公开(公告)号：US08221559B2

公开(公告)日：2012-07-17

申请号：US12077464

申请日：2008-03-19

申请人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

发明人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

IPC分类号： C23C10/02 ,  C25D13/12

CPC分类号： C23C22/34 ,  C23C2222/20 ,  C25D3/56 ,  C25D13/20

摘要： A surface treatment with a zirconium ion that enables sufficient throwing power and superior anti-corrosion properties to be exhibited when thus surface treated metal base material is subjected to cation electrodeposition coating is provided. A metal surface treatment liquid thereof for cation electrodeposition coating includes zirconium ions, copper ions, and other metal ions, and having a pH of 1.5 to 6.5, in which: the other metal ions are at least one selected from the group consisting of tin ions, indium ions, aluminum ions, niobium ions, tantalum ions, yttrium ions and cerium ions; the concentration of zirconium ions is 10 to 10,000 ppm; the concentration ratio of the copper ions to the zirconium ions is 0.005 to 1 on a mass basis; and the concentration ratio of the other metal ions to the copper ions is 0.1 to 1,000 on a mass basis.

摘要翻译： 提供了一种用这种表面处理的金属基材进行阳离子电沉积涂覆时能够发挥足够的抛光力和优异的抗腐蚀性能的锆离子的表面处理。 用于阳离子电沉积涂层的金属表面处理液包括锆离子，铜离子和其它金属离子，并且具有1.5至6.5的pH，其中：其它金属离子是选自锡离子 铟离子，铝离子，铌离子，钽离子，钇离子和铈离子; 锆离子的浓度为10〜10000ppm; 基于质量计，铜离子与锆离子的浓度比为0.005〜1; 并且其他金属离子与铜离子的浓度比以质量计为0.1〜1,000。

公开(公告)号：US20120160372A1

公开(公告)日：2012-06-28

申请号：US13414449

申请日：2012-03-07

申请人： Toshio Inbe ,  Yusuke Wada ,  Masanobu Futsuhara

发明人： Toshio Inbe ,  Yusuke Wada ,  Masanobu Futsuhara

IPC分类号： C23C22/00

CPC分类号： C23C22/78 ,  C09D5/002 ,  C09D5/106 ,  C23C22/60 ,  C23C22/68

摘要： A surface conditioning composition for use in surface conditioning of a metal prior to being subjected to a phosphate-based chemical conversion treatment, in which the surface conditioning composition has a pH of 3 to 12, and includes at least one kind of zinc compound particles selected from the group consisting of zinc oxide particles, zinc hydroxide particles, and basic zinc carbonate particles; phosphoric acid and/or condensed phosphoric acid; and an amine compound having a specific structure and in which the zinc compound particles are dispersed and stabilized by the phosphoric acid and/or condensed phosphoric acid, and the amine compound.

摘要翻译： 一种表面处理组合物，用于在进行基于磷酸盐的化学转化处理之前的金属的表面调节中，其中表面调节组合物的pH为3至12，并且包括至少一种选择的锌化合物颗粒 由氧化锌颗粒，氢氧化锌颗粒和碱式碳酸锌颗粒组成的组中; 磷酸和/或缩合磷酸; 和具有特定结构的胺化合物，其中锌化合物颗粒被磷酸和/或缩合磷酸分散和稳定，以及胺化合物。

公开(公告)号：US20120160129A1

公开(公告)日：2012-06-28

申请号：US13414220

申请日：2012-03-07

申请人： Toshio Inbe ,  Yusuke Wada ,  Masanobu Futsuhara

发明人： Toshio Inbe ,  Yusuke Wada ,  Masanobu Futsuhara

IPC分类号： C09D5/00

CPC分类号： C23C22/78

摘要： The present invention provides a surface conditioning composition having a surface conditioning function that is even more superior as compared with conventional surface conditioning compositions.A surface conditioning composition is provided for use in surface conditioning of a metal prior to being subjected to a phosphate-based chemical conversion treatment, in which the surface conditioning composition has a pH of 3 to 12, and includes nearly spherical zinc phosphate particles having an average particle diameter from 0.05 μm to 3 μm, and in which the zinc phosphate particles are produced by mixing at least one kind of zinc compound particles selected from the group consisting of zinc oxide, zinc hydroxide, and basic zinc carbonate with phosphoric acid and/or condensed phosphoric acid to allow for their reaction in an acidic aqueous solution having a pH lower than 7, and dispersing and stabilizing by a dispersion means.

