚乙炔基; n表示0或1; M表示H，-B（OQ1）2，-Si（Q2）3，-Sn（Q3）3或-Z1（Z2）m，其中Q1表示H或一价烃基; Q2和Q3表示一价烃基; Z1表示金属原子或金属离子; Z2表示抗衡离子; m为0以上的整数。 其中，R1表示一价烃基，R2表示二价烃基。
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公开(公告)号：US09109081B2
公开(公告)日：2015-08-18
申请号：US11816195
申请日：2006-02-15
CPC分类号： C08G61/02 , B01J31/2295 , B01J31/24 , B01J2531/824 , C08G61/10 , C08G2261/312 , C08G2261/3142 , C08G2261/411
摘要： A method for producing an aromatic polymer comprising polycondensing an aromatic compound of the following formula (I) in the presence of a palladium complex containing a phosphine compound of the following formula (II): (wherein, Ar represents an aromatic ring-containing bi-functional organic group. X represents a halogen atom, nitro group or group of the formula —SO3Q (wherein, Q represents an optionally substituted hydrocarbon group). Y represents an oxygen atom, sulfur atom or the like, and n represents 0 or 1. M represents a hydrogen atom, —B(OQ1)2 or the like (Q1 represents a hydrogen atom or hydrocarbon group.) P(R1)3 (II) (wherein, R1 represents a group of the following formula (III) or a group of the following formula (IV) and three R1s may be the same or different, providing at least one of three R1s is a group of the following formula (III)) —C(R2)3 (III) (wherein, R2 represents a hydrogen atom or an optionally substituted hydrocarbon group) (wherein, R3 to R7 represent each independently a hydrogen atom, optionally substituted hydrocarbon group or the like).
摘要翻译： 一种芳香族聚合物的制造方法，其特征在于，在含有下述式（II）的膦化合物的钯络合物的存在下，使下式（I）的芳香族化合物缩聚：（式中，Ar表示含芳环的双 - X表示卤素原子，硝基或式-SO 3 Q基团（其中，Q表示任选取代的烃基），Y表示氧原子，硫原子等，n表示0或1。 M表示氢原子，-B（OQ1）2等（Q1表示氢原子或烃基）P（R1）3（Ⅱ）（式中，R1表示下式（III）的基团或 -C（R2）3（III）（其中，R2表示（R））表示的基团，可以相同或不同，提供三个R 1中的至少一个为下式（III） 氢原子或任选取代的烃基）（其中，R3至R 7独立地表示氢原子，任选取代的烃基等）。
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公开(公告)号：US20100168369A1
公开(公告)日：2010-07-01
申请号：US12278879
申请日：2007-02-13
CPC分类号： C08G61/10
摘要： A method for producing an aromatic polymer including polycondensing an aromatic compound represented by the following general formula (I) in the presence of a nickel complex containing a phosphine compound represented by the following general formula (II). (Wherein, Ar denotes an aromatic ring containing organic group having an aromatic ring which may contain an oxygen atom and/or a nitrogen atom; R denotes a monovalent group which contains a hydrocarbon group; k is an integer of 1 or more; X denotes an halogen atom, a nitro group or a group represented by —SO3Q (wherein Q denotes a monovalent hydrocarbon group); Y denotes O, S, an imino group, an ethenylene group, or an ethynylene group; n denotes 0 or 1; and M denotes H, —B(OQ1)2, —Si(Q2)3, —Sn(Q3)3 or —Z1(Z2)m (wherein Q1 denotes H or a monovalent hydrocarbon group; Q2 and Q3 denote a monovalent hydrocarbon group; Z1 denotes a metal atom or a metal ion; Z2 denotes a counter ion; and m is an integer of 0 or higher.)) (Wherein, R1 denotes a monovalent hydrocarbon group, and R2 denotes a divalent hydrocarbon group.)
