公开(公告)号：US5270414A

公开(公告)日：1993-12-14

申请号：US938409

申请日：1992-08-31

申请人： Koichi Saito ,  Yasutake Mino ,  Eizi Shimoda

发明人： Koichi Saito ,  Yasutake Mino ,  Eizi Shimoda

IPC分类号： C09D5/20 ,  C08F220/04 ,  C08F246/00 ,  C09D5/00 ,  C09D133/04 ,  C09D133/06 ,  C08F26/06 ,  C08F120/60

CPC分类号： C09D5/008 ,  C08F220/04 ,  C08F246/00

摘要： A copolymer for a protective coating is formed from a mixture of .alpha., .beta.-ethylenically unsaturated monomer, .alpha., .beta.-ethylenically unsaturated carboxylic acid monomer, and amphiphilic monomer. The protective coating has an average molecular weight of 7000 to 25000 to provide the desired properties of rapid drying, substantial film strength, and easy removal with an alkaline aqueous solution.

公开(公告)号：US4673444A

公开(公告)日：1987-06-16

申请号：US783059

申请日：1985-10-01

申请人： Koichi Saito ,  Yasutake Mino ,  Ryoichi Murakami

发明人： Koichi Saito ,  Yasutake Mino ,  Ryoichi Murakami

IPC分类号： C23C22/18 ,  C23C22/73 ,  C23C22/14

CPC分类号： C23C22/184 ,  C23C22/182 ,  C23C22/73

摘要： A method of phosphating the surfaces of iron-based metals, zinc-based metals, or combinations of such surfaces by contacting the metal surfaces with an acidic aqueous phosphating solution containing from about 0.1 to about 2.0 g/l of zinc ion, from about 5 to about 30 g/l of phosphate ion, from about 0.2 to about 3 g/l of manganese ion, and a conversion coating accelerator. The phosphated metal surfaces are then suitable for electrocoating.

摘要翻译： 通过使金属表面与含有约0.1至约2.0g / l的锌离子的酸性含水磷酸盐溶液接触，从约5分钟，使铁基金属，锌基金属或这些表面的组合磷酸化， 至约30g / l的磷酸根离子，约0.2至约3g / l的锰离子和转化涂层促进剂。 磷化金属表面适用于电泳。

公开(公告)号：US4443273A

公开(公告)日：1984-04-17

申请号：US332700

申请日：1981-12-21

申请人： Koichi Saito ,  Yasutake Mino ,  Nobuo Nakatani ,  Ryoichi Murakami

发明人： Koichi Saito ,  Yasutake Mino ,  Nobuo Nakatani ,  Ryoichi Murakami

IPC分类号： C23C22/13 ,  C23C22/73 ,  C23C22/77 ,  C23F7/10

CPC分类号： C23C22/73 ,  C23C22/13

摘要： A method for replenishing a nitrite accelerated zinc phosphate treating liquid for forming zinc phosphate coatings on metal surfaces, wherein the metal surface is treated at the rate of 3 to 15 m.sup.2 per hour per cubic meter of treating liquid and the treating liquid is replenished with free phosphoric acid at the rate of 0.10 to 0.31 moles per 10 m.sup.2 of treated surface area.

摘要翻译： 一种补充金属表面上形成磷酸锌涂层的亚硝酸盐加速磷酸锌处理液的方法，其中金属表面以每立方米3立方米处理液3至15m 2 / h的速率处理，并且处理液补充 磷酸，每10平方米处理的表面积为0.10至0.31摩尔。

公开(公告)号：US5039363A

公开(公告)日：1991-08-13

申请号：US532241

申请日：1990-05-30

申请人： Masahiro Jo ,  Yasutake Mino ,  Takamasa Shimizu ,  Koetsu Endo ,  Akio Tokuyama ,  Tamotsu Sobata

发明人： Masahiro Jo ,  Yasutake Mino ,  Takamasa Shimizu ,  Koetsu Endo ,  Akio Tokuyama ,  Tamotsu Sobata

IPC分类号： C23C22/42

CPC分类号： C23C22/42

摘要： A process for phosphating the surfaces of iron-based metals, zinc-based metals or combination of such surfaces by treating the metal surfaces with an aqueous acidic zinc-phosphating solution comprising from about 0.1 to about 200 g/l of zinc ion, from about 5 to about 40 g/l of phosphate ion, from about 0.01 to 20.0 g/l as tungsten of soluble tungsten compound and a conversion coating accelerator. The metal surfaces thus phosphated with the solution are suitable for electrocoating.