摘要翻译： 本发明提供了一种具有与常规表面调理组合物相比更好的表面调节功能的表面调理组合物。 提供表面调理组合物，用于在进行磷酸盐基化学转化处理之前的金属的表面调节中，其中表面调节组合物的pH为3至12，并且包括几乎球形的磷酸锌颗粒，其具有 平均粒径为0.05μm〜3μm，其中通过将选自氧化锌，氢氧化锌和碱式碳酸锌的至少一种锌化合物颗粒与磷酸和/ 或缩合磷酸使其在pH低于7的酸性水溶液中反应，并通过分散方法分散和稳定。

公开(公告)号：US20090218228A1

公开(公告)日：2009-09-03

申请号：US12224628

申请日：2007-02-28

申请人： Toshio Inbe ,  Thomas Kolberg

发明人： Toshio Inbe ,  Thomas Kolberg

IPC分类号： B32B15/00 ,  C11D3/04 ,  B05D3/10 ,  C25D5/00 ,  C23G1/02

CPC分类号： C23C22/48 ,  C08G59/50 ,  C08G77/26 ,  C08K3/10 ,  C09D163/00 ,  C09D175/04 ,  C23C22/50 ,  C23C22/56 ,  C23C22/83 ,  Y10T428/12729 ,  Y10T428/12736 ,  Y10T428/12792 ,  Y10T428/12951

摘要： An easily handleable composition for metal surface treatment is provided which achieves foundation surface concealment, coating adhesion and corrosion resistance equal to or higher than those obtained by the conventional metal surface treatment compositions. This composition for metal surface treatment places no burden on the environment. A method for treating the surface of a metal material in which such a composition for metal surface treatment is used, and a metal material treated by such a metal surface treatment method, are also provided. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or titanium compound substantially not containing fluorine, and an inorganic acid and/or a salt thereof. This metal surface treatment composition has a pH of not less than 1.5 but not more than 6.5.

摘要翻译： 提供了用于金属表面处理的易于处理的组合物，其实现了与通过常规金属表面处理组合物获得的那些相同或更高的基础表面隐蔽性，涂层粘附性和耐腐蚀性。 这种金属表面处理用组合物不会对环境造成负担。 还提供了一种用于处理金属表面处理用金属材料的表面的方法以及通过这种金属表面处理方法处理的金属材料。 具体公开了用于处理金属表面的金属表面处理组合物，该组合物含有基本上不含氟的锆化合物和/或钛化合物，以及无机酸和/或其盐。 该金属表面处理组合物的pH值不低于1.5但不大于6.5。

公开(公告)号：US06659171B2

公开(公告)日：2003-12-09

申请号：US10105421

申请日：2002-03-26

申请人： Toshio Inbe ,  Susumu Maekawa ,  Akira Ushio ,  Koichi Saito ,  Norizumi Matsui ,  Osamu Kasebe ,  Kengo Kobayashi ,  Hiroyoshi Sugawara ,  Kazuhisa Uchiyama

发明人： Toshio Inbe ,  Susumu Maekawa ,  Akira Ushio ,  Koichi Saito ,  Norizumi Matsui ,  Osamu Kasebe ,  Kengo Kobayashi ,  Hiroyoshi Sugawara ,  Kazuhisa Uchiyama

IPC分类号： F28F1318

CPC分类号： C09D129/04 ,  C08K3/32 ,  C08K3/38 ,  C08L29/04 ,  C08L71/02 ,  C08L2205/02 ,  F28D17/005 ,  F28F13/18 ,  F28F2245/02 ,  C08L2666/04 ,  C08L2666/14

摘要： A hydrophilic modification method comprising a step of forming a coat having a solid coat amount of 0.02 to 3 g/m2 on a heat exchanger with a modifier for hydrophilicity after treatment for rust prevention thereof wherein said modifier for hydrophilicity comprises a modified polyvinyl alcohol (A) having, on a side chain thereof, a group represented by the formula (I): in the formula, n represents an integer of 1 to 500, R1 represents a hydrogen atom or an alkyl group containing 1 to 4 carbon atoms, and R2 represents a hydrogen atom or a methyl group, and at least one member (B) selected from the group consisting of phosphorus compound salts and boron compound salts of Ca, Al, Mg, Fe and Zn, said group represented by the formula (I) accounting for 0.01 to 20 mole percent relative to hydroxyl and acetoxy groups contained in said modified polyvinyl alcohol.

