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公开(公告)号:US07175969B1
公开(公告)日:2007-02-13
申请号:US11488588
申请日:2006-07-18
申请人: Kevin B. Ray , Heidi M. Munnelly , Ting Tao , Kevin D. Wieland , Scott A. Beckley , Jianbing Huang
发明人: Kevin B. Ray , Heidi M. Munnelly , Ting Tao , Kevin D. Wieland , Scott A. Beckley , Jianbing Huang
CPC分类号: G03F7/0012 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/027 , G03F7/033 , Y10S430/106 , Y10S430/11 , Y10S430/165
摘要: A method of preparing negative-working, single-layer imageable elements improves their storage stability in a humid environment. The method includes enclosing the coated imageable elements in a water-impermeable sheet material that substantially inhibits the transfer of moisture to and from the imageable element. Such imageable elements include a radiation-sensitive composition that includes a radically polymerizable component, an initiator composition to provide radicals upon exposure to imaging radiation, a radiation absorbing compound, and a polymeric binder having poly(alkylene glycol) side chains.
摘要翻译: 制备负性,单层可成像元素的方法提高了其在潮湿环境中的储存稳定性。 该方法包括将涂覆的可成像元件封装在不透水的片材中,其基本上抑制湿气与可成像元件的转移。 这种可成像元件包括辐射敏感组合物,其包含可自由基聚合的组分,在暴露于成像辐射时提供自由基的引发剂组合物,辐射吸收化合物和具有聚(亚烷基二醇)侧链的聚合物粘合剂。
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公开(公告)号:US07172850B2
公开(公告)日:2007-02-06
申请号:US10891727
申请日:2004-07-15
申请人: Heidi M. Munnelly , Kevin B. Ray , Ting Tao , Shashikant Saraiya , Kouji Hayashi , Jianbing Huang
发明人: Heidi M. Munnelly , Kevin B. Ray , Ting Tao , Shashikant Saraiya , Kouji Hayashi , Jianbing Huang
IPC分类号: G03F7/028 , G03F7/033 , G03F7/09 , G03F7/00 , C08F220/44
CPC分类号: B41C1/1008 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41M5/368 , G03F7/0212 , G03F7/033 , Y10S430/111 , Y10S430/145
摘要: The present invention provides an imageable element including a lithographic substrate and an imageable layer disposed on the substrate. The imageable layer includes a radically polymerizable component, an initiator system capable of generating radicals sufficient to initiate a polymerization reaction upon exposure to imaging radiation, and a polymeric binder having a hydrophobic backbone and including both constitutional units having a pendant cyano group attached directly to the hydrophobic backbone, and constitutional units having a pendant group including a hydrophilic poly(alkylene oxide) segment. The invention also provides a method for preparing a suitable polymeric binder. The method comprises contacting a combination of co-monomers in a solvent mixture consisting essentially of a (C1–C6) alkanol and water.
摘要翻译: 本发明提供一种可成像元件,包括平版印刷基板和设置在基板上的可成像层。 可成像层包括可自由基聚合的组分,能够产生足以在暴露于成像辐射时引发聚合反应的自由基的引发剂体系,以及具有疏水骨架的聚合物粘合剂,并且包括具有氰基侧基的两个结构单元直接连接到 疏水骨架和具有包括亲水性聚(环氧烷)链段)侧基的结构单元。 本发明还提供了制备合适的聚合物粘合剂的方法。 该方法包括将基本上由(C 1 -C 12 -C 6)烷醇组成的溶剂混合物中的共聚单体的组合与水接触。
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公开(公告)号:US20090047599A1
公开(公告)日:2009-02-19
申请号:US11838935
申请日:2007-08-15
申请人: Geoffrey Horne , Kevin B. Ray , Elizabeth Knight , Jianbing Huang , Ting Tao , Heidi M. Munnelly
发明人: Geoffrey Horne , Kevin B. Ray , Elizabeth Knight , Jianbing Huang , Ting Tao , Heidi M. Munnelly
CPC分类号: G03F7/029 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/3035
摘要: A negative-working imageable element has an imageable layer that includes an initiator composition including an iodonium cation and a boron-containing anion at a molar ratio of at least 1.2:1, an infrared radiation absorbing compound, a primary polymeric binder, and a spirolactone or spirolactam colorant precursor. The imaged element exhibits improved print-out.