摘要翻译： 一种芳香族聚合物的制造方法，其特征在于，在含有下述通式（II）表示的膦化合物的镍络合物的存在下，使由下述通式（I）表示的芳香族化合物缩聚。 （其中，Ar表示含有可具有氧原子和/或氮原子的芳香环的含有有机基团的芳香环，R表示含有烃基的一价基团，k表示1以上的整数，X表示 卤素原子，硝基或-SO 3 Q（其中Q表示一价烃基）表示的基团; Y表示O，S，亚氨基，亚乙烯基或亚乙炔基; n表示0或1;以及 M表示H，-B（OQ1）2，-Si（Q2）3，-Sn（Q3）3或-Z1（Z2）m（其中Q1表示H或一价烃基; Q2和Q3表示一价烃基 Z1表示金属原子或金属离子，Z2表示抗衡离子，m表示0以上的整数））（式中，R1表示一价烃基，R2表示二价烃基。
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公开(公告)号：US20100144999A1
公开(公告)日：2010-06-10
申请号：US11816195
申请日：2006-02-15
IPC分类号： C08G61/00
CPC分类号： C08G61/02 , B01J31/2295 , B01J31/24 , B01J2531/824 , C08G61/10 , C08G2261/312 , C08G2261/3142 , C08G2261/411
摘要： Disclosed is a method for producing an aromatic polymer characterized in that an aromatic compound represented by the formula (I) below is polycondensed in the presence of a palladium complex containing a phosphine compound represented by the formula (II) below. (I) (In the formula (I), Ar represents a bifunctional organic group containing an aromatic ring; X represents a halogen atom, a nitro group or a group expressed as —SO3Q (wherein Q is an optionally substituted hydrocarbon group); Y represents an oxygen atom, a sulfur atom or the like; n is 0 or 1; and M represents a hydrogen atom, a —B(OQ1)2 group (wherein Q1 is a hydrogen atom or a hydrocarbon group) or the like.) P(R1)3 (II) (In the formula (II), R1 represents a group represented by the formula (III) below or a group represented by the formula (IV) below, and three R1s may be the same as or different from one another, provided that at least one of R1s is a group represented by the formula (III) below.) —C(R2)3 (III) (In the formula (III), R2 represents a hydrogen atom or an optionally substituted hydrocarbon group.) (IV) (In the formula (IV), R3-R7 independently represent a hydrogen atom, an optionally substituted hydrocarbon group or the like.)
摘要翻译： 公开了一种芳族聚合物的制造方法，其特征在于，在下述式（II）表示的膦化合物的钯络合物的存在下，将下述式（I）表示的芳香族化合物进行缩聚。 （I）（式（I）中，Ar表示含有芳香环的双官能性有机基团，X表示卤素原子，硝基或-SO 3 Q表示的基团（Q表示可以具有取代基的烃基），Y表示 表示氧原子，硫原子等; n为0或1; M表示氢原子，-B（OQ1）2基（其中Q1为氢原子或烃基）等）。 P（R 1）3（II）（式（II）中，R 1表示由下式（III）表示的基团或下述式（IV）表示的基团，3个R 1可以相同或不同 前提条件是R 1中的至少一个是由下式（III）表示的基团）-C（R 2）3（III）（在式（III）中，R 2表示氢原子或任选取代的 烃基）（Ⅳ）（式（Ⅳ）中，R 3 -R 7分别表示氢原子，可以具有取代基的烃基等）。
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公开(公告)号：US20100099823A1
公开(公告)日：2010-04-22
申请号：US12526747
申请日：2008-02-14
IPC分类号： C08F297/00
CPC分类号： C08G61/126 , C08G61/02 , C08G61/12 , C08G61/124 , C08G2261/126 , C08G2261/312 , C08G2261/3142 , C08G2261/3162 , C08G2261/3221 , C08G2261/3223 , C08G2261/411 , C08G2261/417 , C09K11/06 , C09K2211/14 , H01L51/0039 , H01L51/0043
摘要： Disclosed is a method for producing a block copolymer which comprises two or more blocks composed of aromatic units having different basic structures from each other and has a high molecular weight, a narrow chain length distribution and a narrow molecular weight distribution. Also disclosed is a block copolymer produced by the method. The method for producing a block copolymer comprises the step of sequentially reacting two or more aromatic compounds which are selected from aromatic compounds represented by a specific general formula and are different in the group Ar, in the presence of a nickel complex containing a phosphine compound represented by a specific general formula or a palladium complex containing a phosphine compound represented by a specific general formula to thereby form blocks comprising the aromatic compounds sequentially, wherein the two or more aromatic compounds are reacted in descending order of parameter of aromatic ring charge.