摘要翻译： 一种亲水性改性方法，其特征在于，在具有用于防锈处理后的亲水性改性剂的热交换器上形成具有0.02〜3g / m 2的固体涂层量的涂层的步骤，其中所述亲水性改性剂包含改性聚乙烯醇 A）在其侧链上具有由式（I）表示的基团：在该式中，n表示1〜500的整数，R 1表示氢原子或含有1〜4个碳的烷基 原子，R 2表示氢原子或甲基，以及至少一种选自磷化合物盐和Ca，Al，Mg，Fe和Zn的硼化合物的组分（B），所述基团 由式（I）表示，相对于所述改性聚乙烯醇中所含的羟基和乙酰氧基为0.01〜20摩尔％。

公开(公告)号：US06528468B2

公开(公告)日：2003-03-04

申请号：US09726420

申请日：2000-12-01

申请人： Masahiko Matsukawa ,  Kentaro Saito ,  Toshio Inbe ,  Kasuyoshi Yamasoe

发明人： Masahiko Matsukawa ,  Kentaro Saito ,  Toshio Inbe ,  Kasuyoshi Yamasoe

IPC分类号： C11D708

CPC分类号： F28F19/02 ,  C23C22/78 ,  C23G1/125

摘要： The present invention relates to a pickling agent for the chemical conversion coating of a heat exchanger which is capable of cleaning the complicated structure comprising fins and tubes of a heat exchanger in preparation for the successful formation of a chemical conversion film, a method of pickling a heat exchanger, a method of treating a heat exchanger comprising said pickling method, and a heat exchanger produced by using said treating method. The present invention provides pickling agent for the chemical conversion coating of a heat exchanger which comprises an acidic aqueous solution containing nitric acid and/or sulfuric acid and at least one metal and/or metal oxoanion salt derived from any metal selected from the group consisting of iron, nickel, cobalt, molybdenum and cerium.

摘要翻译： 本发明涉及一种热交换器的化学转化涂层的酸洗剂，其能够清洁包括热交换器的翅片和管的复杂结构，以准备成功地形成化学转化膜，酸洗方法 热交换器，处理包括所述酸洗方法的热交换器的方法和使用所述处理方法制造的热交换器。本发明提供一种用于热交换器的化学转化涂层的酸洗剂，其包含含有硝酸的酸性水溶液和/ 或硫酸以及衍生自选自铁，镍，钴，钼和铈的任何金属的至少一种金属和/或金属氧代阴离子盐。

公开(公告)号：US08916006B2

公开(公告)日：2014-12-23

申请号：US12440265

申请日：2007-09-07

申请人： Toshio Inbe ,  Kazuhiro Makino ,  Hiroshi Kameda ,  Masanobu Futsuhara

发明人： Toshio Inbe ,  Kazuhiro Makino ,  Hiroshi Kameda ,  Masanobu Futsuhara

IPC分类号： C23C22/34

CPC分类号： C25D5/34 ,  C23C22/05 ,  C23C22/34 ,  C23C22/73 ,  C23C22/82 ,  C23C22/83 ,  C23C28/00 ,  C23C2222/20 ,  C25D9/08 ,  C25D13/20 ,  Y10T428/24628

摘要： A metal surface treatment method for a metal base material in order to improve the uniformity of a cathodic electrodeposition coating film, the method including: a surface treatment step for forming a chemical conversion film on a metal base material by contacting the metal base material with a metal surface treatment composition including zirconium and/or titanium ions and an adhesive imparting agent characterized in being at least one selected from the group consisting of (A) silicon-containing compound, (B) adhesive imparting metal ion, and (C) adhesive imparting resin; and a heating/drying step to heat and dry the metal base material, on which the chemical conversion film is formed, at 60° C. to 190° C. for at least 30 seconds.

摘要翻译： 为了提高阴极电沉积涂膜的均匀性，金属基材的金属表面处理方法，该方法包括：表面处理步骤，用于通过使金属基材与金属基材接触而在金属基材上形成化学转化膜 金属表面处理组合物，包括锆和/或钛离子，以及粘合剂赋予剂，其特征在于：选自（A）含硅化合物，（B）赋予金属的金属离子和（C）赋予粘合剂的组中的至少一种 树脂; 以及加热干燥步骤，将形成有化学转化膜的金属基材在60℃〜190℃下加热干燥至少30秒钟。

