摘要:
Negative-working, IR-sensitive printing plates utilize a radiation-sensitive composition having a component polymerizable by a free-radical mechanism, at least part of which comprises or consists essentially of a non-particulate, aliphatic urethane acrylic oligomer that is infinitely water-dilutable but not water-soluble.
摘要:
Dry, ablation-type, nitrocellulose-containing lithographic printing members include dual adjacent imaging layers, both including an absorber and at least one containing a binder (which may include or consist essentially of a melamine resin). The absorber of the nitrocellulose-containing layer is a pigment and this layer contains no absorbing dye, while the absorber of the other imaging layer includes or consists essentially of a dye.
摘要:
The blanket cylinder of a printing press is used to remove oleophobic debris from an imaged dry printing member. Following imaging—e.g., imagewise exposure of the printing member to radiation that ablates the layer below the oleophobic layer, or de-anchors it from the oleophobic layer without ablation—the printing member is brought into rolling contact with the blanket cylinder, and the press is operated “on impression.” This rolling contact may remove not only the oleophobic top layer but ablation debris of the underlying imaging layer as well.
摘要:
A recording medium comprises an oleophilic substrate and, thereover, a topmost oleophobic layer comprising a cured polymeric silicone matrix that consists essentially of the addition-cure reaction product of a vinyl-functional polydialkylsiloxane and a silane cross-linking agent. The vinyl-functional polydialkylsiloxane has a molecular weight ranging from 30,000 to 75,000 or 110,000 to 130,000. If the molecular weight of the vinyl-functional polydialkylsiloxane is within the range of 30,000 to 75,000, the molar ratio of silane groups to vinyl groups is within the range of about 11:1 to about 25:1; and if the molecular weight of the vinyl-functional polydialkylsiloxane is within the range of 110,000 to 130,000, the molar ratio of silane groups to vinyl groups is from about 5:1 to about 27:1. The recording medium may be used as a lithographic printing plate.
摘要:
Ablation-type printing plates having increased shelf-life are produced using a melamine resin free of water prior to use. A representative production sequence includes providing a substrate having an oleophilic surface; coating, over the substrate, an oleophilic resin composition having (A) a resin phase consisting essentially of a melamine resin substantially free of water and a resole resin, the resole resin being present in an amount ranging from 0% to 28% by weight of dry film, (B) a near-IR absorber dispersed within the resin phase, and (C) a sulfonic acid catalyst dispersed within the resin phase and being present in an amount ranging from 0.7% to 1.6% by weight of dry film; curing the resin composition to produce a dry film; following resin curing, coating an oleophobic polymer composition over the cured resin composition; and curing the oleophobic polymer composition.
摘要:
In ablation-type printing plates involving silicone acrylate top layers, curing at high oxygen levels not only substantially reduces or eliminates toning, but does not adversely affect plate durability or printing performance.
摘要:
Gum solutions are formulated to protect a negative-working photopolymer imaging layer coated on an anodized aluminum substrate that has undergone a post-anodic sealing treatment with inorganic phosphate and inorganic fluoride, followed by development. In various embodiments, the developer and gum solution have different compositions but contain at least one polycarboxylic acid—which may be a polymer—that beneficially desensitizes the surface after the unexposed photopolymer layer is removed.
摘要:
Negative-working imagable elements can be imaged and then developed using a lower pH organic-based single-phase developer that is less toxic and corrosive and that can be more readily disposed of after use. This developer has a pH less than 12 and comprises a) an amphoteric surfactant comprising a nitrogen-containing heterocycle, b) an amphoteric surfactant having two or more nitrogen atoms, or c) an amphoteric surfactant of a) and an amphoteric surfactant of b).
摘要:
A game cartridge is described that retains a player's current holdings related to game play in a write-once memory. The cartridge thus becomes closely identified with the previous play of a player to simulate non-electronic collectable card or other status games. Further, some aspects of the invention allow for initialization of the player's holdings. In one embodiment of the present invention, the game cartridge provides an environment for playing a collectable card game, such as a POKÉMON™-type game, and the game cartridge remembers and can update the current holdings of electronic cards. The game cartridges of the present invention are collectable items in that they retain a current accounting of a player's holdings and can be traded among different players.
摘要:
Thermally imageable multilayer imageable elements useful as lithographic printing plate precursors that have good solvent resistance are disclosed. The underlayer of the imageable element comprises an acidic copolymer that comprises, in polymerized form, about 10 mol % to about 75 mol % of one or more monomers of the formula: CH2═CH(R1)-Z-X—NH—CO—NH—C6H3—(R2)(CO2H); in which: R1 is H or CH3; R2 is H or OH; Z is —C6H4— or —C(O) —Y—; Y is —O— or —NH—; and X is selected from —C(CH3)2—, —CH(CH3)— and —(CH2)n—, in which n is an integer from 1 to 12.