公开(公告)号：US5328526A

公开(公告)日：1994-07-12

申请号：US40964

申请日：1993-03-31

申请人： Masahiro Jo ,  Yasutake Mino ,  Tamotsu Sobata

发明人： Masahiro Jo ,  Yasutake Mino ,  Tamotsu Sobata

IPC分类号： C23C22/12 ,  C23C22/18 ,  C23C22/36

CPC分类号： C23C22/368 ,  C23C22/12 ,  C23C22/182 ,  C23C22/188 ,  C23C22/362

摘要： A zinc phosphate coating film suitable for cationic electrodeposition coating and superior in both of coating film adhesion and corrosion resistance (especially, warm brine resistance and scab resistance) is formed by a conversion treatment of a metal surface using an acidic zinc-phosphating solution which does not contain a nickel ion as an essential component. The conversion treatment is carried out by bringing a metal surface into contact with a zinc-phosphating solution containing a zinc ion of 0.1 to 2.0 g/l, a phosphate ion of 5 to 40 g/l, a lanthanum compound of 0.001 to 3 g/l in terms of a lanthanum metal, and a phosphating accelerator, thereby the zinc phosphate coating film is formed on the metal surface.

摘要翻译： 通过使用酸性磷酸锌溶液对金属表面进行转化处理，形成适用于阳离子电沉积涂层的磷酸锌涂膜，并且在涂膜粘附性和耐腐蚀性（特别是耐温盐渍性和耐刮擦性）方面均优异。 不含镍离子作为必需成分。 转化处理通过使金属表面与含有0.1〜2.0g / l的锌离子，5〜40g / l的磷酸根离子，0.001〜3g的镧化合物的锌 - 磷酸化溶液接触来进行 镧金属和磷化促进剂，由此在金属表面上形成磷酸锌被膜。

公开(公告)号：US5221370A

公开(公告)日：1993-06-22

申请号：US538054

申请日：1990-06-14

申请人： Masahiro Jo ,  Yasutake Mino ,  Takamasa Shimizu ,  Koetsu Endo ,  Akio Tokuyama ,  Tamotsu Sobata

发明人： Masahiro Jo ,  Yasutake Mino ,  Takamasa Shimizu ,  Koetsu Endo ,  Akio Tokuyama ,  Tamotsu Sobata

IPC分类号： C23C22/12 ,  C23C22/17 ,  C23C22/18 ,  C23C22/22 ,  C23C22/42

CPC分类号： C23C22/42

摘要： A zinc phosphate film on a metal surface is used as a surface-protecting film and an under coating film for coating and so on. The zinc phosphate film is formed by treating a metal surface with an aqueous zinc phosphate solution. The aqueous zinc phosphate solution includes solutions containing a zinc ion in a concentration of more than 2 g/l to 20 g/l, a phosphate ion in a concentration of 5 g/l to 40 g/l, and at least one of silicotungstic acid and a silicotungstate in a concentration of 0.005 g/l to 20 g/l measured in terms of tungsten content.

公开(公告)号：US6083896A

公开(公告)日：2000-07-04

申请号：US362732

申请日：1999-07-29

申请人： Toshio Inbe ,  Shinji Sasakuma ,  Yasutake Mino ,  Satoshi Ikeda

发明人： Toshio Inbe ,  Shinji Sasakuma ,  Yasutake Mino ,  Satoshi Ikeda

IPC分类号： C11D1/72 ,  C11D3/04 ,  C11D17/08 ,  C23G1/12 ,  C11D3/02 ,  C23G1/02 ,  C11D14/02 ,  C23G14/02

CPC分类号： C23G1/125

摘要： The present invention provides an aqueous cleaning solution for aluminum-based metals which comprises an inorganic acid in an amount to provide a pH value of 2 or less, an oxidized form metal ion and a surfactant represented by the following formula (I)R--O--(EO).sub.n H (I)wherein R represents an alkyl group having on average 10 to 18 carbon atoms per molecule, n represents an integer of 8 or greater, and EO represents an ethyleneoxy group which may contain a small proportion of a propyleneoxy group. The degradation of cleaning properties due to the accumulation of lubricating oil or decomposition of surfactants is lessened even when the cleaning operation is carried out for a long period of time.

摘要翻译： 本发明提供一种铝基金属的水性清洗液，其含有pH值为2以下的无机酸，氧化型金属离子和下式（I）表示的表面活性剂RO-（ EO）nH（I）其中R表示每分子平均具有10至18个碳原子的烷基，n表示8或更大的整数，EO表示可含有少量丙烯氧基的乙烯氧基。 即使长时间进行清洁操作，由于润滑油的积聚或表面活性剂的分解而导致的清洗性能的降低也降低。