HYDROPHILIC FILM
    1.
    发明申请
    HYDROPHILIC FILM 有权
    水胶片

    公开(公告)号:US20110008630A1

    公开(公告)日:2011-01-13

    申请号:US12933743

    申请日:2009-03-19

    IPC分类号: B32B27/06 B05D3/10

    摘要: The present invention provides a hydrophilic film that has high adhesion to inorganic materials and is safer and excellent in transparency and also exhibits both very high hydrophilicity and abrasion resistance, and also provides a laminate including the hydrophilic film. The hydrophilic film is produced by applying a specific hydrophilic compound (c) having an acryloyl group and a potassium sulfonate group or the like to a surface of a layer formed from a mixture containing a silane compound (a) including one silicon atom, a mercapto group or the like, and at least one silicon-bonded group selected from the group consisting of an alkoxy group, a halogen group, and a hydroxy group, and a silane compound (b) including at least four silicon-bonded groups selected from the group consisting of an alkoxy group, a halogen group, and a hydroxy group and not including groups reactive with a carbon-carbon double bond, and allowing a reaction between at least a part of acryloyl groups contained in the hydrophilic compound (c) and at least a part of mercapto groups derived from the compound (a).

    摘要翻译: 本发明提供一种对无机材料具有高粘附性的亲水性膜,其透明度更安全且优异,并且亲水性和耐磨性都非常高,并且还提供了包含亲水膜的层压体。 通过将具有丙烯酰基和磺酸钾基等的特定亲水性化合物(c)等涂布在由含有一个硅原子的硅烷化合物(a)的混合物形成的层的表面上,将巯基 基团等,以及选自烷氧基,卤素基和羟基中的至少一个硅键合基团和包含至少四个与硅键合的基团的硅烷化合物(b),所述硅键合基团选自 由烷氧基,卤素基和羟基组成的基团,不包括与碳 - 碳双键反应的基团,并且允许亲水性化合物(c)中包含的至少一部分丙烯酰基与 至少一部分衍生自化合物(a)的巯基。

    Hydrophilic film
    2.
    发明授权
    Hydrophilic film 有权
    亲水膜

    公开(公告)号:US09512034B2

    公开(公告)日:2016-12-06

    申请号:US12933743

    申请日:2009-03-19

    摘要: A hydrophilic film that has high adhesion to inorganic materials and is safer and excellent in transparency and also exhibits both very high hydrophilicity and abrasion resistance, and a laminate including the hydrophilic film. The hydrophilic film is produced by applying a specific hydrophilic compound (c) having an acryloyl group and a potassium sulfonate group or the like to a surface of a layer formed from a mixture containing a silane compound (a) including one silicon atom, a mercapto group or the like, and at least one silicon-bonded group, and a silane compound (b) including at least four silicon-bonded groups and not including groups reactive with a carbon-carbon double bond, and allowing a reaction between at least a part of acryloyl groups contained in the hydrophilic compound (c) and at least a part of mercapto groups derived from the compound (a).

    摘要翻译: 对无机材料具有高粘附性的亲水性膜,透明性更好,透明性优异,亲水性和耐磨性均显示出极高的亲水性,以及包含该亲水性膜的层叠体。 通过将具有丙烯酰基和磺酸钾基等的特定亲水性化合物(c)等涂布在由含有一个硅原子的硅烷化合物(a)的混合物形成的层的表面上,将巯基 基团等和至少一个硅键合基团,以及包含至少四个与硅键合的基团并且不包括与碳 - 碳双键反应的基团的硅烷化合物(b),并且使至少一种 包含在亲水性化合物(c)中的部分丙烯酰基和衍生自化合物(a)的至少一部分巯基。

    Primer composition
    3.
    发明授权

    公开(公告)号:US10040947B2

    公开(公告)日:2018-08-07

    申请号:US12921775

    申请日:2009-03-09

    申请人: Koju Okazaki

    发明人: Koju Okazaki

    摘要: The present invention aims to provide a primer composition that can give good adhesion between an acrylic resin and an inorganic substrate, such as a substrate formed of metal, metal oxide, glass, ceramic, cement, or mortar and is suitably used as a primer for bonding them together. The primer composition is produced by mixing (a) a polythiol having at least two mercapto groups in one molecule, (b) a silane compound having at least one functional group and at least one alkoxysilyl group in one molecule, the at least one functional group being reactive with a mercapto group, and water.