公开(公告)号：US08262809B2

公开(公告)日：2012-09-11

申请号：US12224628

申请日：2007-02-28

申请人： Toshio Inbe ,  Thomas Kolberg

发明人： Toshio Inbe ,  Thomas Kolberg

IPC分类号： C22C22/48 ,  C25D9/00

CPC分类号： C23C22/48 ,  C08G59/50 ,  C08G77/26 ,  C08K3/10 ,  C09D163/00 ,  C09D175/04 ,  C23C22/50 ,  C23C22/56 ,  C23C22/83 ,  Y10T428/12729 ,  Y10T428/12736 ,  Y10T428/12792 ,  Y10T428/12951

摘要： An easily handleable composition for metal surface treatment is provided which achieves foundation surface concealment, coating adhesion and corrosion resistance equal to or higher than those obtained by the conventional metal surface treatment compositions. This composition for metal surface treatment places no burden on the environment. A method for treating the surface of a metal material in which such a composition for metal surface treatment is used, and a metal material treated by such a metal surface treatment method, are also provided. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or titanium compound substantially not containing fluorine, and an inorganic acid and/or a salt thereof. This metal surface treatment composition has a pH of not less than 1.5 but not more than 6.5.

摘要翻译： 提供了用于金属表面处理的易于处理的组合物，其实现了与通过常规金属表面处理组合物获得的那些相同或更高的基础表面隐蔽性，涂层粘附性和耐腐蚀性。 这种金属表面处理用组合物不会对环境造成负担。 还提供了一种用于处理金属表面处理用金属材料的表面的方法以及通过这种金属表面处理方法处理的金属材料。 具体公开了用于处理金属表面的金属表面处理组合物，该组合物含有基本上不含氟的锆化合物和/或钛化合物，以及无机酸和/或其盐。 该金属表面处理组合物的pH值不低于1.5但不大于6.5。

公开(公告)号：US20100243465A1

公开(公告)日：2010-09-30

申请号：US12679048

申请日：2008-09-26

申请人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

发明人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

IPC分类号： C23C22/80 ,  B05D3/10

CPC分类号： C23C22/361 ,  C09D5/4488 ,  C23C22/34 ,  C23C22/83 ,  C23C2222/20 ,  C25D13/04

摘要： A method of producing a surface-treated metal material, comprising: surface treating a metal material using a treatment liquid (1), which comprises from 10 to 10,000 ppm of tin ions and has a pH of 1.0 or greater, and subjecting the metal material that has undergone surface treatment with the treatment liquid (1) to an additional chemical conversion treatment using a treatment liquid (2), which comprises zirconium ions and/or titanium ions.

摘要翻译： 一种表面处理金属材料的制造方法，其特征在于，包括：使用处理液（1）对金属材料进行表面处理，所述处理液包含10〜10000ppm的锡离子，pH为1.0以上，并对所述金属材料 已经用处理液（1）进行表面处理，使用包含锆离子和/或钛离子的处理液（2）进行附加的化学转化处理。

公开(公告)号：US20080230395A1

公开(公告)日：2008-09-25

申请号：US12077464

申请日：2008-03-19

申请人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

发明人： Toshio Inbe ,  Hiroshi Kameda ,  Thomas Kolberg

IPC分类号： C25D5/00

CPC分类号： C23C22/34 ,  C23C2222/20 ,  C25D3/56 ,  C25D13/20

摘要： A surface treatment with a zirconium ion that enables sufficient throwing power and superior anti-corrosion properties to be exhibited when thus surface treated metal base material is subjected to cation electrodeposition coating is provided. A metal surface treatment liquid thereof for cation electrodeposition coating includes zirconium ions, copper ions, and other metal ions, and having a pH of 1.5 to 6.5, in which: the other metal ions are at least one selected from the group consisting of tin ions, indium ions, aluminum ions, niobium ions, tantalum ions, yttrium ions and cerium ions; the concentration of zirconium ions is 10 to 10,000 ppm; the concentration ratio of the copper ions to the zirconium ions is 0.005 to 1 on a mass basis; and the concentration ratio of the other metal ions to the copper ions is 0.1 to 1,000 on a mass basis.

摘要翻译： 提供了一种用这种表面处理的金属基材进行阳离子电沉积涂覆时能够发挥足够的抛光力和优异的抗腐蚀性能的锆离子的表面处理。 用于阳离子电沉积涂层的金属表面处理液包括锆离子，铜离子和其它金属离子，并且具有1.5至6.5的pH，其中：其它金属离子是选自锡离子 铟离子，铝离子，铌离子，钽离子，钇离子和铈离子; 锆离子的浓度为10〜10000ppm; 基于质量计，铜离子与锆离子的浓度比为0.005〜1; 并且其他金属离子与铜离子的浓度比以质量计为0.1〜1,000。