摘要翻译: 负性可成像元件具有可成像层,其包含摩尔比为至少1.2:1的包含碘鎓阳离子和含硼阴离子的引发剂组合物,红外辐射吸收化合物,初级聚合物粘合剂和螺内酯 或螺内酰胺着色剂前体。 成像元件显示出改进的打印输出。
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公开(公告)号:US06902861B2
公开(公告)日:2005-06-07
申请号:US10384989
申请日:2003-03-10
申请人: Ting Tao , Kevin B. Ray , Jianbing Huang , Jeffrey James Collins , Thomas Jordan , Scott A. Beckley
发明人: Ting Tao , Kevin B. Ray , Jianbing Huang , Jeffrey James Collins , Thomas Jordan , Scott A. Beckley
CPC分类号: B41M5/465 , B41C1/1008 , B41C1/1016 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/12 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41M5/368 , C09B23/0066 , C09B23/086 , Y10S430/145 , Y10S430/146
摘要: Infrared absorbing compounds in which the anion is selected from the group consisting of 5-isatinsulfonate, 10-camphorsulfonate, and 4,5-dihydroxy-1,3-benzenedisulfonate are disclosed. Negative-working imageable elements containing these compounds have improved dot stability.
摘要翻译: 公开了其中阴离子选自5-廿烷基磺酸盐,10-樟脑磺酸盐和4,5-二羟基-1,3-苯二磺酸盐的红外吸收化合物。 含有这些化合物的负性可成像元素具有改善的点稳定性。
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公开(公告)号:US07217502B2
公开(公告)日:2007-05-15
申请号:US11444740
申请日:2006-06-01
申请人: Kevin B. Ray , Jianbing Huang , Heidi M. Munnelly
发明人: Kevin B. Ray , Jianbing Huang , Heidi M. Munnelly
IPC分类号: G03C5/00
CPC分类号: B41C1/1008 , B41C2210/02 , B41C2210/04 , B41C2210/08 , B41C2210/20 , B41C2210/22 , B41C2210/24 , G03F1/68 , G03F7/0047 , G03G13/28 , G03G13/283 , G03G13/286
摘要: The present invention provides methods of imagewise exposing a thermally sensitive composition formed from a nanopaste comprising inorganic nanoparticles, a carrier, and preferably certain polymeric binders. The composition has been applied to a substrate and treated to improve adhesion. Exposure affects the solubility of exposed portions of the applied and treated layer relative to unexposed portions of the applied layer. The imaged layer is then developed on-press with a fountain solution, lithographic ink, or both, to remove the exposed portions or unexposed portions of the layer to form an image in a printing plate.
摘要翻译: 本发明提供了成像曝光由包含无机纳米颗粒,载体和优选某些聚合物粘合剂的纳米糊料形成的热敏组合物的方法。 将该组合物施用于基材并进行处理以提高粘合性。 暴露影响施加和处理的层相对于施加层的未曝光部分的暴露部分的溶解度。 然后,利用润版液,平版印刷油墨或两者在印刷机上显影成像层,以去除该层的曝光部分或未曝光部分,以在印版中形成图像。
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公开(公告)号:US07592128B2
公开(公告)日:2009-09-22
申请号:US11500261
申请日:2006-08-07
申请人: Jianbing Huang , Kevin B. Ray , Scott A. Beckley
发明人: Jianbing Huang , Kevin B. Ray , Scott A. Beckley
CPC分类号: B41C1/1008 , B41C2210/04 , B41C2210/08 , B41C2210/20 , B41C2210/22 , B41C2210/24 , B41M5/368 , G03C1/04 , G03C1/49863 , G03F7/0212 , G03F7/033 , Y10S430/106 , Y10S430/117 , Y10S430/126 , Y10S430/145
摘要: The present invention relates to negative-working imageable elements that can be used for the manufacture of printing plates. These imageable elements can be developed on on-press by the action of a lithographic printing ink used in combination with either water or a fountain solution. The imageable elements comprise an imageable layer that is not removable in water or fountain solution alone. The imageable layer includes a free radically polymerizable compound, a free radical initiator composition, an infrared radiation absorbing compound, and a polymeric binder comprising poly(alkylene oxide) pendant groups, and preferably additionally pendant cyano groups.
摘要翻译: 本发明涉及可用于制造印版的负性可成像元件。 这些可成像元件可以通过与水或润版液组合使用的平版印刷油墨的作用在印刷机上显影。 可成像元件包括不可在水或喷泉溶液中单独移除的可成像层。 可成像层包括可自由基聚合的化合物,自由基引发剂组合物,红外辐射吸收化合物和包含聚(环氧烷)侧基的聚合物粘合剂,优选另外悬挂氰基。
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公开(公告)号:US20100015549A1
公开(公告)日:2010-01-21
申请号:US12500637
申请日:2009-07-10
申请人: Jianbing Huang , Kevin B. Ray , Scott A. Beckley
发明人: Jianbing Huang , Kevin B. Ray , Scott A. Beckley
IPC分类号: G03F7/004
CPC分类号: B41C1/1008 , B41C2210/04 , B41C2210/08 , B41C2210/20 , B41C2210/22 , B41C2210/24 , B41M5/368 , G03C1/04 , G03C1/49863 , G03F7/0212 , G03F7/033 , Y10S430/106 , Y10S430/117 , Y10S430/126 , Y10S430/145
摘要: The present invention relates to negative-working imageable elements that can be used for the manufacture of printing plates. These imageable elements can be developed on on-press by the action of a lithographic printing ink used in combination with either water or a fountain solution. The imageable elements comprise an imageable layer that is not removable in water or fountain solution alone. The imageable layer includes a free radically polymerizable compound, a free radical initiator composition, an infrared radiation absorbing compound, and a polymeric binder comprising poly(alkylene oxide) pendant groups, and preferably additionally pendant cyano groups.
