公开(公告)号：US4237143A

公开(公告)日：1980-12-02

申请号：US9564

申请日：1979-02-05

申请人： Klaus Grohe ,  Hans-Joachim Scholl ,  Volker Paul ,  Wilhelm Brandes ,  Paul-Ernst Frohberger

发明人： Klaus Grohe ,  Hans-Joachim Scholl ,  Volker Paul ,  Wilhelm Brandes ,  Paul-Ernst Frohberger

IPC分类号： A01N43/78 ,  A01N47/08 ,  C07D277/20 ,  C07D277/38 ,  C07D277/40 ,  C07D277/42 ,  C07D277/04

CPC分类号： C07D277/20 ,  A01N47/08

摘要： 2-Methylene-3-substituted-4,5-bis-trifluoromethylimino-thiazoldines of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted cycloalkyl, optionally substituted aryl, aralkyl, it being possible for the last-mentioned group to be substituted on the alkyl radical, or an amino group --NR.sup.4 R.sup.5, whereinR.sup.4 and R.sup.5 may be identical or different, each represent optionally substituted alkyl, or R.sup.4 and R.sup.5 together with the connecting nitrogen atom and optionally one or more further heteroatoms, form a 4-membered to 12-membered heterocyclic ring,R.sup.2 represents cyano, alkoxycarbonyl, acyl, alkylsulphonyl or arylspulphonyl, the four last-mentioned groups being optionally substituted, or represents an amide or thioamide group, comprising the radical CO--NR.sup.6 R.sup.7 or CS--NR.sup.6 R.sup.7, whereinR.sup.6 represents hydrogen or alkyl andR.sup.7 represents alkyl, cycloalkyl or optionally substituted phenyl, orR.sup.2 and R.sup.3, together with the connecting carbon atom, represent an .alpha.-cycloalkanone ring system with 5 to 7 carbon atoms, which can be optionally substituted,which possess fungicidal properties.

摘要翻译： 其中R 1表示任选取代的烷基，任选取代的烯基，任选取代的炔基，任选取代的环烷基，任选取代的芳基，芳烷基，芳基，芳基，芳基， 最后提到的基团可以被烷基取代，或氨基-NR4R5，其中R4和R5可以相同或不同，各自表示任选取代的烷基，或者R4和R5连同连接的氮原子和 任选的一个或多个另外的杂原子形成4元至12元杂环，R 2表示氰基，烷氧基羰基，酰基，烷基磺酰基或芳基磺酰基，四个最后提及的基团任选被取代，或表示酰胺基或硫代酰胺基团，包括 基团CO-NR 6 R 7或CS-NR 6 R 7，其中R 6表示氢或烷基，R 7表示烷基，环烷基或任选取代的苯基，或R 2和R 3，togeth 与连接碳原子一起表示具有5至7个碳原子的α-环烷酮环系统，其可任选被取代，其具有杀真菌性质。

公开(公告)号：US4382933A

公开(公告)日：1983-05-10

申请号：US267830

申请日：1981-05-28

申请人： Klaus Grohe ,  Hans-Joachim Scholl ,  Volker Paul ,  Wilhelm Brandes ,  Paul-Ernst Frohberger

发明人： Klaus Grohe ,  Hans-Joachim Scholl ,  Volker Paul ,  Wilhelm Brandes ,  Paul-Ernst Frohberger

IPC分类号： A01N43/78 ,  A01N47/08 ,  C07D277/20 ,  C07D277/38 ,  C07D277/40 ,  C07D277/42 ,  C07D277/04 ,  A61K31/425

CPC分类号： C07D277/20 ,  A01N47/08

摘要： 2-Methylene-3-substituted-4,5-bis-trifluoromethyl-imino-thiazolidines of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted cycloalkyl, optionally substituted aryl, aralkyl, it being possible for the last-mentioned group to be substituted on the alkyl radical, or an amino group --NR.sup.4 R.sup.5, whereinR.sup.4 and R.sup.5 may be identical or different, each represent optionally substituted alkyl, or R.sup.4 and R.sup.5 together with the connecting nitrogen atom and optionally one or more further hetero-atoms, form a 4-membered to 12-membered heterocyclic ring,R.sup.2 represents cyano, alkoxycarbonyl, acyl, alkylsulphonyl or arylsulphonyl, the four last-mentioned groups being optionally substituted, or represents an amide or thioamide group, comprising the radical CO--NR.sup.6 R.sup.7 or CS--NR.sup.6 R.sup.7,whereinR.sup.6 represents hydrogen or alkyl andR.sup.7 represents alkyl, cycloalkyl or optionally substituted phenyl, orR.sup.2 and R.sup.3, together with the connecting carbon atom, represent an .alpha.-cycloalkanone ring system with 5 to 7 carbon atoms, which can be optionally substituted, which possess fungicidal properties.

