摘要:
A method of manufacturing a microporous polymeric membrane including: heat-setting the microporous polymeric membrane in at least a first stage and a final stage, the first stage being upstream of the final stage and a temperature of the first stage being at least 15° C. cooler than a temperature of the final stage.
摘要:
A microporous polymeric membrane having excellent properties for use as a battery separator is provided. The membrane is produced by heat-setting the microporous polymeric membrane in at least a first stage and a final stage, the first stage being upstream of the final stage and the temperature of the first stage being at least 15° C. cooler than the temperature of the final stage.
摘要:
A microporous polymeric membrane having excellent properties for use as a battery separator is provided. The membrane is produced by heat-setting the microporous polymeric membrane in at least a first stage and a final stage, the first stage being upstream of the final stage and the temperature of the first stage being at least 15° C. cooler than the temperature of the final stage.
摘要:
The invention generally relates to an extruder for preparing a mixture of polymer and diluent. The extruder includes multiple extruder stages, the multiple extruder stages comprising an inlet stage, a dispersion stage, and at least one mixing stage comprising a reverse mixing screw segment having a helical flight that traverses and forms an outer periphery thereof, the helical flight having a plurality of notches positioned therealong. A process for extruding the polymer-diluent mixture is also provided.
摘要:
The invention relates to a multilayer microporous membrane comprising polyethylene and polypropylene and having an improved balance of properties including improved thickness variation in at least one planar direction. The invention also relates to a system and method for producing such a membrane, the use of such a membrane as a battery separator film, and batteries containing such a membrane.
摘要:
The microporous polyolefin membrane obtained by stretching a gel molding comprising a polyolefin and a membrane-forming solvent at least uniaxially, heat-setting it, removing the membrane-forming solvent, and re-stretching it at least uniaxially has a large pore diameter and excellent air permeability, mechanical strength and compression resistance.
摘要:
A method of producing a microporous polyolefin membrane having a relatively large pore size and a high permeability, the membrane being suitable for use in water treatment, microfiltration, etc. The method comprises dissolving a polyolefin composition in a solvent to prepare a solution, extruding the solution through a die lip into a form of gel-like sheet, rapidly cooling the gel-like sheet, removing a residual solvent in the cooled sheet by a washing solvent, and drying the resultant sheet to remove the washing solvent. The polyolefin composition is a mixture of (A) an ultra high molecular weight polyolefin having a weight average molecular weight of 5.times.10.sup.5 or more and (B) a polyolefin having a weight average molecular weight less than 5.times.10.sup.5, and a weight ratio of (B)/(A) is 0.2 to 20.
摘要:
The invention relates to a twin screw extruder for preparing a polymeric solution. The extruder includes an elongated housing having an inlet end, an outlet end, an extruder shaft length L and a pair of interconnecting bores disposed within the housing, a pair of elongated extruder shafts, each having an axis of rotation, the pair of elongated extruder shafts disposed within the pair of interconnecting bores and drivable in at least one direction of rotation, a plurality of extruder screw segments positioned along the pair of elongated extruder shafts in a fixed angular relationship therewith, the plurality of extruder screw segments selected to form multiple extruder stages. The invention also relates to a process for extruding a mixture of polymer and diluent.
摘要:
A method for producing a microporous polyolefin membrane by extruding a melt blend comprising a polyethylene resin, polypropylene having a mass-average molecular weight of 1×105 or more and an ethylene content of 5% by mass or less, and a membrane-forming solvent through a die, slowly cooling the resultant extrudate to form a gel-like sheet, stretching the gel-like sheet, and removing the above membrane-forming solvent, the slow-cooling speed of the extrudate being 30° C./second or less.
摘要:
A microporous polyolefin composite membrane, preferably for use as a battery separator, comprising a microporous polyolefin membrane and a polyolefin nonwoven fabric laminated on at least one surface of the microporous polyolefin membrane. The composite membrane has a thickness of 25 to 200 .mu.m, a porosity of 30 to 70%, an air permeability of 100 to 2000 sec/100 cc and a surface opening area ratio of 50 to 90% on at least one outer surface thereof. The microporous polyolefin membrane comprises a matrix polyolefin component which is a polyolefin having a weight average molecular weight of 5.times.10.sup.5 or more or a polyolefin mixture containing the polyolefin having a weight average molecular weight of 5.times.10.sup.5 or more, and has a porosity of 30 to 95%, an air permeability of 100 to 2000 sec/100 cc, an average open pore diameter of 0.001 to 1 .mu.m and a tensile strength at break of 500 kg/cm.sup.2 or more. The microporous polyolefin membrane may further comprise a shutdown polymer component to shut down the pores, thereby making the composite membrane impermeable. The polyolefin nonwoven fabric comprises fine fibers and has an air permeability of 0.1 to 100 sec/100 cc and a basis weight of 5 to 50 g/m.sup.2. The polyolefin nonwoven fabric prevents the composite membrane from melting down at a low temperature thereby preventing the short-circuit between the electrodes.
摘要翻译:一种微孔聚烯烃复合膜,优选用作电池隔板,其包含微孔聚烯烃膜和聚烯烃无纺布,该聚烯烃无纺布层叠在微孔聚烯烃膜的至少一个表面上。 复合膜的至少一个外表面的厚度为25〜200μm,孔隙率为30〜70%,透气度为100〜2000秒/ 100cc,表面开口面积率为50〜90% 。 微孔聚烯烃膜包括基重聚烯烃组分,其是重均分子量为5×10 5以上的聚烯烃或含有重均分子量为5×10 5以上的聚烯烃的聚烯烃混合物,其孔隙率为30〜95% 透气度为100〜2000秒/ 100cc,平均开孔直径为0.001〜1μm,断裂强度为500kg / cm 2以上。 微孔聚烯烃膜还可以包括关闭聚合物组分以关闭孔,从而使复合膜不可渗透。 聚烯烃无纺布包括细纤维,透气度为0.1〜100秒/ 100cc,单位面积重量为5〜50g / m 2。 聚烯烃无纺布防止复合膜在低温下熔化,从而防止电极之间的短路。