Branched fluoropolymers
    4.
    发明申请
    Branched fluoropolymers 有权
    分支含氟聚合物

    公开(公告)号:US20070106010A1

    公开(公告)日:2007-05-10

    申请号:US11271057

    申请日:2005-11-10

    IPC分类号: D06M15/277 C08L27/12

    摘要: The invention relates to the preparation of branched fluoropolymers having long chain branches and little or no gels, by a process involving polymerization at high temperatures using persulfates and optionally multifunctional initiators. The invention also relates to gel-free, branched polymers with strain hardening produced by the process.

    摘要翻译: 本发明涉及通过使用过硫酸盐和任选的多官能引发剂在高温下聚合的方法制备具有长支链和很少或不含凝胶的支链含氟聚合物。 本发明还涉及通过该方法产生的具有应变硬化性的无凝胶的支化聚合物。

    POLYMERIZATION OF FLUOROPOLYMERS USING NON-FLUORINATED SURFACTANTS
    7.
    发明申请
    POLYMERIZATION OF FLUOROPOLYMERS USING NON-FLUORINATED SURFACTANTS 有权
    使用非氟化表面活性剂的氟聚合物的聚合

    公开(公告)号:US20090221776A1

    公开(公告)日:2009-09-03

    申请号:US11995593

    申请日:2006-06-26

    CPC分类号: C08F214/22 C08F14/18 C08F2/22

    摘要: The present invention relates to a method for the polymerization in an aqueous medium of monomers, and especially of fluoromonomers, using non-fluorinated surfactants; and the fluoropolymers formed therefrom. Specifically, the method of the polymerization uses one or more non-fluorinated surfactants selected from the group consisting of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid, and salts thereof. Additionally, the use of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid as surfactants in aqueous free radical polymerization is also novel.

    摘要翻译: 本发明涉及使用非氟化表面活性剂在单体,特别是含氟单体的水性介质中聚合的方法; 和由其形成的含氟聚合物。 具体地,聚合方法使用一种或多种选自聚乙烯基膦酸,聚丙烯酸,聚乙烯基磺酸及其盐的非氟化表面活性剂。 此外,在水性自由基聚合中使用聚乙烯基膦酸,聚丙烯酸,聚乙烯基磺酸作为表面活性剂也是新颖的。

    Polymerization of fluoropolymers using non-fluorinated surfactants
    10.
    发明授权
    Polymerization of fluoropolymers using non-fluorinated surfactants 有权
    使用非氟化表面活性剂聚合含氟聚合物

    公开(公告)号:US08697822B2

    公开(公告)日:2014-04-15

    申请号:US11995593

    申请日:2006-06-26

    IPC分类号: C08L27/16

    CPC分类号: C08F214/22 C08F14/18 C08F2/22

    摘要: The present invention relates to a method for the polymerization in an aqueous medium of monomers, and especially of fluoromonomers, using non-fluorinated surfactants; and the fluoropolymers formed therefrom. Specifically, the method of the polymerization uses one or more non-fluorinated surfactants selected from the group consisting of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid, and salts thereof. Additionally, the use of polyvinylphosphonic acid, polyacrylic acids, polyvinyl sulfonic acid as surfactants in aqueous free radical polymerization is also novel.

    摘要翻译: 本发明涉及使用非氟化表面活性剂在单体,特别是含氟单体的水性介质中聚合的方法; 和由其形成的含氟聚合物。 具体地,聚合方法使用一种或多种选自聚乙烯基膦酸,聚丙烯酸,聚乙烯基磺酸及其盐的非氟化表面活性剂。 此外,在水性自由基聚合中使用聚乙烯基膦酸,聚丙烯酸,聚乙烯基磺酸作为表面活性剂也是新颖的。