摘要翻译： 其中R 1表示任选取代的烷基，任选取代的烯基，任选取代的炔基，任选取代的环烷基，任选取代的芳基，芳烷基（取代或未取代的芳基），亚烷基 最后提到的基团可以被烷基取代，或氨基-NR4R5，其中R4和R5可以相同或不同，各自表示任选取代的烷基，或者R4和R5连同连接的氮 原子和任选的一个或多个另外的杂原子形成4元至12元杂环，R 2表示氰基，烷氧基羰基，酰基，烷基磺酰基或芳基磺酰基，四个最后提及的基团任选被取代，或表示酰胺或 硫代酰胺基团，其包含基团CO-NR 6 R 7或CS-NR 6 R 7，其中R 6表示氢或烷基，R 7表示烷基，环烷基或任选取代的苯基，或R 2和R 3， 与连接碳原子一起表示具有5至7个碳原子的α-环烷酮环系，其可任选被取代，其具有杀真菌性质。

公开(公告)号：US4396624A

公开(公告)日：1983-08-02

申请号：US964768

申请日：1978-11-29

申请人： Jorg Stetter ,  Udo Kraatz ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Jorg Stetter ,  Udo Kraatz ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D401/12 ,  C07D521/00 ,  A01N43/40

CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： 1-(Azol-1-yl)-2-hydroxy-or-keto-pyridinyloxy-alkanes of the formula ##STR1## in which A is CH or N,R is alkylX is --CO--or --CH(OH)--Y is halogen, alkyl, halogenoalkyl, alkenyl, alkynyl, alkoxy, alkylthio, nitro, cyano, optionally substituted aryl or optionally substituted aryloxy, andn is 0, 1, 2 or 3,an acid addition salt thereof, or a metal salt complex thereof, which possess fungicidal properties.

摘要翻译： 其中A为CH或N，R为烷基X的式（IMA）的1-（偶氮-1-基）-2-羟基 - 或酮 - 吡啶氧基 - 烷烃为-CO-或-CH（OH） Y是卤素，烷基，卤代烷基，烯基，炔基，烷氧基，烷硫基，硝基，氰基，任选取代的芳基或任选取代的芳氧基，n是0,1,2或3，其酸加成盐或金属盐络合物 具有杀菌性。

公开(公告)号：US4904296A

公开(公告)日：1990-02-27

申请号：US121552

申请日：1987-11-17

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D521/00

CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are substituted 1-hydroxyalkylazolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cycloalkyl or optionally substituted phenyl group, Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.

公开(公告)号：US4797499A

公开(公告)日：1989-01-10

申请号：US895089

申请日：1986-08-11

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D521/00 ,  C07D303/08

CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are substituted 1-hydroxyalkyl-azolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cycloalkyl or optionally substituted phenyl group,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.

摘要翻译： 化合物，其中A表示氮原子或CH基团，B表示氧，硫或CH2基团，其中R表示取代的烷基，且表示取代的烷基， B代表硫的情况也代表未取代的烷基，任选取代的环烷基或任选取代的苯基，Z代表卤素原子或烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基，任选取代的苯基， 苯氧基，任选取代的苯基烷基或任选取代的苯基烷氧基，m为0,1,2或3，其酸加成盐和金属盐络合物是新的，如上所述制备，可用作杀真菌剂和植物生长调节剂。

公开(公告)号：US4331675A

公开(公告)日：1982-05-25

申请号：US166268

申请日：1980-07-02

申请人： Erik Regel ,  Wilfried Draber ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Erik Regel ,  Wilfried Draber ,  Karl H. Buchel ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/653 ,  C07D249/08 ,  C07D521/00 ,  A01N43/64

CPC分类号： C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

摘要： A triazolyl-alkene of the formula ##STR1## in which R is an alkyl radical or an optionally substituted phenyl radical,R.sup.1 is a cycloalkyl radical, andR.sup.2 is a hydrogen atom, orR.sup.1 and R.sup.2 together, in the o-position relative to each other, are an optionally substituted polymethylene bridge, or, together with the phenyl ring, are naphthyl,R.sup.3 is a halogen atom or an alkyl, alkoxy or halogenoalkyl radical,n is 0, 1, 2 or 3, andX is a keto radical or a --CH(OH)-radical,or an acid addition salt or metal salt complex thereof, which possesses fungicidal activity.

摘要翻译： 式中，R为烷基或任选取代的苯基的式（III）的三唑基 - 烯烃，R 1为环烷基，R 2为氢原子，或者R 1和R 2一起位于相对于 彼此是任意取代的多亚甲基桥，或者与苯环一起为萘基，R3为卤素原子或烷基，烷氧基或卤代烷基，n为0,1,2或3，X为酮基 自由基或具有杀真菌活性的-CH（OH） - 或其酸加成盐或金属盐络合物。

公开(公告)号：US4960456A

公开(公告)日：1990-10-02

申请号：US354329

申请日：1989-05-19

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D521/00

CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are substituted 1-hydroxyalkyl-azolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents a substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cyclo-alkyl or optionally substituted phenyl group,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.

公开(公告)号：US4734126A

公开(公告)日：1988-03-29

申请号：US683891

申请日：1984-12-20

申请人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Erik Regel ,  Gerhard Jager ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N43/653 ,  C07D233/60 ,  C07D249/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D521/00 ,  A61K31/41

CPC分类号： C07D303/22 ,  A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

摘要： Compounds which are substituted 1-hydroxyalkyl-azolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cycloalkyl or optionally substituted phenyl group,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.