    MONOLAYER FILM AND HYDROPHILIC MATERIAL COMPRISING THE SAME
    4.
    发明申请
    MONOLAYER FILM AND HYDROPHILIC MATERIAL COMPRISING THE SAME 有权
    单层膜和包含它的水解材料

    公开(公告)号:US20140154451A1

    公开(公告)日:2014-06-05

    申请号:US14234941

    申请日:2011-07-25

    申请人: Koju Okazaki

    发明人: Koju Okazaki

    IPC分类号: C09K3/18 C09D5/00 C09D5/16

    摘要: The invention provides monolayer films which not only have hydrophilicity and are excellent in such properties as antifogging properties, antifouling properties, antistatic properties and anti-condensation properties but also tend to exhibit excellent transparency even with a large film thickness and excellent scratch resistance, as well as stacks having the monolayer film. The monolayer film is obtained by preparing a mixture including a monomer composition and a solvent, the monomer composition including a specific monomer and a polyvalent monomer having two or more (meth)acryloyl groups and being free of sulfonic group, carboxyl group and phosphoric group in a specific molar ratio, the solvent having a specific solubility parameter σ; applying the mixture onto a substrate and removing at least part of the solvent; and polymerizing the monomer composition to produce a monolayer film having at least one anionic hydrophilic group selected from a sulfonic group, a carboxyl group and a phosphoric group and a specific anion concentration ratio (Sa/Da) of the anion concentration (Sa) at the outer surface to the anion concentration (Da) at the middle point between the inner surface in contact with the substrate and the outer surface.

    摘要翻译: 本发明提供了单层膜,其不仅具有亲水性,并且在防雾性,防污性,抗静电性和抗缩合性等性能方面优异,而且即使具有大的膜厚度和优异的耐刮擦性也倾向于表现出优异的透明性,以及 作为具有单层膜的堆叠。 通过制备包含单体组合物和溶剂的混合物获得单层膜,该单体组合物包含特定单体和具有两个或更多个(甲基)丙烯酰基并且不含磺酸基,羧基和磷酸基的多价单体 特定摩尔比,具有特定溶解度参数的溶剂; 将混合物施加到基材上并除去至少一部分溶剂; 并且使单体组合物聚合以制备具有至少一个选自磺酸基,羧基和磷酸基的阴离子亲水基团的单层膜和阴离子浓度(Sa)的特定阴离子浓度比(Sa / Da) 外表面与底物接触的内表面与外表面之间的中点处的阴离子浓度(Da)。

    Polymerizable composition
    7.
    发明授权
    Polymerizable composition 有权
    可聚合组合物

    公开(公告)号:US06300464B2

    公开(公告)日:2001-10-09

    申请号:US09745448

    申请日:2000-12-26

    IPC分类号: C08G7508

    摘要: An optical resin prepared by curing a polymerizable composition comprising a (thio)epoxy compound having at least one intramolecular disulfide bond exhibits a considerably high refractive index while maintaining good optical properties and a high Abbe number. In addition, the above polymerizable composition to which is added primary and/or secondary amines as an yellowing inhibitor in a proportion of 0.001 to 0.5 of the total molar number of NH2 and NH groups in the amines to the total molar number of thioepoxy and epoxy groups in the (thio)epoxy compound having at least one intramolecular disulfide bond, can provide a transparent resin in which yellowing and reduction in heat resistance associated therewith are adequately prevented while maintaining a high refractive index.

    摘要翻译: 通过固化包含具有至少一个分子内二硫键的(硫代)环氧化合物的可聚合组合物制备的光学树脂显示相当高的折射率,同时保持良好的光学性能和高的阿贝数。 此外,上述可聚合组合物中加入伯胺和/或仲胺作为泛黄抑制剂,其比例为胺的总NH 2和NH基总数的0.001至0.5,硫代环氧和环氧基的总摩尔数 具有至少一个分子内二硫键的(硫代)环氧化合物中的基团可以提供透明树脂,其中在保持高折射率的同时充分防止与其相关的黄变和降低的耐热性。

    SINGLE-LAYER FILM AND HYDROPHILIC MATERIAL COMPRISING THE SAME
    10.
    发明申请
    SINGLE-LAYER FILM AND HYDROPHILIC MATERIAL COMPRISING THE SAME 有权
    单层薄膜和包含它的水解材料

    公开(公告)号:US20130156959A1

    公开(公告)日:2013-06-20

    申请号:US13812779

    申请日:2011-07-25

    申请人: Koju Okazaki

    发明人: Koju Okazaki

    IPC分类号: C08G75/24

    摘要: There is stably provided a hydrophilic cured product, such as a single-layer film, in which anionic hydrophilic groups are concentrated at a surface that is in contact with the air and which is excellent in transparency and adhesion to a substrate and tends to be rarely cracked. The hydrophilic cured product or single-layer film comprising a resin composition is produced by applying a mixture containing a polyvalent monomer (II) having two or more (meth) acryloyl groups and a compound (IV) having a specific group and a sulfonic acid group to a substrate or the like, drying the mixture if necessary, and then performing polymerization.

    摘要翻译: 稳定地提供亲水性固化物,例如单层膜,其中阴离子亲水基团在与空气接触的表面上浓缩,并且透明性和对基材的粘合性优异,并且倾向于很少 破裂了 含有树脂组合物的亲水性固化物或单层膜通过涂布含有具有两个以上(甲基)丙烯酰基的多元单体(II)和具有特定基团和磺酸基的化合物(IV) 加入到基材等中,根据需要干燥混合物,然后进行聚合。