摘要翻译: 本发明涉及可用于制造印版的负性可成像元件。 这些可成像元件可以通过与水或润版液组合使用的平版印刷油墨的作用在印刷机上显影。 可成像元件包括不可在水或喷泉溶液中单独移除的可成像层。 可成像层包括可自由基聚合的化合物,自由基引发剂组合物,红外辐射吸收化合物和包含聚(环氧烷)侧基的聚合物粘合剂,优选另外悬挂氰基。
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公开(公告)号:US07326521B1
公开(公告)日:2008-02-05
申请号:US11513995
申请日:2006-08-31
申请人: Ting Tao , Kevin B. Ray , Scott A. Beckley , Paul R. West
发明人: Ting Tao , Kevin B. Ray , Scott A. Beckley , Paul R. West
CPC分类号: G03F7/322 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/10 , B41C2210/22 , B41C2210/24 , B41N3/06
摘要: Negative-working imageable elements can be imaged and then developed using a lower pH organic-based single-phase developer that is less toxic and corrosive and that can be more readily disposed of after use. This developer has a pH less than 12 and comprises a) an amphoteric surfactant comprising a nitrogen-containing heterocycle, b) an amphoteric surfactant having two or more nitrogen atoms, or c) an amphoteric surfactant of a) and an amphoteric surfactant of b).
摘要翻译: 负性工作的可成像元件可以成像,然后使用较低毒性和腐蚀性的较低pH的基于有机的单相显影剂显影,并且使用后可以更容易地处理。 该显影剂的pH小于12,包括a)包含含氮杂环的两性表面活性剂,b)具有两个或更多个氮原子的两性表面活性剂,或c)a)的两性表面活性剂和b)的两性表面活性剂, 。
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公开(公告)号:US07338745B2
公开(公告)日:2008-03-04
申请号:US11337776
申请日:2006-01-23
申请人: Kevin B. Ray , Ting Tao , Scott A. Beckley
发明人: Kevin B. Ray , Ting Tao , Scott A. Beckley
CPC分类号: B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262 , Y10S430/106 , Y10S430/111 , Y10S430/165
摘要: Positive-working imageable elements comprise a radiation absorbing compound and inner and outer layers on a substrate having a hydrophilic surface. The inner layer comprises a polymeric material that is removable using an alkaline developer and comprises a backbone and attached groups represented by the following Structure Q: wherein L1, L2, and L3 independently represent linking groups, T1, T2, and T3 independently represent terminal groups, and a, b, and c are independently 0 or 1. The imageable elements have improved resistance to development and printing chemicals and solvents.
摘要翻译: 正性可成像元件包括辐射吸收化合物和在具有亲水表面的基底上的内层和外层。 内层包含可使用碱性显影剂除去的聚合物材料,其包含由以下结构Q表示的骨架和连接基团:其中L 1,L 2,和 L 3独立地表示连接基团,T 1,T 2和T 3独立地表示连接基团,和 a,b和c独立地为0或1.可成像元件具有改善的耐显影和印刷化学品和溶剂的能力。
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公开(公告)号:US20100151385A1
公开(公告)日:2010-06-17
申请号:US12336635
申请日:2008-12-17
IPC分类号: G03F7/004
CPC分类号: B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24
摘要: A plurality of negative-working lithographic printing plate precursors is provided in a stack. Each precursor comprises an aluminum-containing substrate having thereon a single imageable layer and an outermost topcoat that has a dry coating weight equal to or less than 1 g/m2. The non-imaging backside of the substrate is free of polymer coatings and has an average surface roughness (Ra) in both longitudinal and width directions greater than 0.15 μm. In addition, the imageable side of each underlying precursor is arranged in direct contact with the aluminum-containing substrate of the precursor above it without the use of an interleaf paper between the precursors.
摘要翻译: 在堆叠中提供多个负性平版印刷版前体。 每个前体包括其上具有单一可成像层的铝含基材和具有等于或小于1g / m 2的干涂层重量的最外面漆。 衬底的非成像背面没有聚合物涂层,并且在纵向和宽度方向上的平均表面粗糙度(Ra)大于0.15μm。 此外,每个下面的前体的可成像侧布置成与其上方的前体的含铝基底直接接触,而不使用前体之间的中间纸。
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