摘要翻译： 化合物，其中A表示氮原子或CH基团，B表示氧，硫或CH2基团，其中R表示取代的烷基，且表示取代的烷基， B代表硫的情况也代表未取代的烷基，任选取代的环烷基或任选取代的苯基，Z代表卤素原子或烷基，环烷基，烷氧基，烷硫基，卤代烷基，卤代烷氧基，卤代烷硫基，任选取代的苯基， 苯氧基，任选取代的苯基烷基或任选取代的苯基烷氧基，m为0,1,2或3，其酸加成盐和金属盐络合物是新的，如上所述制备，可用作杀真菌剂和植物生长调节剂。

公开(公告)号：US4518600A

公开(公告)日：1985-05-21

申请号：US161636

申请日：1980-06-20

申请人： Graham Holmwood ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Graham Holmwood ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/40 ,  A01N43/54 ,  C04B35/565 ,  C07D213/30 ,  C07D239/26 ,  A61K31/505

CPC分类号： C07D213/30 ,  A01N43/40 ,  A01N43/54 ,  C04B35/565 ,  C07D239/26

摘要： 1-Phenoxy-2-pyridinyl(pyrimidinyl)-alkanols of the formula ##STR1## in which R represents alkyl, optionally substituted aryl or optionally substituted aralkyl,X represents a nitrogen atom or the CH group,Y represents halogen, alkyl, cycloalkyl, alkoxy, halogenoalkyl, alkylthio, or an optionally substituted phenyl, phenoxy, phenylalkoxy or phenylalkyl radical, andn represents 0 or an integer from 1 to 5, the Y's being selected independently of one another when n is 2, 3, 4 or 5,in the form of the free base, a salt or a metal salt complex thereof, which possess fungicidal properties.

摘要翻译： 式“IMAGE”的1-苯氧基-2-吡啶基（嘧啶基） - 链烷醇，其中R表示烷基，任选取代的芳基或任选取代的芳烷基，X表示氮原子或CH基团，Y表示卤素，烷基，环烷基， 烷氧基，卤代烷基，烷硫基或任选取代的苯基，苯氧基，苯基烷氧基或苯基烷基，n表示0或1至5的整数，当n为2,3,4或5时，Y彼此独立地选择， 以游离碱的形式，其盐或金属盐络合物具有杀真菌性能。

公开(公告)号：US4415586A

公开(公告)日：1983-11-15

申请号：US376802

申请日：1982-05-10

申请人： Wolfgang Kramer ,  Karl H. Buchel ,  Jorg Stetter ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

发明人： Wolfgang Kramer ,  Karl H. Buchel ,  Jorg Stetter ,  Paul-Ernst Frohberger ,  Wilhelm Brandes ,  Volker Paul

IPC分类号： A01N43/50 ,  A01N47/06 ,  A01N47/12 ,  A01N47/20 ,  A61K31/415 ,  A61P31/04 ,  C07C45/63 ,  C07C45/67 ,  C07C45/71 ,  C07C49/16 ,  C07C49/167 ,  C07C49/255 ,  C07D233/60 ,  C07D521/00 ,  A01N59/16 ,  C07F15/00

CPC分类号： C07D231/12 ,  A01N43/50 ,  A01N47/06 ,  A01N47/12 ,  A01N47/20 ,  C07C45/63 ,  C07C45/673 ,  C07C45/71 ,  C07C49/16 ,  C07C49/167 ,  C07C49/255 ,  C07D233/56 ,  C07D249/08

摘要： Fungicidally active acylated imidazolyl-.gamma.-fluoropiniacolyl derivatives of the formula ##STR1## in which R represents alkyl, alkenyl, alkynyl, alkoxy, alkoxyalkyl, cycloalkyl, halogenoalkyl, optionally substituted phenyl, optionally substituted phenylalkyl, optionally substituted phenoxyalkyl, alkylamino, dialkylamino, optionally substituted phenylamino, halogenoalkylamino, alkoxycarbonylamino or alkoxyalkylamino,X represents hydrogen or fluorine,Z represents halogen, alkyl, cycloalkyl, alkoxy, halogenoalkyl, alkylthio, alkoxycarbonyl, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl, cyano or nitro, each Z being selected independently, andn represents 0 or an integer from 1 to 5,or a physiologically acceptable acid addition salt or metal salt complex thereof.

摘要翻译： 其中R表示烷基，烯基，炔基，烷氧基，烷氧基烷基，环烷基，卤代烷基，任选取代的苯基，任选取代的苯基烷基，任选取代的苯氧基烷基，烷基氨基，二烷基氨基，任选地（C 1 -C 4）烷氧基羰基， 取代的苯基氨基，卤代烷基氨基，烷氧基羰基氨基或烷氧基烷基氨基，X代表氢或氟，Z代表卤素，烷基，环烷基，烷氧基，卤代烷基，烷硫基，烷氧基羰基，任选取代的苯基，任意取代的苯氧基，任意取代的苯基烷基，氰基或硝基， n表示0或1〜5的整数，或其生理学上可接受的酸加成盐或金属盐络合物。