摘要翻译： 公开了一种嵌段共聚物的制造方法，其包含两个以上由具有不同碱性结构的芳香族单元构成的嵌段，具有高分子量，窄链长分布和窄分子量分布。 还公开了通过该方法制备的嵌段共聚物。 嵌段共聚物的制造方法包括在含有表示的膦化合物的镍配合物的存在下，使两种以上选自由特定通式表示的芳香族化合物与Ar组不同的芳香族化合物反应的工序 通过具体通式或含有由特定通式表示的膦化合物的钯络合物，从而依次形成包含芳香族化合物的嵌段，其中两个或更多个芳香族化合物以芳环电荷参数的降序进行反应。
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8.发明授权Layered structure comprising a layer containing a conjugated polymer compound 有权包含含有共轭高分子化合物的层的层状结构公开(公告)号：US08951646B2
公开(公告)日：2015-02-10
申请号：US12921108
申请日：2009-03-05
CPC分类号： H01L51/0039 , C08G61/02 , C08G61/12 , C08G61/122 , C08G2261/124 , C08G2261/1426 , C08G2261/3142 , C08G2261/316 , C08G2261/3221 , C08G2261/5222 , C08G2261/80 , H01L51/5048 , Y02E10/549 , Y10S428/917
摘要： A layered structure including a first electrode and a second electrode, a light-emitting layer or a charge separation layer between the first electrode and the second electrode, and a layer containing a conjugated polymer compound between the light-emitting layer or the charge separation layer and the first electrode, wherein the conjugated polymer compound contains a repeating unit selected from the group consisting of a repeating unit of formula (1).
摘要翻译： 包括第一电极和第二电极的层状结构，在第一电极和第二电极之间的发光层或电荷分离层，以及在发光层或电荷分离层之间含有共轭高分子化合物的层 和第一电极，其中共轭高分子化合物含有选自式（1）的重复单元的重复单元。
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9.发明申请公开(公告)号：US20130099224A1
公开(公告)日：2013-04-25
申请号：US13807226
申请日：2011-06-24
CPC分类号： H01L51/5012 , C07D471/04 , C08G61/02 , C08G2261/1424 , C08G2261/1426 , C08G2261/149 , C08G2261/3142 , C08G2261/411 , C08G2261/412 , C08G2261/95 , H01L51/0002 , H01L51/0003 , H01L51/0037 , H01L51/0039 , H01L51/42 , H01L51/424 , H01L51/4253 , H01L51/5076 , H01L51/5092 , H05B33/22 , Y02E10/549 , Y02P70/521
摘要： Provided are a light-emitting device and a photovoltaic cell having excellent characteristics. A light-emitting device (10) includes a cathode (34), an anode (32), a light-emitting layer (50) interposed between the cathode (34) and the anode (32), and an electron injection layer (44) provided between the cathode (34) and the light-emitting layer (50) and connected to the cathode (34), in which at least one of the anode (32) and the cathode (34) contains a conductive material having an aspect ratio of 1.5 or more, and the electron injection layer (44) contains an organic compound having at least one of an ionic group and a polar group.
摘要翻译： 提供了具有优异特性的发光器件和光伏电池。 发光装置（10）包括阴极（34），阳极（32），介于阴极（34）和阳极（32）之间的发光层（50）和电子注入层（44） ）设置在阴极（34）和发光层（50）之间并连接到阴极（34），其中阳极（32）和阴极（34）中的至少一个包含具有一方面的导电材料 比例为1.5以上，电子注入层（44）含有具有离子性基团和极性基团中的至少一种的有机化合物。
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公开(公告)号：US20120032121A1
公开(公告)日：2012-02-09
申请号：US13263220
申请日：2010-04-06
IPC分类号： H01B1/22 , C07D471/04 , H05B33/26 , H01J40/04 , B82Y30/00
CPC分类号： H01B1/128 , B22F1/00 , B22F1/0025 , B22F1/0062 , B22F1/02 , B22F9/00 , B22F9/24 , B22F2999/00 , B82B1/00 , B82Y30/00 , C07F5/025 , C08G61/02 , C08G2261/1424 , C08G2261/1426 , C08G2261/143 , C08G2261/145 , C08G2261/149 , C08G2261/3142 , C08G2261/411 , C08G2261/51 , C08G2261/95 , C08G2261/964 , C08K3/08 , C08K2201/016 , C08L65/00 , C09D5/24 , H01L21/28 , H01L51/0039 , H01L51/0043 , H01L51/009 , H05B33/28 , Y02E10/549 , Y02P70/521 , B22F2301/255
摘要： A metallic composite in which a conjugated compound having a molecular weight of 200 or more is adsorbed to a metallic nanostructure having an aspect ratio of 1.5 or more, for example, a metallic composite in which a compound having a group represented by the formula (I) or a repeating unit represented by the formula (II) or both of them is adsorbed to a metallic nanostructure having an aspect ratio of 1.5 or more, is useful for electronic devices such as a light-emitting device, a solar cell and an organic transistor.
摘要翻译： 将分子量为200以上的共轭化合物吸附在纵横比为1.5以上的金属纳米结构体的金属复合体中，例如具有式（I）所示基团的化合物 ）或由式（II）表示的重复单元或它们两者都被吸收到纵横比为1.5以上的金属纳米结构体上，可用于发光元件，太阳能电池和有机物等电子器件 晶体管。
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